Synthesis and performance evaluation of binuclear metal phthalocyanines as high-efficiency electrocatalysts for Li/SOCl2 batteries
Two series of binuclear metal phthalocyanine complexes M2(PcTN)2Nap and M2(PcTA)2Nap (M = Mn2+, Fe2+, Co2+, Cu2+) were designed and synthesized through the liquid solvent method and amination reaction. Elemental analysis, IR, and UV-vis spectroscopy were applied to characterize the compounds. To eva...
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| Veröffentlicht in: | Journal of materials research 2018-08, Vol.33 (16), p.2376-2384 |
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| creator | Su, Yuanyuan Zhang, Ying Zhang, Ronglan Yang, Fei Zhao, Jianshe |
| description | Two series of binuclear metal phthalocyanine complexes M2(PcTN)2Nap and M2(PcTA)2Nap (M = Mn2+, Fe2+, Co2+, Cu2+) were designed and synthesized through the liquid solvent method and amination reaction. Elemental analysis, IR, and UV-vis spectroscopy were applied to characterize the compounds. To evaluate their catalytic performance, all the compounds were respectively added into the electrolyte of Li/SOCl2 battery systems as well as three-electrode systems for cyclic voltammetry (CV) measurements. The research studies indicate that the average discharge voltage and discharge time of the battery could be effectively enhanced by 0.2440 V and 810.7 s when compared with the battery in the absence of the compounds. As for capacities of the batteries containing catalysts, they were also found to have an improvement of 51.78–91.62%. Among the effects of diverse metal ions on the catalytic performance of phthalocyanines, the complexes whose center metal ions were Mn2+ or Co2+ exhibited relatively high catalytic performance. Meanwhile, combined with experimental results of CV analyses, the suggested catalytic mechanism of binuclear phthalocyanines for catalyzing Li/SOCl2 batteries had been proposed. |
| doi_str_mv | 10.1557/jmr.2018.238 |
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Elemental analysis, IR, and UV-vis spectroscopy were applied to characterize the compounds. To evaluate their catalytic performance, all the compounds were respectively added into the electrolyte of Li/SOCl2 battery systems as well as three-electrode systems for cyclic voltammetry (CV) measurements. The research studies indicate that the average discharge voltage and discharge time of the battery could be effectively enhanced by 0.2440 V and 810.7 s when compared with the battery in the absence of the compounds. As for capacities of the batteries containing catalysts, they were also found to have an improvement of 51.78–91.62%. Among the effects of diverse metal ions on the catalytic performance of phthalocyanines, the complexes whose center metal ions were Mn2+ or Co2+ exhibited relatively high catalytic performance. Meanwhile, combined with experimental results of CV analyses, the suggested catalytic mechanism of binuclear phthalocyanines for catalyzing Li/SOCl2 batteries had been proposed.</description><identifier>ISSN: 0884-2914</identifier><identifier>EISSN: 2044-5326</identifier><identifier>DOI: 10.1557/jmr.2018.238</identifier><language>eng</language><publisher>New York, USA: Cambridge University Press</publisher><subject>Applied and Technical Physics ; Aviation ; Batteries ; Biomaterials ; Carbon ; Catalysis ; Chemical synthesis ; Chloride ; Cobalt ; Coordination compounds ; Copper ; Discharge ; Electrocatalysts ; Electrodes ; Electrolytes ; Infrared spectroscopy ; Inorganic Chemistry ; Kerosene ; Lithium ; Manganese ions ; Materials Engineering ; Materials research ; Materials Science ; Metal ions ; Metal phthalocyanines ; Nanotechnology ; Performance evaluation ; Photocatalysis ; Work stations</subject><ispartof>Journal