A novel porous carbon material made from wild rice stem and its application in supercapacitors
Nowadays, it is known that activated porous carbon materials behave high specific capacitance owing to their high specific surface area, microporous and mesoporous structures. Therefore, the carbon materials with low cost and good cycle stability become one of the most promising electrode materials...
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Veröffentlicht in: | Materials chemistry and physics 2018-07, Vol.213, p.267-276 |
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creator | Tian, Qiang Wang, Xiaoxue Xu, Xiaoyang Zhang, Man Wang, Luyao Zhao, Xiaoxiang An, Zhaolin Yao, Hongduo Gao, Jianping |
description | Nowadays, it is known that activated porous carbon materials behave high specific capacitance owing to their high specific surface area, microporous and mesoporous structures. Therefore, the carbon materials with low cost and good cycle stability become one of the most promising electrode materials in supercapacitors. In this paper, the carbon material prepared by the carbonization of wild rice stem and the alkali activation possesses high specific surface area up to 1228 m2/g, which makes it more hopeful application prospects in electrochemical field. The results indicate that activation temperature and alkali concentration play important roles in improving the performance of specific capacitance of the activated carbon. The activated porous carbon prepared at 800 °C with a KOH/wild rice stem mass ratio of 3 shows the best performance and displays a specific capacitance of 301 F/g at current density of 1 A/g in a three-electrode configuration. Furthermore, the assembled symmetric supercapacitor attains a high energy density of 13.05 Wh/kg at the power density of 250 W/kg in 6 M KOH electrolyte. So the activated porous carbon made from wild rice stem is a low-cost, eco-friendly and high performance material for supercapacitors.
[Display omitted]
•Wild rice stem was converted into activated porous carbon for electrode materials.•The porous carbon possesses high specific surface area and abundant pore distribution.•The highest specific capacitance of activated porous carbon is as high as 301 F/g at current density of 1 A/g.•The supercapacitor exhibits excellent rate performance and cycling stability. |
doi_str_mv | 10.1016/j.matchemphys.2018.04.026 |
format | Article |
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[Display omitted]
•Wild rice stem was converted into activated porous carbon for electrode materials.•The porous carbon possesses high specific surface area and abundant pore distribution.•The highest specific capacitance of activated porous carbon is as high as 301 F/g at current density of 1 A/g.•The supercapacitor exhibits excellent rate performance and cycling stability.</description><identifier>ISSN: 0254-0584</identifier><identifier>EISSN: 1879-3312</identifier><identifier>DOI: 10.1016/j.matchemphys.2018.04.026</identifier><language>eng</language><publisher>Lausanne: Elsevier B.V</publisher><subject>Activated carbon ; Activated porous carbon ; Activation ; Capacitance ; Carbonization ; Density ; Electrode materials ; Electrodes ; Flux density ; Low cost ; Porous materials ; Specific surface ; Supercapacitor ; Supercapacitors ; Surface area ; Wild rice stem</subject><ispartof>Materials chemistry and physics, 2018-07, Vol.213, p.267-276</ispartof><rights>2018</rights><rights>Copyright Elsevier BV Jul 1, 2018</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c400t-b46d63a1cef9c44daf914125c2df0544c1339eb8d653ea13c0de446ce9f102fd3</citedby><cites>FETCH-LOGICAL-c400t-b46d63a1cef9c44daf914125c2df0544c1339eb8d653ea13c0de446ce9f102fd3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://www.sciencedirect.com/science/article/pii/S0254058418302888$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>314,776,780,3537,27901,27902,65306</link.rule.ids></links><search><creatorcontrib>Tian, Qiang</creatorcontrib><creatorcontrib>Wang, Xiaoxue</creatorcontrib><creatorcontrib>Xu, Xiaoyang</creatorcontrib><creatorcontrib>Zhang, Man</creatorcontrib><creatorcontrib>Wang, Luyao</creatorcontrib><creatorcontrib>Zhao, Xiaoxiang</creatorcontrib><creatorcontrib>An, Zhaolin</creatorcontrib><creatorcontrib>Yao, Hongduo</creatorcontrib><creatorcontrib>Gao, Jianping</creatorcontrib><title>A