Feasibility Study on the Utilization of Serpentine Residues for Mg(OH)2 Production
Serpentinite tailings from La Nationale chrysotile mine in Thetford Mines (Quebec, Canada) were studied to extract the Mg contained therein. The study began with an initial chemical characterization of the residue to determine the Mg concentration in the different grain size fractions. The resulting...
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Veröffentlicht in: | Waste and biomass valorization 2018-10, Vol.9 (10), p.1921-1933 |
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creator | Sierra, C. Chouinard, S. Pasquier, L. C. Mercier, G. Blais, J. F. |
description | Serpentinite tailings from
La Nationale
chrysotile mine in Thetford Mines (Quebec, Canada) were studied to extract the Mg contained therein. The study began with an initial chemical characterization of the residue to determine the Mg concentration in the different grain size fractions. The resulting Mg-containing fractions were leached under a variety of parameters such as type of acid, acid concentration, treatment time, and temperature, and the obtained solution was neutralized with NaOH for the selective recovery of the metals. The results of this study were used to design a process to obtain Mg as a marketable chemical. The tested process consists of a leaching step using an H
2
SO
4
solution followed by the purification of the leachates using NaOH at pH 8 and Mg recovery with NaOH at pH 10. A final product composed of mirabilite (Na
2
SO
4
) and brucite (Mg(OH)
2
) was obtained. The procedure was tested, and its economic viability was discussed. The approach proved to be technically feasible, promoting clean production. |
doi_str_mv | 10.1007/s12649-017-9926-9 |
format | Article |
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La Nationale
chrysotile mine in Thetford Mines (Quebec, Canada) were studied to extract the Mg contained therein. The study began with an initial chemical characterization of the residue to determine the Mg concentration in the different grain size fractions. The resulting Mg-containing fractions were leached under a variety of parameters such as type of acid, acid concentration, treatment time, and temperature, and the obtained solution was neutralized with NaOH for the selective recovery of the metals. The results of this study were used to design a process to obtain Mg as a marketable chemical. The tested process consists of a leaching step using an H
2
SO
4
solution followed by the purification of the leachates using NaOH at pH 8 and Mg recovery with NaOH at pH 10. A final product composed of mirabilite (Na
2
SO
4
) and brucite (Mg(OH)
2
) was obtained. The procedure was tested, and its economic viability was discussed. The approach proved to be technically feasible, promoting clean production.</description><identifier>ISSN: 1877-2641</identifier><identifier>EISSN: 1877-265X</identifier><identifier>DOI: 10.1007/s12649-017-9926-9</identifier><language>eng</language><publisher>Dordrecht: Springer Netherlands</publisher><subject>Brucite ; Chrysotile ; Economic conditions ; Engineering ; Environment ; Environmental Engineering/Biotechnology ; Feasibility studies ; Industrial Pollution Prevention ; Leachates ; Leaching ; Magnesium hydroxide ; Materials recovery ; Metals ; Mine tailings ; Organic chemistry ; Original Paper ; pH effects ; Purification ; Renewable and Green Energy ; Serpentine ; Sodium hydroxide ; Sodium sulfate ; Sulfuric acid ; Viability ; Waste Management/Waste Technology</subject><ispartof>Waste and biomass valorization, 2018-10, Vol.9 (10), p.1921-1933</ispartof><rights>Springer Science+Business Media Dordrecht 2017</rights><rights>Copyright Springer Science & Business Media 2018</rights><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c396t-e0155b20ecf65bbfafc3e94b67029c2a3aeabe5ad56b8f92ea3fb878eb6ea4393</citedby><cites>FETCH-LOGICAL-c396t-e0155b20ecf65bbfafc3e94b67029c2a3aeabe5ad56b8f92ea3fb878eb6ea4393</cites><orcidid>0000-0002-7155-3257</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s12649-017-9926-9$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s12649-017-9926-9$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,776,780,27901,27902,41464,42533,51294</link.rule.ids></links><search><creatorcontrib>Sierra, C.