Sorption–luminescence method for determination of europium using acid-modified clinoptilolite
Sorption–luminescent method for europium determination based on the acid-modified Transcarpathian clinoptilolite without using toxic organic solvents was proposed. Optimal luminophore preparation condition is the sorption of Eu(III) on the precalcined at 400 °C H-clinoptilolite, in the solution with...
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| Veröffentlicht in: | Applied nanoscience 2019-07, Vol.9 (5), p.1145-1153 |
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| creator | Vasylechko, Volodymyr O. Gryshchouk, Galyna V. Kalychak, Yaroslav M. Vasylechko, Leonid O. Voloshinovskii, Anatoliy S. Vistovskyy, Vitaliy V. Tupys, Andrii M. |
| description | Sorption–luminescent method for europium determination based on the acid-modified Transcarpathian clinoptilolite without using toxic organic solvents was proposed. Optimal luminophore preparation condition is the sorption of Eu(III) on the precalcined at 400 °C H-clinoptilolite, in the solution with pH 9.5. The obtained H-clinoptilolite–Eu(III) sample, precalcined at 50 °C, was treated with 1,10-phenanthroline, atophan, and urotropine solutions. For luminescence excitation, the rays with wavelength of
λ
= 276 nm were used. Luminescence intensity at
λ
= 615 nm was selected as an analytical parameter for a europium quantitative determination. Linear calibration range of Eu(III) concentration with the detection limit of 3 ng mL
−1
is within 10–900 ng mL
−1
. The proposed method can be used for europium determination in the presence of many rare earths. Sorption–luminescent method can be applied for the determination of europium ions trace amounts in synthetic water solutions. The proposed analytical method gave recoveries from 95 to 102% and RSD from 3.5 to 7.9% during the determination of europium. |
| doi_str_mv | 10.1007/s13204-018-0878-6 |
| format | Article |
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λ
= 276 nm were used. Luminescence intensity at
λ
= 615 nm was selected as an analytical parameter for a europium quantitative determination. Linear calibration range of Eu(III) concentration with the detection limit of 3 ng mL
−1
is within 10–900 ng mL
−1
. The proposed method can be used for europium determination in the presence of many rare earths. Sorption–luminescent method can be applied for the determination of europium ions trace amounts in synthetic water solutions. The proposed analytical method gave recoveries from 95 to 102% and RSD from 3.5 to 7.9% during the determination of europium.</description><identifier>ISSN: 2190-5509</identifier><identifier>EISSN: 2190-5517</identifier><identifier>DOI: 10.1007/s13204-018-0878-6</identifier><language>eng</language><publisher>Cham: Springer International Publishing</publisher><subject>Chemistry and Materials Science ; Europium ; Luminescence ; Materials Science ; Mathematical analysis ; Membrane Biology ; Nanochemistry ; Nanotechnology ; Nanotechnology and Microengineering ; Original Article ; Rare earth elements ; Sorption</subject><ispartof>Applied nanoscience, 2019-07, Vol.9 (5), p.1145-1153</ispartof><rights>Springer-Verlag GmbH Germany, part of Springer Nature 2018</rights><rights>Applied Nanoscience is a copyright of Springer, (2018). All Rights Reserved.</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c359t-394f8901dcd6c5a91449f0d261ef2a9f9af02f2df31cc726702530fd66eb32e03</citedby><cites>FETCH-LOGICAL-c359t-394f8901dcd6c5a91449f0d261ef2a9f9af02f2df31cc726702530fd66eb32e03</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s13204-018-0878-6$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s13204-018-0878-6$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,776,780,27903,27904,41467,42536,51298</link.rule.ids></links><search><creatorcontrib>Vasylechko, Volodymyr O.</creatorcontrib><creatorcontrib>Gryshchouk, Galyna V.