The study of selectivity of 137Cs sorption by iron and nickel hexacyanoferrates
The possibility of treatment of liquid radioactive wastes containing 137Cs based on sorption on nickel and iron hexacyanoferrates was studied in this work. Centrifuging was recommended for separation of hexacyanoferrates from solution because of low particles size of these hexacyanoferrates. It was...
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creator | Semenishchev, V. S. Pyankov, A. A. |
description | The possibility of treatment of liquid radioactive wastes containing 137Cs based on sorption on nickel and iron hexacyanoferrates was studied in this work. Centrifuging was recommended for separation of hexacyanoferrates from solution because of low particles size of these hexacyanoferrates. It was shown that iron and nickel hexacyanoferrates allow separation of 137Cs from aqueous solutions at the pH range of 0.5–11.5 and at concentrations of sodium and potassium up to 2.5 mol/L with distribution coefficients as high as 104–105 mL/g. Thus, the studied hexacyanoferrates can be recommended for separation of 137Cs from difficult liquid radioactive wastes with high salt content and in a wide pH range. |
doi_str_mv | 10.1063/1.5055163 |
format | Conference Proceeding |
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S. ; Pyankov, A. A.</creator><contributor>Narkhov, Evgeniy D. ; Volkovich, Vladimir A. ; Zvonarev, Sergey V. ; Kashin, Ilya V.</contributor><creatorcontrib>Semenishchev, V. S. ; Pyankov, A. A. ; Narkhov, Evgeniy D. ; Volkovich, Vladimir A. ; Zvonarev, Sergey V. ; Kashin, Ilya V.</creatorcontrib><description>The possibility of treatment of liquid radioactive wastes containing 137Cs based on sorption on nickel and iron hexacyanoferrates was studied in this work. Centrifuging was recommended for separation of hexacyanoferrates from solution because of low particles size of these hexacyanoferrates. It was shown that iron and nickel hexacyanoferrates allow separation of 137Cs from aqueous solutions at the pH range of 0.5–11.5 and at concentrations of sodium and potassium up to 2.5 mol/L with distribution coefficients as high as 104–105 mL/g. Thus, the studied hexacyanoferrates can be recommended for separation of 137Cs from difficult liquid radioactive wastes with high salt content and in a wide pH range.</description><identifier>ISSN: 0094-243X</identifier><identifier>EISSN: 1551-7616</identifier><identifier>DOI: 10.1063/1.5055163</identifier><identifier>CODEN: APCPCS</identifier><language>eng</language><publisher>Melville: American Institute of Physics</publisher><subject>Cesium 137 ; Cesium isotopes ; Iron ; Nickel ; Radioactive wastes ; Separation ; Sorption</subject><ispartof>AIP conference proceedings, 2018, Vol.2015 (1)</ispartof><rights>Author(s)</rights><rights>2018 Author(s). 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A.</creatorcontrib><title>The study of selectivity of 137Cs sorption by iron and nickel hexacyanoferrates</title><title>AIP conference proceedings</title><description>The possibility of treatment of liquid radioactive wastes containing 137Cs based on sorption on nickel and iron hexacyanoferrates was studied in this work. Centrifuging was recommended for separation of hexacyanoferrates from solution because of low particles size of these hexacyanoferrates. It was shown that iron and nickel hexacyanoferrates allow separation of 137Cs from aqueous solutions at the pH range of 0.5–11.5 and at concentrations of sodium and potassium up to 2.5 mol/L with distribution coefficients as high as 104–105 mL/g. Thus, the studied hexacyanoferrates can be recommended for separation of 137Cs from difficult liquid radioactive wastes with high salt content and in a wide pH range.