of materials research, 2018-08, Vol.33 (16), p.2376-2384</ispartof><rights>Copyright © Materials Research Society 2018</rights><rights>The Materials Research Society 2018</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><cites>FETCH-LOGICAL-c299t-72bd50f9b809e3895edba8782aa732d69a5a136c5ec2f940c0f38191c9cfd8043</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1557/jmr.2018.238$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://www.cambridge.org/core/product/identifier/S0884291418002388/type/journal_article$$EHTML$$P50$$Gcambridge$$H</linktohtml><link.rule.ids>164,314,780,784,27924,27925,41488,42557,51319,55628</link.rule.ids></links><search><creatorcontrib>Su, Yuanyuan</creatorcontrib><creatorcontrib>Zhang, Ying</creatorcontrib><creatorcontrib>Zhang, Ronglan</creatorcontrib><creatorcontrib>Yang, Fei</creatorcontrib><creatorcontrib>Zhao, Jianshe</creatorcontrib><title>Synthesis and performance evaluation of binuclear metal phthalocyanines as high-efficiency electrocatalysts for Li/SOCl2 batteries</title><title>Journal of materials research</title><addtitle>Journal of Materials Research</addtitle><addtitle>J. Mater. Res</addtitle><description>Two series of binuclear metal phthalocyanine complexes M2(PcTN)2Nap and M2(PcTA)2Nap (M = Mn2+, Fe2+, Co2+, Cu2+) were designed and synthesized through the liquid solvent method and amination reaction. Elemental analysis, IR, and UV-vis spectroscopy were applied to characterize the compounds. To evaluate their catalytic performance, all the compounds were respectively added into the electrolyte of Li/SOCl2 battery systems as well as three-electrode systems for cyclic voltammetry (CV) measurements. The research studies indicate that the average discharge voltage and discharge time of the battery could be effectively enhanced by 0.2440 V and 810.7 s when compared with the battery in the absence of the compounds. As for capacities of the batteries containing catalysts, they were also found to have an improvement of 51.78–91.62%. Among the effects of diverse metal ions on the catalytic performance of phthalocyanines, the complexes whose center metal ions were Mn2+ or Co2+ exhibited relatively high catalytic performance. Meanwhile, combined with experimental results of CV analyses, the suggested catalytic mechanism of binuclear phthalocyanines for catalyzing Li/SOCl2 batteries had been proposed.</description><subject>Applied and Technical Physics</subject><subject>Aviation</subject><subject>Batteries</subject><subject>Biomaterials</subject><subject>Carbon</subject><subject>Catalysis</subject><subject>Chemical synthesis</subject><subject>Chloride</subject><subject>Cobalt</subject><subject>Coordination compounds</subject><subject>Copper</subject><subject>Discharge</subject><subject>Electrocatalysts</subject><subject>Electrodes</subject><subject>Electrolytes</subject><subject>Infrared spectroscopy</subject><subject>Inorganic Chemistry</subject><subject>Kerosene</subject><subject>Lithium</subject><subject>Manganese ions</subject><subject>Materials Engineering</subject><subject>Materials research</subject><subject>Materials Science</subject><subject>Metal ions</subject><subject>Metal phthalocyanines</subject><subject>Nanotechnology</subject><subject>Performance evaluation</subject><subject>Photocatalysis</subject><subject>Work