RETRACTED ARTICLE: Study on Methylation of Naphthalene with Methanol over ZSM-5 (core)/SAPO-11(shell) Composite Molecular Sieve

ZSM-5 (core)/SAPO-11 (shell) composite molecular sieve was synthesized by the hydrothermal method in order to combine the advantages of ZSM-5 and SAPO-11 for the methylation of naphthalene with methanol. For comparison, the mechanical mixture was prepared through the blending of ZSM-5 and SAPO-11. T...

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Veröffentlicht in:Russian journal of applied chemistry 2018, Vol.91 (6), p.1002-1008
Hauptverfasser: Wang, Xiaoxiao, Guo, Fang, Wei, Xianxian, Liu, Zhenmin, Wang, Yingchun, Guo, Shaoqing, Wang, Yuanyang, Yu, Yue
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container_issue 6
container_start_page 1002
container_title Russian journal of applied chemistry
container_volume 91
creator Wang, Xiaoxiao
Guo, Fang
Wei, Xianxian
Liu, Zhenmin
Wang, Yingchun
Guo, Shaoqing
Wang, Yuanyang
Yu, Yue
description ZSM-5 (core)/SAPO-11 (shell) composite molecular sieve was synthesized by the hydrothermal method in order to combine the advantages of ZSM-5 and SAPO-11 for the methylation of naphthalene with methanol. For comparison, the mechanical mixture was prepared through the blending of ZSM-5 and SAPO-11. The characterization results indicated that ZSM-5/SAPO-11 composite molecular sieve exhibited a core–shell structure, with the ZSM-5 phase as the core and the SAPO-11 phase as the shell. The pore size of the composite was between that of ZSM-5 and SAPO-11. The composite had fewer acid sites than ZSM-5 and mechanical mixture while more acid sites than SAPO-11. The experimental results indicated that the composite exhibited high catalytic performances for the methylation of naphthalene with methanol.
doi_str_mv 10.1134/S1070427218060198
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Chemistry/Food Science
Industrial Chemistry/Chemical Engineering
Organic Synthesis and Industrial Organic Chemistry
title RETRACTED ARTICLE: Study on Methylation of Naphthalene with Methanol over ZSM-5 (core)/SAPO-11(shell) Composite Molecular Sieve
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