</creatorcontrib><creatorcontrib>Chouinard, S.</creatorcontrib><creatorcontrib>Pasquier, L. C.</creatorcontrib><creatorcontrib>Mercier, G.</creatorcontrib><creatorcontrib>Blais, J. F.</creatorcontrib><title>Feasibility Study on the Utilization of Serpentine Residues for Mg(OH)2 Production</title><title>Waste and biomass valorization</title><addtitle>Waste Biomass Valor</addtitle><description>Serpentinite tailings from
La Nationale
chrysotile mine in Thetford Mines (Quebec, Canada) were studied to extract the Mg contained therein. The study began with an initial chemical characterization of the residue to determine the Mg concentration in the different grain size fractions. The resulting Mg-containing fractions were leached under a variety of parameters such as type of acid, acid concentration, treatment time, and temperature, and the obtained solution was neutralized with NaOH for the selective recovery of the metals. The results of this study were used to design a process to obtain Mg as a marketable chemical. The tested process consists of a leaching step using an H
2
SO
4
solution followed by the purification of the leachates using NaOH at pH 8 and Mg recovery with NaOH at pH 10. A final product composed of mirabilite (Na
2
SO
4
) and brucite (Mg(OH)
2
) was obtained. The procedure was tested, and its economic viability was discussed. The approach proved to be technically feasible, promoting clean production.</description><subject>Brucite</subject><subject>Chrysotile</subject><subject>Economic conditions</subject><subject>Engineering</subject><subject>Environment</subject><subject>Environmental Engineering/Biotechnology</subject><subject>Feasibility studies</subject><subject>Industrial Pollution Prevention</subject><subject>Leachates</subject><subject>Leaching</subject><subject>Magnesium hydroxide</subject><subject>Materials recovery</subject><subject>Metals</subject><subject>Mine tailings</subject><subject>Organic chemistry</subject><subject>Original Paper</subject><subject>pH effects</subject><subject>Purification</subject><subject>Renewable and Green Energy</subject><subject>Serpentine</subject><subject>Sodium hydroxide</subject><subject>Sodium sulfate</subject><subject>Sulfuric acid</subject><subject>Viability</subject><subject>Waste Management/Waste Technology</subject><issn>1877-2641</issn><issn>1877-265X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2018</creationdate><recordtype>article</recordtype><recordid>eNp1kE1Lw0AQhhdRsNT-AG8LXvQQ3Y9kkz1KsVaoVFoL3pbdZLam1KTubg7117shoieZw3zwzjvDg9AlJbeUkPzOUyZSmRCaJ1IykcgTNKJFnidMZG-nv3VKz9HE-x0hhFFaMJ6P0GoG2tem3tfhiNehq464bXB4B7wJcfilQx371uI1uAM0oW4Ar8DXVQce29bh5-31cn7D8Itrq67s1RfozOq9h8lPHqPN7OF1Ok8Wy8en6f0iKbkUIQFCs8wwAqUVmTFW25KDTI3ICZMl01yDNpDpKhOmsJKB5tYUeQFGgE655GN0NfgeXPsZ3wlq13auiScVo4THEIRGFR1UpWu9d2DVwdUf2h0VJaqnpwZ6KtJTPT3VO7Nhx0dtswX35_z_0jeDzHLF</recordid><startdate>20181001</startdate><enddate>20181001</enddate><creator>Sierra, C.</creator><creator>Chouinard, S.</creator><creator>Pasquier, L. C.</creator><creator>Mercier, G.</creator><creator>Blais, J. F.</creator><general>Springer Netherlands</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><orcidid>https://orcid.org/0000-0002-7155-3257</orcidid></search><sort><creationdate>20181001</creationdate><title>Feasibility Study on the Utilization of Serpentine Residues for Mg(OH)2 Production</title><author>Sierra, C. ; Chouinard, S. ; Pasquier, L. C. ; Mercier, G. ; Blais, J. F.