Copolymers of Maleic Anhydride and Methylene Alkanes: Synthesis, Modification, and Pour Point Depressant Properties
Copolymers with the equimolar composition and presumably alternating microstructure are synthesized by the radical copolymerization of methylene alkanes, the products of dimerization of α-olefins with the general formula RCH 2 CH 2 C(=CH 2 )R (R = n -C 4 H 7 , n -C 6 H 13 , n -C 8 H 17 , n -C 10 H 2...
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| Veröffentlicht in: | Polymer science. Series B 2018-07, Vol.60 (4), p.469-480 |
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| creator | Nifant’ev, I. E. Vinogradov, A. A. Bondarenko, G. N. Korchagina, S. A. Shlyakhtin, A. V. Roznyatovskii, V. A. Ivchenko, P. V. |
| description | Copolymers with the equimolar composition and presumably alternating microstructure are synthesized by the radical copolymerization of methylene alkanes, the products of dimerization of α-olefins with the general formula RCH
2
CH
2
C(=CH
2
)R (R =
n
-C
4
H
7
,
n
-C
6
H
13
,
n
-C
8
H
17
,
n
-C
10
H
21
,
n
-C
12
H
25
), with maleic anhydride. The products of reactions between the obtained copolymers and 1-octadecanamine or 1-octadecanol are isolated and spectrally characterized. The depressor efficiency of the copolymers with respect to the solutions of paraffins in
n
-alkanes is studied. Qualitative differences between the copolymers of maleic anhydride with methylene alkanes and reference copolymers based on 1-octadecene are estimated using vibrational viscometry combined with analysis of the size and morphology of paraffin crystals. It is shown that the copolymers with methylene alkanes more effectively decrease the cold filter plugging point (CFPP) of paraffin solutions in
n
-decane. |
| doi_str_mv | 10.1134/S1560090418040061 |
| format | Article |
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2
CH
2
C(=CH
2
)R (R =
n
-C
4
H
7
,
n
-C
6
H
13
,
n
-C
8
H
17
,
n
-C
10
H
21
,
n
-C
12
H
25
), with maleic anhydride. The products of reactions between the obtained copolymers and 1-octadecanamine or 1-octadecanol are isolated and spectrally characterized. The depressor efficiency of the copolymers with respect to the solutions of paraffins in
n
-alkanes is studied. Qualitative differences between the copolymers of maleic anhydride with methylene alkanes and reference copolymers based on 1-octadecene are estimated using vibrational viscometry combined with analysis of the size and morphology of paraffin crystals. It is shown that the copolymers with methylene alkanes more effectively decrease the cold filter plugging point (CFPP) of paraffin solutions in
n
-decane.</description><identifier>ISSN: 1560-0904</identifier><identifier>EISSN: 1555-6123</identifier><identifier>DOI: 10.1134/S1560090418040061</identifier><language>eng</language><publisher>Moscow: Pleiades Publishing</publisher><subject>Alkanes ; Alkenes ; Anhydrides ; Chemical synthesis ; Chemistry ; Chemistry and Materials Science ; Copolymerization ; Copolymers ; Dimerization ; Functional Polymers ; Maleic anhydride ; Methylene ; Morphology ; Paraffins ; Polymer Sciences ; Viscometry</subject><ispartof>Polymer science. Series B, 2018-07, Vol.60 (4), p.469-480</ispartof><rights>Pleiades Publishing, Ltd. 2018</rights><rights>Copyright Springer Science & Business Media 2018</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c316t-d43fb77a61d762c840b478a2c86cd0d1179bc5d131ba92e4475a9a8cfb2e6b783</citedby><cites>FETCH-LOGICAL-c316t-d43fb77a61d762c840b478a2c86cd0d1179bc5d131ba92e4475a9a8cfb2e6b783</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1134/S1560090418040061$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1134/S1560090418040061$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,776,780,27901,27902,41464,42533,51294</link.rule.ids></links><search><creatorcontrib>Nifant’ev, I. E.</creatorcontrib><creatorcontrib>Vinogradov, A. A.</creatorcontrib><creatorcontrib>Bondarenko, G. N.</creatorcontrib><creatorcontrib>Korchagina, S. A.</creatorcontrib><creatorcontrib>Shlyakhtin, A. V.</creatorcontrib><creatorcontrib>Roznyatovskii, V. A.</creatorcontrib><creatorcontrib>Ivchenko, P. V.</creatorcontrib><title>Copolymers of Maleic Anhydride and Methylene Alkanes: Synthesis, Modification, and Pour Point Depressant Properties</title><title>Polymer science. Series B</title><addtitle>Polym. Sci. Ser. B</addtitle><description>Copolymers with the equimolar composition and presumably alternating microstructure are synthesized by the radical copolymerization of methylene alkanes, the products of dimerization of α-olefins with the general formula RCH
