Investigation of Bridgehead Effects on Reduction Potential in Alkyl and Aryl Azadithiolate‐Bridged (µ‐SCH2XCH2S) [Fe(CO)3]2 Synthetic Analogues of [FeFe]‐H2ase Active Site

Factors affecting the FeIFeI/FeIFe0 reduction potentials (E0) in a series of propane and azadithiolate bridged (µ‐SRS)[Fe(CO)3]2 synthetic model complexes of diiron hydrogenases are investigated. The E0 is found to vary from 60 to 390 mV depending on the nature of the substituent (Alkyl or Aryl) on...

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Veröffentlicht in:	European journal of inorganic chemistry 2018-08, Vol.2018 (32), p.3633-3643
Hauptverfasser:	Rana, Atanu, Kumar Das, Pradip, Mondal, Biswajit, Dey, Subal, Crouthers, Danielle, Dey, Abhishek
Format:	Artikel
Sprache:	eng
Schlagworte:	[FeFe]‐Hydrogenase Aromatic compounds Azadithiolate Cobalt Computational chemistry Density functional theory Dependence Hyperconjugation Inductive effect Inorganic chemistry Iron Nitrogen Organic chemistry Reduction
Online-Zugang:	Volltext
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