</creatorcontrib><creatorcontrib>Kalychak, Yaroslav M.</creatorcontrib><creatorcontrib>Vasylechko, Leonid O.</creatorcontrib><creatorcontrib>Voloshinovskii, Anatoliy S.</creatorcontrib><creatorcontrib>Vistovskyy, Vitaliy V.</creatorcontrib><creatorcontrib>Tupys, Andrii M.</creatorcontrib><title>Sorption–luminescence method for determination of europium using acid-modified clinoptilolite</title><title>Applied nanoscience</title><addtitle>Appl Nanosci</addtitle><description>Sorption–luminescent method for europium determination based on the acid-modified Transcarpathian clinoptilolite without using toxic organic solvents was proposed. Optimal luminophore preparation condition is the sorption of Eu(III) on the precalcined at 400 °C H-clinoptilolite, in the solution with pH 9.5. The obtained H-clinoptilolite–Eu(III) sample, precalcined at 50 °C, was treated with 1,10-phenanthroline, atophan, and urotropine solutions. For luminescence excitation, the rays with wavelength of
λ
= 276 nm were used. Luminescence intensity at
λ
= 615 nm was selected as an analytical parameter for a europium quantitative determination. Linear calibration range of Eu(III) concentration with the detection limit of 3 ng mL
−1
is within 10–900 ng mL
−1
. The proposed method can be used for europium determination in the presence of many rare earths. Sorption–luminescent method can be applied for the determination of europium ions trace amounts in synthetic water solutions. The proposed analytical method gave recoveries from 95 to 102% and RSD from 3.5 to 7.9% during the determination of europium.</description><subject>Chemistry and Materials Science</subject><subject>Europium</subject><subject>Luminescence</subject><subject>Materials Science</subject><subject>Mathematical analysis</subject><subject>Membrane Biology</subject><subject>Nanochemistry</subject><subject>Nanotechnology</subject><subject>Nanotechnology and Microengineering</subject><subject>Original Article</subject><subject>Rare earth elements</subject><subject>Sorption</subject><issn>2190-5509</issn><issn>2190-5517</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2019</creationdate><recordtype>article</recordtype><sourceid>AFKRA</sourceid><sourceid>BENPR</sourceid><sourceid>CCPQU</sourceid><sourceid>DWQXO</sourceid><recordid>eNp1kMtKxDAUhoMoOOg8gLuA6-hJ0ibNUgZvMOBCXYeay5ihbcakXbjzHXxDn8QMFV15NjmQ7_8PfAidUbigAPIyU86gIkAbAo1siDhAC0YVkLqm8vB3B3WMljlvoUxdScHrBdKPMe3GEIevj89u6sPgsnGDcbh342u02MeErRtdKl_tnsPRYzeluAtTj6cchg1uTbCkjzb44Cw2XRhiqexiF0Z3io5822W3_HlP0PPN9dPqjqwfbu9XV2tieK1GwlXlGwXUGitM3SpaVcqDZYI6z1rlVeuBeWY9p8ZIJiSwmoO3QrgXzhzwE3Q-9-5SfJtcHvU2TmkoJzWjlFVMSS4LRWfKpJhzcl7vUujb9K4p6L1KPavURaXeq9SiZNicyYUdNi79Nf8f-gbPMXjx</recordid><startdate>20190701</startdate><enddate>20190701</enddate><creator>Vasylechko, Volodymyr O.</creator><creator>Gryshchouk, Galyna V.</creator><creator>Kalychak, Yaroslav M.</creator><creator>Vasylechko, Leonid O.</creator><creator>Voloshinovskii, Anatoliy S.</creator><creator>Vistovskyy, Vitaliy V.</creator><creator>Tupys, Andrii M.</creator><general>Springer International Publishing</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>8FE</scope><scope>8FG</scope><scope>ABJCF</scope><scope>AFKRA</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>DWQXO</scope><scope>HCIFZ</scope><scope>L6V</scope><scope>M7S</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>PRINS</scope><scope>PTHSS</scope></search><sort><creationdate>20190701</creationdate><title>Sorption–luminescence method for determination of europium using acid-modified clinoptilolite</title><author>Vasylechko, Volodymyr O. ; Gryshchouk, Galyna V. ; Kalychak, Yaroslav M. ; Vasylechko, Leonid O. ; Voloshinovskii, Anatoliy S. ; Vistovskyy, Vitaliy V. ; Tupys, Andrii M.