novel porous carbon material made from wild rice stem and its application in supercapacitors</title><title>Materials chemistry and physics</title><description>Nowadays, it is known that activated porous carbon materials behave high specific capacitance owing to their high specific surface area, microporous and mesoporous structures. Therefore, the carbon materials with low cost and good cycle stability become one of the most promising electrode materials in supercapacitors. In this paper, the carbon material prepared by the carbonization of wild rice stem and the alkali activation possesses high specific surface area up to 1228 m2/g, which makes it more hopeful application prospects in electrochemical field. The results indicate that activation temperature and alkali concentration play important roles in improving the performance of specific capacitance of the activated carbon. The activated porous carbon prepared at 800 °C with a KOH/wild rice stem mass ratio of 3 shows the best performance and displays a specific capacitance of 301 F/g at current density of 1 A/g in a three-electrode configuration. Furthermore, the assembled symmetric supercapacitor attains a high energy density of 13.05 Wh/kg at the power density of 250 W/kg in 6 M KOH electrolyte. So the activated porous carbon made from wild rice stem is a low-cost, eco-friendly and high performance material for supercapacitors.
[Display omitted]
•Wild rice stem was converted into activated porous carbon for electrode materials.•The porous carbon possesses high specific surface area and abundant pore distribution.•The highest specific capacitance of activated porous carbon is as high as 301 F/g at current density of 1 A/g.•The supercapacitor exhibits excellent rate performance and cycling stability.</description><subject>Activated carbon</subject><subject>Activated porous carbon</subject><subject>Activation</subject><subject>Capacitance</subject><subject>Carbonization</subject><subject>Density</subject><subject>Electrode materials</subject><subject>Electrodes</subject><subject>Flux density</subject><subject>Low cost</subject><subject>Porous materials</subject><subject>Specific surface</subject><subject>Supercapacitor</subject><subject>Supercapacitors</subject><subject>Surface area</subject><subject>Wild rice stem</subject><issn>0254-0584</issn><issn>1879-3312</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2018</creationdate><recordtype>article</recordtype><recordid>eNqNkE1PwzAMhiMEEmPwH4I4t9hN2rVHNPElIXGBK1HmuFqmtilJB-LfUzQOHDnZh_d5LT9CXCLkCFhd7_LeTrTlftx-pbwArHPQORTVkVhgvWoypbA4FgsoSp1BWetTcZbSDgBXiGoh3m7kED64k2OIYZ8k2bgJg5xLOXrbzYtj2cbQy0_fORk9sUwT99IOTvopSTuOnSc7-Znyg0z7kSPZ0ZKfQkzn4qS1XeKL37kUr3e3L-uH7On5_nF985SRBpiyja5cpSwStw1p7WzboMaipMK1UGpNqFTDm9pVpWKLisCx1hVx0yIUrVNLcXXoHWN433OazC7s4zCfNAVCXVcKVT2nmkOKYkgpcmvG6HsbvwyC-dFpduaPTvOj04A2s86ZXR9Ynt_48BxNIs8DsfORaTIu-H-0fAMzooXa</recordid><startdate>20180701</startdate><enddate>20180701</enddate><creator>Tian, Qiang</creator><creator>Wang, Xiaoxue</creator><creator>Xu, Xiaoyang</creator><creator>Zhang, Man</creator><creator>Wang, Luyao</creator><creator>Zhao, Xiaoxiang</creator><creator>An, Zhaolin</creator><creator>Yao, Hongduo</creator><creator>Gao, Jianping</creator><general>Elsevier B.V</general><general>Elsevier BV</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope></search><sort><creationdate>20180701</creationdate><title>A novel porous carbon material made from wild rice stem and its application in supercapacitors</title><author>Tian, Qiang ; Wang, Xiaoxue ; Xu, Xiaoyang ; Zhang, Man ; Wang, Luyao ; Zhao, Xiaoxiang ; An, Zhaolin ; Yao, Hongduo ; Gao, Jianping</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c400t-b46d63a1cef9c44daf914125c2df0544c1339eb8d653ea13c0de446ce9f102fd3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2018</creationdate><topic>Activated carbon</topic><topic>Activated porous carbon</topic><topic>Activation</topic><topic>Capacitance</topic><topic>Carbonization</topic><topic>Density</topic><topic>Electrode materials</topic><topic>Electrodes</topic><topic>Flux density</topic><topic>Low cost</topic><topic>Porous materials</topic><topic>Specific surface</topic><topic>Supercapacitor</topic><topic>Supercapacitors</topic><topic>Surface area</topic><topic>Wild rice stem</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Tian, Qiang</creatorcontrib><creatorcontrib>Wang, Xiaoxue</creatorcontrib><creatorcontrib>Xu, Xiaoyang</creatorcontrib><creatorcontrib>Zhang, Man</creatorcontrib><creatorcontrib>Wang, Luyao</creatorcontrib><creatorcontrib>Zhao, Xiaoxiang</creatorcontrib><creatorcontrib>An, Zhaolin</creatorcontrib><creatorcontrib>Yao, Hongduo</creatorcontrib><creatorcontrib>Gao, Jianping</creatorcontrib><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Materials chemistry and physics</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Tian, Qiang</au><au>Wang, Xiaoxue</au><au>Xu, Xiaoyang</au><au>Zhang, Man</au><au>Wang, Luyao</au><au>Zhao, Xiaoxiang</au><au>An, Zhaolin</au><au>Yao, Hongduo</au><au>Gao, Jianping</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>A novel porous carbon material made from wild rice stem and its application in supercapacitors</atitle><jtitle>Materials chemistry and physics</jtitle><date>2018-07-01</date><risdate>2018</risdate><volume>213</volume><spage>267</spage><epage>276</epage><pages>267-276</pages><issn>0254-0584</issn><eissn>1879-3312</eissn><abstract>Nowadays, it is known that activated porous carbon materials behave high specific capacitance owing to their high specific surface area, microporous and mesoporous structures. Therefore, the carbon materials with low cost and good cycle stability become one of the most promising electrode materials in supercapacitors. In this paper, the carbon material prepared by the carbonization of wild rice stem and the alkali activation possesses high specific surface area up to 1228 m2/g, which makes it more hopeful application prospects in electrochemical field. The results indicate that activation temperature and alkali concentration play important roles in improving the performance of specific capacitance of the activated carbon. The activated porous carbon prepared at 800 °C with a KOH/wild rice stem mass ratio of 3 shows the best performance and displays a specific capacitance of 301 F/g at current density of 1 A/g in a three-electrode configuration. Furthermore, the assembled symmetric supercapacitor attains a high energy density of 13.05 Wh/kg at the power density of 250 W/kg in 6 M KOH electrolyte. So the activated porous carbon made from wild rice stem is a low-cost, eco-friendly and high performance material for supercapacitors.
[Display omitted]
•Wild rice stem was converted into activated porous carbon for electrode materials.•The porous carbon possesses high specific surface area and abundant pore distribution.•The highest specific capacitance of activated porous carbon is as high as 301 F/g at current density of 1 A/g.•The supercapacitor exhibits excellent rate performance and cycling stability.</abstract><cop>Lausanne</cop><pub>Elsevier B.V</pub><doi>10.1016/j.matchemphys.2018.04.026</doi><tpages>10</tpages><oa>free_for_read</oa></addata></record> |
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subjects | Activated carbon Activated porous carbon Activation Capacitance Carbonization Density Electrode materials Electrodes Flux density Low cost Porous materials Specific surface Supercapacitor Supercapacitors Surface area Wild rice stem |
title | A novel porous carbon material made from wild rice stem and its application in supercapacitors |
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