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c396t-e0155b20ecf65bbfafc3e94b67029c2a3aeabe5ad56b8f92ea3fb878eb6ea4393</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2018</creationdate><topic>Brucite</topic><topic>Chrysotile</topic><topic>Economic conditions</topic><topic>Engineering</topic><topic>Environment</topic><topic>Environmental Engineering/Biotechnology</topic><topic>Feasibility studies</topic><topic>Industrial Pollution Prevention</topic><topic>Leachates</topic><topic>Leaching</topic><topic>Magnesium hydroxide</topic><topic>Materials recovery</topic><topic>Metals</topic><topic>Mine tailings</topic><topic>Organic chemistry</topic><topic>Original Paper</topic><topic>pH effects</topic><topic>Purification</topic><topic>Renewable and Green Energy</topic><topic>Serpentine</topic><topic>Sodium hydroxide</topic><topic>Sodium sulfate</topic><topic>Sulfuric acid</topic><topic>Viability</topic><topic>Waste Management/Waste Technology</topic><toplevel>online_resources</toplevel><creatorcontrib>Sierra, C.</creatorcontrib><creatorcontrib>Chouinard, S.</creatorcontrib><creatorcontrib>Pasquier, L. C.</creatorcontrib><creatorcontrib>Mercier, G.</creatorcontrib><creatorcontrib>Blais, J. F.</creatorcontrib><collection>CrossRef</collection><jtitle>Waste and biomass valorization</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Sierra, C.</au><au>Chouinard, S.</au><au>Pasquier, L. C.</au><au>Mercier, G.</au><au>Blais, J. F.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Feasibility Study on the Utilization of Serpentine Residues for Mg(OH)2 Production</atitle><jtitle>Waste and biomass valorization</jtitle><stitle>Waste Biomass Valor</stitle><date>2018-10-01</date><risdate>2018</risdate><volume>9</volume><issue>10</issue><spage>1921</spage><epage>1933</epage><pages>1921-1933</pages><issn>1877-2641</issn><eissn>1877-265X</eissn><abstract>Serpentinite tailings from
La Nationale
chrysotile mine in Thetford Mines (Quebec, Canada) were studied to extract the Mg contained therein. The study began with an initial chemical characterization of the residue to determine the Mg concentration in the different grain size fractions. The resulting Mg-containing fractions were leached under a variety of parameters such as type of acid, acid concentration, treatment time, and temperature, and the obtained solution was neutralized with NaOH for the selective recovery of the metals. The results of this study were used to design a process to obtain Mg as a marketable chemical. The tested process consists of a leaching step using an H
2
SO
4
solution followed by the purification of the leachates using NaOH at pH 8 and Mg recovery with NaOH at pH 10. A final product composed of mirabilite (Na
2
SO
4
) and brucite (Mg(OH)
2
) was obtained. The procedure was tested, and its economic viability was discussed. The approach proved to be technically feasible, promoting clean production.</abstract><cop>Dordrecht</cop><pub>Springer Netherlands</pub><doi>10.1007/s12649-017-9926-9</doi><tpages>13</tpages><orcidid>https://orcid.org/0000-0002-7155-3257</orcidid><oa>free_for_read</oa></addata></record> |
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subjects | Brucite Chrysotile Economic conditions Engineering Environment Environmental Engineering/Biotechnology Feasibility studies Industrial Pollution Prevention Leachates Leaching Magnesium hydroxide Materials recovery Metals Mine tailings Organic chemistry Original Paper pH effects Purification Renewable and Green Energy Serpentine Sodium hydroxide Sodium sulfate Sulfuric acid Viability Waste Management/Waste Technology |
title | Feasibility Study on the Utilization of Serpentine Residues for Mg(OH)2 Production |
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