Correlation of intergranular corrosion behaviour with microstructure in Al-Cu-Li alloy

•Increasing ageing temperature and predeformation caused acceleration in the evolution of corrosion mode.•The corrosion mode in AA1460 evolved from intergranular to intragranular.•The precipitation of δ′(Al3Li) and T1 (Al2CuLi) in AA1460 resulted in a lower value of open circuit potential.•A relatio...

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Veröffentlicht in:Corrosion science 2018-07, Vol.139, p.215-226
Hauptverfasser: Huang, Jia-lei, Li, Jin-feng, Liu, Dan-yang, Zhang, Rui-feng, Chen, Yong-lai, Zhang, Xu-hu, Ma, Peng-cheng, Gupta, Rajeev Kumar, Birbilis, Nick
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container_end_page 226
container_issue
container_start_page 215
container_title Corrosion science
container_volume 139
creator Huang, Jia-lei
Li, Jin-feng
Liu, Dan-yang
Zhang, Rui-feng
Chen, Yong-lai
Zhang, Xu-hu
Ma, Peng-cheng
Gupta, Rajeev Kumar
Birbilis, Nick
description •Increasing ageing temperature and predeformation caused acceleration in the evolution of corrosion mode.•The corrosion mode in AA1460 evolved from intergranular to intragranular.•The precipitation of δ′(Al3Li) and T1 (Al2CuLi) in AA1460 resulted in a lower value of open circuit potential.•A relationship between open circuit potential and corrosion mode was presented. The IGC behaviour, OCP and microstructure of AA1460 (Al-3.12Cu-2.14Li-0.12Sc-0.12Zr, in wt.%), following HT1 (heat treatment without predeformation) and HT2 (heat treatment with predeformation) tempers were investigated. Both δ′ (Al3Li) and T1 (Al2CuLi) phases were precipitated within grains during heat treatment, while T1 phase also precipitated in the vicinity of grain boundaries. The evolution of inter- and intra-granular microstructures in AA1460 influenced the local and global electrochemical characteristics, which in turn influenced the temper dependent corrosion morphologies of AA1460. A correlation between OCP and corrosion mode was proposed, which may be used to compare the IGC sensitivity of AA1460 with different tempers.
doi_str_mv 10.1016/j.corsci.2018.05.011
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source ScienceDirect Journals (5 years ago - present)
subjects Aluminium
Aluminum alloys
Aluminum base alloys
Circuits
Copper
Corrosion
Grain boundaries
Heat treating
Heat treatment
Intergranular corrosion
Intergranular corrosion (IGC)
Microstructure
Morphology
Open circuit potential (OCP)
Predeformation
TEM
title Correlation of intergranular corrosion behaviour with microstructure in Al-Cu-Li alloy
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