Structural and spectroscopic investigations on the crystallization of uranium brannerite phases in glass
Brannerite‐based glass‐ceramics with relatively high actinide waste loadings are potential waste forms for the immobilization of actinide‐rich radioactive wastes containing process chemicals. In this work, the crystallization of pentavalent uranium brannerite phases in glass with the incorporation o...
Gespeichert in:
| Veröffentlicht in: | Journal of the American Ceramic Society 2018-11, Vol.101 (11), p.5219-5228 |
|---|---|
| Hauptverfasser: | , , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 5228 |
|---|---|
| container_issue | 11 |
| container_start_page | 5219 |
| container_title | Journal of the American Ceramic Society |
| container_volume | 101 |
| creator | Zhang, Yingjie Karatchevtseva, Inna Kong, Linggen Wei, Tao Zhang, Zhaoming |
| description | Brannerite‐based glass‐ceramics with relatively high actinide waste loadings are potential waste forms for the immobilization of actinide‐rich radioactive wastes containing process chemicals. In this work, the crystallization of pentavalent uranium brannerite phases in glass with the incorporation of yttrium/cerium/europium has been investigated. The formation of brannerite phases in glass has been confirmed with X‐ray diffraction and Raman spectroscopy. The evolution of microstructures and the development of micro pores in brannerite phases have been revealed by scanning electron microscopy with the nominal formula, Y0.51U0.49Ti2O6, Ce0.65U0.35Ti2O6, and Eu0.53U0.47Ti2O6, being determined with energy‐dispersive spectroscopy. The presence of dominant U5+ species has been proven with both diffuse reflectance spectroscopy and X‐ray absorption near‐edge spectroscopy. In addition, the systematic Raman band shifts with the mean cation radius in the studied brannerite series have been observed and discussed.
The crystallization of uranium brannerite phases in glass with the incorporation of Y‐Ce‐Eu has been investigated. |
| doi_str_mv | 10.1111/jace.15750 |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_journals_2100359440</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>2100359440</sourcerecordid><originalsourceid>FETCH-LOGICAL-c3010-14d57f2c77acb8235aceef56cc52e761c378a49e599c94887885cb86386b38973</originalsourceid><addsrcrecordid>eNp9kMtKAzEUhoMoWKsbnyDgTpiay2SSLEupVSm4UNchTTNtynQyJhmlPr1px7Vn83MO37n9ANxiNME5Hnba2AlmnKEzMMKM4YJIXJ2DEUKIFFwQdAmuYtzlFEtRjsD2LYXepD7oBup2DWNnTQo-Gt85A137ZWNyG52cbyP0LUxbC004xKSbxv2c6tDXMPe3rt_DVdbWBpcs7LY62phHwE2jY7wGF7Vuor350zH4eJy_z56K5evieTZdFoYijApcrhmvieFcm5UglOWHbM0qYxixvMKGcqFLaZmURpZCcCFYBisqqhUVktMxuBvmdsF_9vl6tfN9aPNKRTBClMmyRJm6HyiTf43B1qoLbq_DQWGkjk6qo5Pq5GSG8QB_u8Ye_iHVy3Q2H3p-AUf0d4Y</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2100359440</pqid></control><display><type>article</type><title>Structural and spectroscopic investigations on the crystallization of uranium brannerite phases in glass</title><source>Wiley Online Library Journals Frontfile Complete</source><creator>Zhang, Yingjie ; Karatchevtseva, Inna ; Kong, Linggen ; Wei, Tao ; Zhang, Zhaoming</creator><creatorcontrib>Zhang, Yingjie ; Karatchevtseva, Inna ; Kong, Linggen ; Wei, Tao ; Zhang, Zhaoming</creatorcontrib><description>Brannerite‐based glass‐ceramics with relatively high actinide waste loadings are potential waste forms for the immobilization of actinide‐rich radioactive wastes containing process chemicals. In this work, the crystallization of pentavalent uranium brannerite phases in glass with the incorporation of yttrium/cerium/europium has been investigated. The formation of brannerite phases in glass has been confirmed with X‐ray diffraction and Raman spectroscopy. The evolution of microstructures and the development of micro pores in brannerite phases have been revealed by scanning electron microscopy with the nominal formula, Y0.51U0.49Ti2O6, Ce0.65U0.35Ti2O6, and Eu0.53U0.47Ti2O6, being determined with energy‐dispersive spectroscopy. The presence of dominant U5+ species has been proven with both diffuse reflectance spectroscopy and X‐ray absorption near‐edge spectroscopy. In addition, the systematic Raman band shifts with the mean cation radius in the studied brannerite series have been observed and discussed.
