Tetrathienoanthracene and Tetrathienylbenzene Derivatives as Hole‐Transporting Materials for Perovskite Solar Cell
The synthesis and characterization of two related families of star‐shaped thiophene‐containing hole‐transporting materials (HTMs) based on fused tetrathienoanthracene and nonfused tetrathienylbenzene cores are reported. All of them are endowed with four terminal (4,4′‐dimethoxy)diphenylamino groups...
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| Veröffentlicht in: | Advanced energy materials 2018-09, Vol.8 (25), p.n/a |
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| creator | Rojas, Diana Elizabeth Meza Cho, Kyung Taek Zhang, Yi Urbani, Maxence Tabet, Nouar la Torre, Gema Nazeeruddin, Mohammad Khaja Torres, Tomás |
| description | The synthesis and characterization of two related families of star‐shaped thiophene‐containing hole‐transporting materials (HTMs) based on fused tetrathienoanthracene and nonfused tetrathienylbenzene cores are reported. All of them are endowed with four terminal (4,4′‐dimethoxy)diphenylamino groups that are either linked directly to the core or showed a different type of bridges (i.e., thiophene‐phenyl or phenyl rings). The novel HTMs are tested in mixed‐ion perovskite (Cs0.1FA0.74MA0.13PbI2.48Br0.39) solar cells, and power conversion efficiencies of up to 18.8% are measured under 1 sun irradiation, comparable with the efficiency obtained for the reference cell using 2,2′,7,7′‐tetrakis(N,N′‐di‐p‐methoxyphenylamine)‐9,9′‐spirobifluorene as an HTM.
Two related families of star‐shaped thiophene‐containing small molecules based on fused tetrathienoanthracene and nonfused tetrathienylbenzene cores are tested as hole‐transporting materials (HTMs) in mixed‐ion perovskite solar cells (PSCs). The best‐tested HTM, TTA3, reach a similar power conversion efficiency (PCE) in PSC to the standard Spiro‐OMeTAD, with maxima PCE of 18.8% under simulated 1 sun illumination (AM1.5G). |
| doi_str_mv | 10.1002/aenm.201800681 |
| format | Article |
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Two related families of star‐shaped thiophene‐containing small molecules based on fused tetrathienoanthracene and nonfused tetrathienylbenzene cores are tested as hole‐transporting materials (HTMs) in mixed‐ion perovskite solar cells (PSCs). The best‐tested HTM, TTA3, reach a similar power conversion efficiency (PCE) in PSC to the standard Spiro‐OMeTAD, with maxima PCE of 18.8% under simulated 1 sun illumination (AM1.5G).</description><identifier>ISSN: 1614-6832</identifier><identifier>EISSN: 1614-6840</identifier><identifier>DOI: 10.1002/aenm.201800681</identifier><language>eng</language><publisher>Weinheim: Wiley Subscription Services, Inc</publisher><subject>Energy conversion efficiency ; hole‐transporting materials ; perovskite solar cells ; Perovskites ; Photovoltaic cells ; Solar cells ; solar energy conversion ; tetrathienoanthracenes ; tetrathienylbenzenes ; Transportation</subject><ispartof>Advanced energy materials, 2018-09, Vol.8 (25), p.n/a</ispartof><rights>2018 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c4221-96d87d940383e700d9e923426b72d60a7deee394ebbe4ae53bd0195b26c43c0a3</citedby><cites>FETCH-LOGICAL-c4221-96d87d940383e700d9e923426b72d60a7deee394ebbe4ae53bd0195b26c43c0a3</cites><orcidid>0000-0001-5955-4786</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Faenm.201800681$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Faenm.201800681$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,780,784,1416,27922,27923,45572,45573</link.rule.ids></links><search><creatorcontrib>Rojas, Diana Elizabeth Meza</creatorcontrib><creatorcontrib>Cho, Kyung Taek</creatorcontrib><creatorcontrib>Zhang, Yi</creatorcontrib><creatorcontrib>Urbani, Maxence</creatorcontrib><creatorcontrib>Tabet, Nouar</creatorcontrib><creatorcontrib>la Torre, Gema</creatorcontrib><creatorcontrib>Nazeeruddin, Mohammad Khaja</creatorcontrib><creatorcontrib>Torres, Tomás</creatorcontrib><title>Tetrathienoanthracene and Tetrathienylbenzene Derivatives as Hole‐Transporting Materials for Perovskite Solar Cell</title><title>Advanced energy materials</title><description>The synthesis and characterization of two related families of star‐shaped thiophene‐containing hole‐transporting materials (HTMs) based on fused tetrathienoanthracene and nonfused tetrathienylbenzene cores are reported. All of them are endowed with four terminal (4,4′‐dimethoxy)diphenylamino groups that are either linked directly to the core or showed a different type of bridges (i.e., thiophene‐phenyl or phenyl rings). The novel HTMs are tested in mixed‐ion perovskite (Cs0.1FA0.74MA0.13PbI2.48Br0.39) solar cells, and power conversion efficiencies of up to 18.8% are measured under 1 sun irradiation, comparable with the efficiency obtained for the reference cell using 2,2′,7,7′‐tetrakis(N,N′‐di‐p‐methoxyphenylamine)‐9,9′‐spirobifluorene as an HTM.
