Efficient Vanadium‐Catalyzed Aerobic C−C Bond Oxidative Cleavage of Vicinal Diols

The aerobic oxidative C−C bond cleavage of vicinal diols catalyzed by vanadium amino triphenolates is described. Our results show that C−C bond cleavage can be performed in different solvents, under an air or oxygen atmosphere, with a large variety of glycols (cyclic or linear, with aromatic or alip...

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Veröffentlicht in:	Advanced synthesis & catalysis 2018-09, Vol.360 (17), p.3286-3296
Hauptverfasser:	Amadio, Emanuele, González‐Fabra, Joan, Carraro, Davide, Denis, William, Gjoka, Blerina, Zonta, Cristiano, Bartik, Kristin, Cavani, Fabrizio, Solmi, Stefania, Bo, Carles, Licini, Giulia
Format:	Artikel
Sprache:	eng
Schlagworte:	Aerobic Oxidation Aliphatic compounds Carbonyls Cleavage C−C Activation Density functional theory Diols Homogeneous Catalysis Oxygen Reaction mechanisms Vanadium
Online-Zugang:	Volltext
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