</description><subject>Cesium 137</subject><subject>Cesium isotopes</subject><subject>Iron</subject><subject>Nickel</subject><subject>Radioactive wastes</subject><subject>Separation</subject><subject>Sorption</subject><issn>0094-243X</issn><issn>1551-7616</issn><fulltext>true</fulltext><rsrctype>conference_proceeding</rsrctype><creationdate>2018</creationdate><recordtype>conference_proceeding</recordtype><recordid>eNp9kE1LxDAQhoMoWFcP_oOAN6FrpmmT9iiLX7Cwlz14C2k-2Ky1qUl2sf_errvgzdMzAw_vMC9Ct0DmQBh9gHlFqgoYPUMZTEPOGbBzlBHSlHlR0vdLdBXjlpCi4bzO0Gq9MTimnR6xtziazqjk9i79rkD5IuLow5Cc73E7Yhcmyl7j3qkP0-GN-ZZqlL23JgSZTLxGF1Z20dycOEPr56f14jVfrl7eFo_LfGhqm7Oika1W0GquqFTWWDqRlgw0N9JoTZmsZMl5VSvelk2pZcFboqjllnFV0Bm6O8YOwX_tTExi63ehny6KAgDqmnLSTNb90YrKJXn4QQzBfcowCiDi0JcAcerrP3nvw58oBm3pD6ORbGM</recordid><startdate>20180925</startdate><enddate>20180925</enddate><creator>Semenishchev, V. S.</creator><creator>Pyankov, A. A.</creator><general>American Institute of Physics</general><scope>8FD</scope><scope>H8D</scope><scope>L7M</scope></search><sort><creationdate>20180925</creationdate><title>The study of selectivity of 137Cs sorption by iron and nickel hexacyanoferrates</title><author>Semenishchev, V. S. ; Pyankov, A. A.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-p98f-629abdc1bd7c3acfef3c3a3461d7eaedd36a5a47758c7b494da27b0c3f7f67c23</frbrgroupid><rsrctype>conference_proceedings</rsrctype><prefilter>conference_proceedings</prefilter><language>eng</language><creationdate>2018</creationdate><topic>Cesium 137</topic><topic>Cesium isotopes</topic><topic>Iron</topic><topic>Nickel</topic><topic>Radioactive wastes</topic><topic>Separation</topic><topic>Sorption</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Semenishchev, V. S.</creatorcontrib><creatorcontrib>Pyankov, A. A.</creatorcontrib><collection>Technology Research Database</collection><collection>Aerospace Database</collection><collection>Advanced Technologies Database with Aerospace</collection></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Semenishchev, V. S.</au><au>Pyankov, A. A.</au><au>Narkhov, Evgeniy D.</au><au>Volkovich, Vladimir A.</au><au>Zvonarev, Sergey V.</au><au>Kashin, Ilya V.</au><format>book</format><genre>proceeding</genre><ristype>CONF</ristype><atitle>The study of selectivity of 137Cs sorption by iron and nickel hexacyanoferrates</atitle><btitle>AIP conference proceedings</btitle><date>2018-09-25</date><risdate>2018</risdate><volume>2015</volume><issue>1</issue><issn>0094-243X</issn><eissn>1551-7616</eissn><coden>APCPCS</coden><abstract>The possibility of treatment of liquid radioactive wastes containing 137Cs based on sorption on nickel and iron hexacyanoferrates was studied in this work. Centrifuging was recommended for separation of hexacyanoferrates from solution because of low particles size of these hexacyanoferrates. It was shown that iron and nickel hexacyanoferrates allow separation of 137Cs from aqueous solutions at the pH range of 0.5–11.5 and at concentrations of sodium and potassium up to 2.5 mol/L with distribution coefficients as high as 104–105 mL/g. Thus, the studied hexacyanoferrates can be recommended for separation of 137Cs from difficult liquid radioactive wastes with high salt content and in a wide pH range.</abstract><cop>Melville</cop><pub>American Institute of Physics</pub><doi>10.1063/1.5055163</doi><tpages>5</tpages></addata></record> |
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subjects | Cesium 137 Cesium isotopes Iron Nickel Radioactive wastes Separation Sorption |
title | The study of selectivity of 137Cs sorption by iron and nickel hexacyanoferrates |
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