Phosphine‐Free NNN‐Manganese Complex Catalyzed α‐Alkylation of Ketones with Primary Alcohols and Friedländer Quinoline Synthesis

Herein, we report a very simple and inexpensive catalytic system based on Earth's abundant transition metal manganese and on a bench‐stable phosphine‐free NNN‐pincer ligand for an atom‐efficient α‐alkylations of ketones with primary alcohols via hydrogen‐autotransfer C−C bond formation protocol...

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Veröffentlicht in:	Advanced synthesis & catalysis 2018-09, Vol.360 (17), p.3233-3238
Hauptverfasser:	Barman, Milan K., Jana, Akash, Maji, Biplab
Format:	Artikel
Sprache:	eng
Schlagworte:	Alcohol Alcohols Alkylation Catalysis Chemical synthesis Friedländer reaction Hydrogen-autotransfer Ketones Manganese Manganese catalysts NNN-pincer Quinoline
Online-Zugang:	Volltext
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