stations</subject><issn>0884-2914</issn><issn>2044-5326</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2018</creationdate><recordtype>article</recordtype><sourceid>ABUWG</sourceid><sourceid>AFKRA</sourceid><sourceid>BENPR</sourceid><sourceid>CCPQU</sourceid><sourceid>DWQXO</sourceid><recordid>eNqFkE1LAzEURYMoWKs7f0DA9bRJJukkSyl-QcGFuh7eZF46KdNMTVKhW3-5Uyq4dHU3594Lh5BbzmZcqWq-2caZYFzPRKnPyEQwKQtVisU5mTCtZSEMl5fkKqUNY1yxSk7I99sh5A6TTxRCS3cY3RC3ECxS_IJ-D9kPgQ6ONj7sbY8Q6RYz9HTX5Q76wR4g-IBjO9HOr7sCnfPWY7AHij3aHAcLI39IOdFxmq78_O112QvaQM4YPaZrcuGgT3jzm1Py8fjwvnwuVq9PL8v7VWGFMbmoRNMq5kyjmcFSG4VtA7rSAqAqRbswoICXC6vQCmcks8yVmhtujXWtZrKckrvT7i4On3tMud4M-xjGy1owI7leSKlGqjhRaRd9WGP8ozirj5rrUXN91FyPmkd-duItbJvo2zX-U_gBYWmCiQ</recordid><startdate>20180828</startdate><enddate>20180828</enddate><creator>Su, Yuanyuan</creator><creator>Zhang, Ying</creator><creator>Zhang, Ronglan</creator><creator>Yang, Fei</creator><creator>Zhao, Jianshe</creator><general>Cambridge University Press</general><general>Springer International Publishing</general><general>Springer Nature B.V</general><scope>0U~</scope><scope>1-H</scope><scope>3V.</scope><scope>7SR</scope><scope>7WY</scope><scope>7WZ</scope><scope>7XB</scope><scope>87Z</scope><scope>8BQ</scope><scope>8FD</scope><scope>8FE</scope><scope>8FG</scope><scope>8FK</scope><scope>8FL</scope><scope>ABJCF</scope><scope>ABUWG</scope><scope>AFKRA</scope><scope>BENPR</scope><scope>BEZIV</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>FRNLG</scope><scope>F~G</scope><scope>HCIFZ</scope><scope>JG9</scope><scope>K60</scope><scope>K6~</scope><scope>KB.</scope><scope>L.-</scope><scope>L.0</scope><scope>M0C</scope><scope>PDBOC</scope><scope>PQBIZ</scope><scope>PQBZA</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>Q9U</scope><scope>S0W</scope></search><sort><creationdate>20180828</creationdate><title>Synthesis and performance evaluation of binuclear metal phthalocyanines as high-efficiency electrocatalysts for Li/SOCl2 batteries</title><author>Su, Yuanyuan ; Zhang, Ying ; Zhang, Ronglan ; Yang, Fei ; Zhao, Jianshe</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c299t-72bd50f9b809e3895edba8782aa732d69a5a136c5ec2f940c0f38191c9cfd8043</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2018</creationdate><topic>Applied and Technical Physics</topic><topic>Aviation</topic><topic>Batteries</topic><topic>Biomaterials</topic><topic>Carbon</topic><topic>Catalysis</topic><topic>Chemical synthesis</topic><topic>Chloride</topic><topic>Cobalt</topic><topic>Coordination compounds</topic><topic>Copper</topic><topic>Discharge</topic><topic>Electrocatalysts</topic><topic>Electrodes</topic><topic>Electrolytes</topic><topic>Infrared spectroscopy</topic><topic>Inorganic Chemistry</topic><topic>Kerosene</topic><topic>Lithium</topic><topic>Manganese ions</topic><topic>Materials Engineering</topic><topic>Materials research</topic><topic>Materials Science</topic><topic>Metal ions</topic><topic>Metal phthalocyanines</topic><topic>Nanotechnology</topic><topic>Performance evaluation</topic><topic>Photocatalysis</topic><topic>Work stations</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Su, Yuanyuan</creatorcontrib><creatorcontrib>Zhang, Ying</creatorcontrib><creatorcontrib>Zhang, Ronglan</creatorcontrib><creatorcontrib>Yang, Fei</creatorcontrib><creatorcontrib>Zhao, Jianshe</creatorcontrib><collection>Global News & ABI/Inform Professional</collection><collection>Trade PRO</collection><collection>ProQuest Central (Corporate)</collection><collection>Engineered Materials Abstracts</collection><collection>ABI商业信息数据库</collection><collection>ABI/INFORM Global (PDF only)</collection><collection>ProQuest Central (purchase pre-March 2016)</collection><collection>ABI/INFORM Collection</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>ProQuest Central (Alumni) (purchase pre-March 2016)</collection><collection>ABI/INFORM Collection (Alumni Edition)</collection><collection>Materials Science & Engineering Collection</collection><collection>ProQuest Central (Alumni)</collection><collection>ProQuest Central UK/Ireland</collection><collection>ProQuest Central</collection><collection>ProQuest Business Premium