Two related families of star‐shaped thiophene‐containing small molecules based on fused tetrathienoanthracene and nonfused tetrathienylbenzene cores are tested as hole‐transporting materials (HTMs) in mixed‐ion perovskite solar cells (PSCs). The best‐tested HTM, TTA3, reach a similar power conversion efficiency (PCE) in PSC to the standard Spiro‐OMeTAD, with maxima PCE of 18.8% under simulated 1 sun illumination (AM1.5G).</description><subject>Energy conversion efficiency</subject><subject>hole‐transporting materials</subject><subject>perovskite solar cells</subject><subject>Perovskites</subject><subject>Photovoltaic cells</subject><subject>Solar cells</subject><subject>solar energy conversion</subject><subject>tetrathienoanthracenes</subject><subject>tetrathienylbenzenes</subject><subject>Transportation</subject><issn>1614-6832</issn><issn>1614-6840</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2018</creationdate><recordtype>article</recordtype><recordid>eNqFkM9OwkAQxhujiQS5et7Ec3H2D233SBDFBNREPG-27SDFsou7CwZPPoLP6JNYgoGjc5iZzPy-meSLoksKXQrArjWaZZcBzQCSjJ5ELZpQESeZgNNDz9l51PF-AU0ISYHzVhSmGJwO8wqN1SbMnS7QINGmJMfNts7RfO7mN-iqjQ7VBj3RnoxsjT9f31OnjV9ZFyrzSiY6NJCuPZlZR57Q2Y1_qwKSZ1trRwZY1xfR2awBsPNX29HL7XA6GMXjx7v7QX8cF4IxGsukzNJSCuAZxxSglCgZFyzJU1YmoNMSEbkUmOcoNPZ4XgKVvZwlheAFaN6OrvZ3V86-r9EHtbBrZ5qXioGUoklUNFR3TxXOeu9wplauWmq3VRTUzly1M1cdzG0Eci_4qGrc_kOr_vBhctT-AiPMgQM</recordid><startdate>20180905</startdate><enddate>20180905</enddate><creator>Rojas, Diana Elizabeth Meza</creator><creator>Cho, Kyung Taek</creator><creator>Zhang, Yi</creator><creator>Urbani, Maxence</creator><creator>Tabet, Nouar</creator><creator>la Torre, Gema</creator><creator>Nazeeruddin, Mohammad Khaja</creator><creator>Torres, Tomás</creator><general>Wiley Subscription Services, Inc</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SP</scope><scope>7TB</scope><scope>8FD</scope><scope>F28</scope><scope>FR3</scope><scope>H8D</scope><scope>L7M</scope><orcidid>https://orcid.org/0000-0001-5955-4786</orcidid></search><sort><creationdate>20180905</creationdate><title>Tetrathienoanthracene and Tetrathienylbenzene Derivatives as Hole‐Transporting Materials for Perovskite Solar Cell</title><author>Rojas, Diana Elizabeth Meza ; Cho, Kyung Taek ; Zhang, Yi ; Urbani, Maxence ; Tabet, Nouar ; la Torre, Gema ; Nazeeruddin, Mohammad Khaja ; Torres, Tomás</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c4221-96d87d940383e700d9e923426b72d60a7deee394ebbe4ae53bd0195b26c43c0a3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2018</creationdate><topic>Energy conversion efficiency</topic><topic>hole‐transporting materials</topic><topic>perovskite solar cells</topic><topic>Perovskites</topic><topic>Photovoltaic cells</topic><topic>Solar cells</topic><topic>solar energy conversion</topic><topic>tetrathienoanthracenes</topic><topic>tetrathienylbenzenes</topic><topic>Transportation</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Rojas, Diana Elizabeth Meza</creatorcontrib><creatorcontrib>Cho, Kyung Taek</creatorcontrib><creatorcontrib>Zhang, Yi</creatorcontrib><creatorcontrib>Urbani, Maxence</creatorcontrib><creatorcontrib>Tabet, Nouar</creatorcontrib><creatorcontrib>la