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c359t-394f8901dcd6c5a91449f0d261ef2a9f9af02f2df31cc726702530fd66eb32e03</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2019</creationdate><topic>Chemistry and Materials Science</topic><topic>Europium</topic><topic>Luminescence</topic><topic>Materials Science</topic><topic>Mathematical analysis</topic><topic>Membrane Biology</topic><topic>Nanochemistry</topic><topic>Nanotechnology</topic><topic>Nanotechnology and Microengineering</topic><topic>Original Article</topic><topic>Rare earth elements</topic><topic>Sorption</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Vasylechko, Volodymyr O.</creatorcontrib><creatorcontrib>Gryshchouk, Galyna V.</creatorcontrib><creatorcontrib>Kalychak, Yaroslav M.</creatorcontrib><creatorcontrib>Vasylechko, Leonid O.</creatorcontrib><creatorcontrib>Voloshinovskii, Anatoliy S.</creatorcontrib><creatorcontrib>Vistovskyy, Vitaliy V.</creatorcontrib><creatorcontrib>Tupys, Andrii M.</creatorcontrib><collection>CrossRef</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>Materials Science & Engineering Collection</collection><collection>ProQuest Central UK/Ireland</collection><collection>ProQuest Central</collection><collection>Technology Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest Central Korea</collection><collection>SciTech Premium Collection</collection><collection>ProQuest Engineering Collection</collection><collection>Engineering Database</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>ProQuest Central China</collection><collection>Engineering Collection</collection><jtitle>Applied nanoscience</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Vasylechko, Volodymyr O.</au><au>Gryshchouk, Galyna V.</au><au>Kalychak, Yaroslav M.</au><au>Vasylechko, Leonid O.</au><au>Voloshinovskii, Anatoliy S.</au><au>Vistovskyy, Vitaliy V.</au><au>Tupys, Andrii M.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Sorption–luminescence method for determination of europium using acid-modified clinoptilolite</atitle><jtitle>Applied nanoscience</jtitle><stitle>Appl Nanosci</stitle><date>2019-07-01</date><risdate>2019</risdate><volume>9</volume><issue>5</issue><spage>1145</spage><epage>1153</epage><pages>1145-1153</pages><issn>2190-5509</issn><eissn>2190-5517</eissn><abstract>Sorption–luminescent method for europium determination based on the acid-modified Transcarpathian clinoptilolite without using toxic organic solvents was proposed. Optimal luminophore preparation condition is the sorption of Eu(III) on the precalcined at 400 °C H-clinoptilolite, in the solution with pH 9.5. The obtained H-clinoptilolite–Eu(III) sample, precalcined at 50 °C, was treated with 1,10-phenanthroline, atophan, and urotropine solutions. For luminescence excitation, the rays with wavelength of
λ
= 276 nm were used. Luminescence intensity at
λ
= 615 nm was selected as an analytical parameter for a europium quantitative determination. Linear calibration range of Eu(III) concentration with the detection limit of 3 ng mL
−1
is within 10–900 ng mL
−1
. The proposed method can be used for europium determination in the presence of many rare earths. Sorption–luminescent method can be applied for the determination of europium ions trace amounts in synthetic water solutions. The proposed analytical method gave recoveries from 95 to 102% and RSD from 3.5 to 7.9% during the determination of europium.</abstract><cop>Cham</cop><pub>Springer International Publishing</pub><doi>10.1007/s13204-018-0878-6</doi><tpages>9</tpages><oa>free_for_read</oa></addata></record> |
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| subjects | Chemistry and Materials Science Europium Luminescence Materials Science Mathematical analysis Membrane Biology Nanochemistry Nanotechnology Nanotechnology and Microengineering Original Article Rare earth elements Sorption |
| title | Sorption–luminescence method for determination of europium using acid-modified clinoptilolite |
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