The crystallization of uranium brannerite phases in glass with the incorporation of Y‐Ce‐Eu has been investigated.</description><identifier>ISSN: 0002-7820</identifier><identifier>EISSN: 1551-2916</identifier><identifier>DOI: 10.1111/jace.15750</identifier><language>eng</language><publisher>Columbus: Wiley Subscription Services, Inc</publisher><subject>Cerium ; Crystallization ; Diffuse reflectance spectroscopy ; Europium ; Glass ; glass‐ceramics ; Organic chemistry ; Phases ; radioactive waste ; Radioactive wastes ; Raman spectroscopy ; Scanning electron microscopy ; Spectrum analysis ; titanates ; Uranium ; uranium/uranium compounds ; X-ray diffraction ; Yttrium</subject><ispartof>Journal of the American Ceramic Society, 2018-11, Vol.101 (11), p.5219-5228</ispartof><rights>2018 The American Ceramic Society</rights><rights>2018 American Ceramic Society</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c3010-14d57f2c77acb8235aceef56cc52e761c378a49e599c94887885cb86386b38973</citedby><cites>FETCH-LOGICAL-c3010-14d57f2c77acb8235aceef56cc52e761c378a49e599c94887885cb86386b38973</cites><orcidid>0000-0001-6321-4696</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1111%2Fjace.15750$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1111%2Fjace.15750$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,776,780,1411,27901,27902,45550,45551</link.rule.ids></links><search><creatorcontrib>Zhang, Yingjie</creatorcontrib><creatorcontrib>Karatchevtseva, Inna</creatorcontrib><creatorcontrib>Kong, Linggen</creatorcontrib><creatorcontrib>Wei, Tao</creatorcontrib><creatorcontrib>Zhang, Zhaoming</creatorcontrib><title>Structural and spectroscopic investigations on the crystallization of uranium brannerite phases in glass</title><title>Journal of the American Ceramic Society</title><description>Brannerite‐based glass‐ceramics with relatively high actinide waste loadings are potential waste forms for the immobilization of actinide‐rich radioactive wastes containing process chemicals. In this work, the crystallization of pentavalent uranium brannerite phases in glass with the incorporation of yttrium/cerium/europium has been investigated. The formation of brannerite phases in glass has been confirmed with X‐ray diffraction and Raman spectroscopy. The evolution of microstructures and the development of micro pores in brannerite phases have been revealed by scanning electron microscopy with the nominal formula, Y0.51U0.49Ti2O6, Ce0.65U0.35Ti2O6, and Eu0.53U0.47Ti2O6, being determined with energy‐dispersive spectroscopy. The presence of dominant U5+ species has been proven with both diffuse reflectance spectroscopy and X‐ray absorption near‐edge spectroscopy. In addition, the systematic Raman band shifts with the mean cation radius in the studied brannerite series have been observed and discussed.
The crystallization of uranium brannerite phases in glass with the incorporation of Y‐Ce‐Eu has been investigated.</description><subject>Cerium</subject><subject>Crystallization</subject><subject>Diffuse reflectance spectroscopy</subject><subject>Europium</subject><subject>Glass</subject><subject>glass‐ceramics</subject><subject>Organic chemistry</subject><subject>Phases</subject><subject>radioactive waste</subject><subject>Radioactive wastes</subject><subject>Raman spectroscopy</subject><subject>Scanning electron microscopy</subject><subject>Spectrum analysis</subject><subject>titanates</subject><subject>Uranium</subject><subject>uranium/uranium compounds</subject><subject>X-ray diffraction</subject><subject>Yttrium</subject><issn>0002-7820</issn><issn>1551-2916</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2018</creationdate><recordtype>article</recordtype><recordid>eNp9kMtKAzEUhoMoWKsbnyDgTpiay2SSLEupVSm4UNchTTNtynQyJhmlPr1px7Vn83MO37n9ANxiNME5Hnba2AlmnKEzMMKM4YJIXJ2DEUKIFFwQdAmuYtzlFEtRjsD2LYXepD7oBup2DWNnTQo-Gt85A137ZWNyG52cbyP0LUxbC004xKSbxv2c6tDXMPe3rt_DVdbWBpcs7LY62phHwE2jY7wGF7Vuor350zH4eJy_z56K5evieTZdFoYijApcrhmvieFcm5UglOWHbM0qYxixvMKGcqFLaZmURpZCcCFYBisqqhUVktMxuBvmdsF_9vl6tfN9aPNKRTBClMmyRJm6HyiTf43B1qoLbq_DQWGkjk6qo5Pq5GSG8QB_u8Ye_iHVy3Q2H3p-AUf0d4Y</recordid><startdate>201811</startdate><enddate>201811</enddate><creator>Zhang, Yingjie</creator><creator>Karatchevtseva, Inna</creator><creator>Kong, Linggen</creator><creator>Wei, Tao</creator><creator>Zhang, Zhaoming</creator><general>Wiley Subscription Services, Inc</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7QQ</scope><scope>7SR</scope><scope>8FD</scope><scope>JG9</scope><orcidid>https://orcid.org/0000-0001-6321-4696</orcidid></search><sort><creationdate>201811</creationdate><title>Structural