Torre, Gema</creatorcontrib><creatorcontrib>Nazeeruddin, Mohammad Khaja</creatorcontrib><creatorcontrib>Torres, Tomás</creatorcontrib><collection>CrossRef</collection><collection>Electronics & Communications Abstracts</collection><collection>Mechanical & Transportation Engineering Abstracts</collection><collection>Technology Research Database</collection><collection>ANTE: Abstracts in New Technology & Engineering</collection><collection>Engineering Research Database</collection><collection>Aerospace Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Advanced energy materials</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Rojas, Diana Elizabeth Meza</au><au>Cho, Kyung Taek</au><au>Zhang, Yi</au><au>Urbani, Maxence</au><au>Tabet, Nouar</au><au>la Torre, Gema</au><au>Nazeeruddin, Mohammad Khaja</au><au>Torres, Tomás</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Tetrathienoanthracene and Tetrathienylbenzene Derivatives as Hole‐Transporting Materials for Perovskite Solar Cell</atitle><jtitle>Advanced energy materials</jtitle><date>2018-09-05</date><risdate>2018</risdate><volume>8</volume><issue>25</issue><epage>n/a</epage><issn>1614-6832</issn><eissn>1614-6840</eissn><abstract>The synthesis and characterization of two related families of star‐shaped thiophene‐containing hole‐transporting materials (HTMs) based on fused tetrathienoanthracene and nonfused tetrathienylbenzene cores are reported. All of them are endowed with four terminal (4,4′‐dimethoxy)diphenylamino groups that are either linked directly to the core or showed a different type of bridges (i.e., thiophene‐phenyl or phenyl rings). The novel HTMs are tested in mixed‐ion perovskite (Cs0.1FA0.74MA0.13PbI2.48Br0.39) solar cells, and power conversion efficiencies of up to 18.8% are measured under 1 sun irradiation, comparable with the efficiency obtained for the reference cell using 2,2′,7,7′‐tetrakis(N,N′‐di‐p‐methoxyphenylamine)‐9,9′‐spirobifluorene as an HTM.
Two related families of star‐shaped thiophene‐containing small molecules based on fused tetrathienoanthracene and nonfused tetrathienylbenzene cores are tested as hole‐transporting materials (HTMs) in mixed‐ion perovskite solar cells (PSCs). The best‐tested HTM, TTA3, reach a similar power conversion efficiency (PCE) in PSC to the standard Spiro‐OMeTAD, with maxima PCE of 18.8% under simulated 1 sun illumination (AM1.5G).</abstract><cop>Weinheim</cop><pub>Wiley Subscription Services, Inc</pub><doi>10.1002/aenm.201800681</doi><tpages>9</tpages><orcidid>https://orcid.org/0000-0001-5955-4786</orcidid></addata></record> |
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| subjects | Energy conversion efficiency hole‐transporting materials perovskite solar cells Perovskites Photovoltaic cells Solar cells solar energy conversion tetrathienoanthracenes tetrathienylbenzenes Transportation |
| title | Tetrathienoanthracene and Tetrathienylbenzene Derivatives as Hole‐Transporting Materials for Perovskite Solar Cell |
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