Collection</collection><collection>Technology Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest Materials Science Collection</collection><collection>ProQuest Central Korea</collection><collection>Business Premium Collection (Alumni)</collection><collection>ABI/INFORM Global (Corporate)</collection><collection>SciTech Premium Collection</collection><collection>Materials Research Database</collection><collection>ProQuest Business Collection (Alumni Edition)</collection><collection>ProQuest Business Collection</collection><collection>https://resources.nclive.org/materials</collection><collection>ABI/INFORM Professional Advanced</collection><collection>ABI/INFORM Professional Standard</collection><collection>ABI/INFORM Global</collection><collection>Materials science collection</collection><collection>ProQuest One Business</collection><collection>ProQuest One Business (Alumni)</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>ProQuest Central Basic</collection><collection>DELNET Engineering & Technology Collection</collection><jtitle>Journal of materials research</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Su, Yuanyuan</au><au>Zhang, Ying</au><au>Zhang, Ronglan</au><au>Yang, Fei</au><au>Zhao, Jianshe</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Synthesis and performance evaluation of binuclear metal phthalocyanines as high-efficiency electrocatalysts for Li/SOCl2 batteries</atitle><jtitle>Journal of materials research</jtitle><stitle>Journal of Materials Research</stitle><addtitle>J. Mater. Res</addtitle><date>2018-08-28</date><risdate>2018</risdate><volume>33</volume><issue>16</issue><spage>2376</spage><epage>2384</epage><pages>2376-2384</pages><issn>0884-2914</issn><eissn>2044-5326</eissn><abstract>Two series of binuclear metal phthalocyanine complexes M2(PcTN)2Nap and M2(PcTA)2Nap (M = Mn2+, Fe2+, Co2+, Cu2+) were designed and synthesized through the liquid solvent method and amination reaction. Elemental analysis, IR, and UV-vis spectroscopy were applied to characterize the compounds. To evaluate their catalytic performance, all the compounds were respectively added into the electrolyte of Li/SOCl2 battery systems as well as three-electrode systems for cyclic voltammetry (CV) measurements. The research studies indicate that the average discharge voltage and discharge time of the battery could be effectively enhanced by 0.2440 V and 810.7 s when compared with the battery in the absence of the compounds. As for capacities of the batteries containing catalysts, they were also found to have an improvement of 51.78–91.62%. Among the effects of diverse metal ions on the catalytic performance of phthalocyanines, the complexes whose center metal ions were Mn2+ or Co2+ exhibited relatively high catalytic performance. Meanwhile, combined with experimental results of CV analyses, the suggested catalytic mechanism of binuclear phthalocyanines for catalyzing Li/SOCl2 batteries had been proposed.</abstract><cop>New York, USA</cop><pub>Cambridge University Press</pub><doi>10.1557/jmr.2018.238</doi><tpages>9</tpages></addata></record> |
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| subjects | Applied and Technical Physics Aviation Batteries Biomaterials Carbon Catalysis Chemical synthesis Chloride Cobalt Coordination compounds Copper Discharge Electrocatalysts Electrodes Electrolytes Infrared spectroscopy Inorganic Chemistry Kerosene Lithium Manganese ions Materials Engineering Materials research Materials Science Metal ions Metal phthalocyanines Nanotechnology Performance evaluation Photocatalysis Work stations |
| title | Synthesis and performance evaluation of binuclear metal phthalocyanines as high-efficiency electrocatalysts for Li/SOCl2 batteries |
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