and spectroscopic investigations on the crystallization of uranium brannerite phases in glass</title><author>Zhang, Yingjie ; Karatchevtseva, Inna ; Kong, Linggen ; Wei, Tao ; Zhang, Zhaoming</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c3010-14d57f2c77acb8235aceef56cc52e761c378a49e599c94887885cb86386b38973</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2018</creationdate><topic>Cerium</topic><topic>Crystallization</topic><topic>Diffuse reflectance spectroscopy</topic><topic>Europium</topic><topic>Glass</topic><topic>glass‐ceramics</topic><topic>Organic chemistry</topic><topic>Phases</topic><topic>radioactive waste</topic><topic>Radioactive wastes</topic><topic>Raman spectroscopy</topic><topic>Scanning electron microscopy</topic><topic>Spectrum analysis</topic><topic>titanates</topic><topic>Uranium</topic><topic>uranium/uranium compounds</topic><topic>X-ray diffraction</topic><topic>Yttrium</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Zhang, Yingjie</creatorcontrib><creatorcontrib>Karatchevtseva, Inna</creatorcontrib><creatorcontrib>Kong, Linggen</creatorcontrib><creatorcontrib>Wei, Tao</creatorcontrib><creatorcontrib>Zhang, Zhaoming</creatorcontrib><collection>CrossRef</collection><collection>Ceramic Abstracts</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Journal of the American Ceramic Society</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Zhang, Yingjie</au><au>Karatchevtseva, Inna</au><au>Kong, Linggen</au><au>Wei, Tao</au><au>Zhang, Zhaoming</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Structural and spectroscopic investigations on the crystallization of uranium brannerite phases in glass</atitle><jtitle>Journal of the American Ceramic Society</jtitle><date>2018-11</date><risdate>2018</risdate><volume>101</volume><issue>11</issue><spage>5219</spage><epage>5228</epage><pages>5219-5228</pages><issn>0002-7820</issn><eissn>1551-2916</eissn><abstract>Brannerite‐based glass‐ceramics with relatively high actinide waste loadings are potential waste forms for the immobilization of actinide‐rich radioactive wastes containing process chemicals. In this work, the crystallization of pentavalent uranium brannerite phases in glass with the incorporation of yttrium/cerium/europium has been investigated. The formation of brannerite phases in glass has been confirmed with X‐ray diffraction and Raman spectroscopy. The evolution of microstructures and the development of micro pores in brannerite phases have been revealed by scanning electron microscopy with the nominal formula, Y0.51U0.49Ti2O6, Ce0.65U0.35Ti2O6, and Eu0.53U0.47Ti2O6, being determined with energy‐dispersive spectroscopy. The presence of dominant U5+ species has been proven with both diffuse reflectance spectroscopy and X‐ray absorption near‐edge spectroscopy. In addition, the systematic Raman band shifts with the mean cation radius in the studied brannerite series have been observed and discussed.
The crystallization of uranium brannerite phases in glass with the incorporation of Y‐Ce‐Eu has been investigated.</abstract><cop>Columbus</cop><pub>Wiley Subscription Services, Inc</pub><doi>10.1111/jace.15750</doi><tpages>10</tpages><orcidid>https://orcid.org/0000-0001-6321-4696</orcidid></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0002-7820 |
| ispartof | Journal of the American Ceramic Society, 2018-11, Vol.101 (11), p.5219-5228 |
| issn | 0002-7820 1551-2916 |
| language | eng |
| recordid | cdi_proquest_journals_2100359440 |
| source | Wiley Online Library Journals Frontfile Complete |
| subjects | Cerium Crystallization Diffuse reflectance spectroscopy Europium Glass glass‐ceramics Organic chemistry Phases radioactive waste Radioactive wastes Raman spectroscopy Scanning electron microscopy Spectrum analysis titanates Uranium uranium/uranium compounds X-ray diffraction Yttrium |
| title | Structural and spectroscopic investigations on the crystallization of uranium brannerite phases in glass |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-31T03%3A24%3A02IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Structural%20and%20spectroscopic%20investigations%20on%20the%20crystallization%20of%20uranium%20brannerite%20phases%20in%20glass&rft.jtitle=Journal%20of%20the%20American%20Ceramic%20Society&rft.au=Zhang,%20Yingjie&rft.date=2018-11&rft.volume=101&rft.issue=11&rft.spage=5219&rft.epage=5228&rft.pages=5219-5228&rft.issn=0002-7820&rft.eissn=1551-2916&rft_id=info:doi/10.1111/jace.15750&rft_dat=%3Cproquest_cross%3E2100359440%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=2100359440&rft_id=info:pmid/&rfr_iscdi=true |