2
CH
2
C(=CH
2
)R (R =
n
-C
4
H
7
,
n
-C
6
H
13
,
n
-C
8
H
17
,
n
-C
10
H
21
,
n
-C
12
H
25
), with maleic anhydride. The products of reactions between the obtained copolymers and 1-octadecanamine or 1-octadecanol are isolated and spectrally characterized. The depressor efficiency of the copolymers with respect to the solutions of paraffins in
n
-alkanes is studied. Qualitative differences between the copolymers of maleic anhydride with methylene alkanes and reference copolymers based on 1-octadecene are estimated using vibrational viscometry combined with analysis of the size and morphology of paraffin crystals. It is shown that the copolymers with methylene alkanes more effectively decrease the cold filter plugging point (CFPP) of paraffin solutions in
n
-decane.</description><subject>Alkanes</subject><subject>Alkenes</subject><subject>Anhydrides</subject><subject>Chemical synthesis</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Copolymerization</subject><subject>Copolymers</subject><subject>Dimerization</subject><subject>Functional Polymers</subject><subject>Maleic anhydride</subject><subject>Methylene</subject><subject>Morphology</subject><subject>Paraffins</subject><subject>Polymer Sciences</subject><subject>Viscometry</subject><issn>1560-0904</issn><issn>1555-6123</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2018</creationdate><recordtype>article</recordtype><recordid>eNp1UMtOwzAQjBBIVKUfwM0S1wa8seMk3KrylFpRqXCOnHhDXVI72Okhf49LkTgg9rA70s7MriaKLoFeAzB-s4ZUUFpQDjnllAo4iUaQpmksIGGnByxofNifRxPvtzQUKxhAMYr83Ha2HXboPLENWcoWdU1mZjMopxUSaRRZYr8ZWjRIZu2HNOhvyXow_Qa99lOytEo3upa9tmb6zV_ZvQtNm57cYefQexngytkOXa_RX0RnjWw9Tn7mOHp7uH-dP8WLl8fn-WwR1wxEHyvOmirLpACViaTOOa14lsuARK2oAsiKqk4VMKhkkSDnWSoLmddNlaCospyNo6ujb-fs5x59X27DZyacLBNaJHkBCU8DC46s2lnvHTZl5_ROuqEEWh7iLf_EGzTJUeMD17yj-3X-X_QFVv58TQ</recordid><startdate>20180701</startdate><enddate>20180701</enddate><creator>Nifant’ev, I. E.</creator><creator>Vinogradov, A. A.</creator><creator>Bondarenko, G. N.</creator><creator>Korchagina, S. A.</creator><creator>Shlyakhtin, A. V.</creator><creator>Roznyatovskii, V. A.</creator><creator>Ivchenko, P. V.</creator><general>Pleiades Publishing</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20180701</creationdate><title>Copolymers of Maleic Anhydride and Methylene Alkanes: Synthesis, Modification, and Pour Point Depressant Properties</title><author>Nifant’ev, I. E. ; Vinogradov, A. A. ; Bondarenko, G. N. ; Korchagina, S. A. ; Shlyakhtin, A. V. ; Roznyatovskii, V. A. ; Ivchenko, P. V.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c316t-d43fb77a61d762c840b478a2c86cd0d1179bc5d131ba92e4475a9a8cfb2e6b783</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2018</creationdate><topic>Alkanes</topic><topic>Alkenes</topic><topic>Anhydrides</topic><topic>Chemical synthesis</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Copolymerization</topic><topic>Copolymers</topic><topic>Dimerization</topic><topic>Functional Polymers</topic><topic>Maleic anhydride</topic><topic>Methylene</topic><topic>Morphology</topic><topic>Paraffins</topic><topic>Polymer Sciences</topic><topic>Viscometry</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Nifant’ev, I. E.</creatorcontrib><creatorcontrib>Vinogradov, A. A.</creatorcontrib><creatorcontrib>Bondarenko, G. N.</creatorcontrib><creatorcontrib>Korchagina, S. A.</creatorcontrib><creatorcontrib>Shlyakhtin, A. V.</creatorcontrib><creatorcontrib>Roznyatovskii, V. A.</creatorcontrib><creatorcontrib>Ivchenko, P. V.</creatorcontrib><collection>CrossRef</collection><jtitle>Polymer science. Series B</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Nifant’ev, I. E.</au><au>Vinogradov, A. A.</au><au>Bondarenko, G. N.</au><au>Korchagina, S. A.</au><au>Shlyakhtin, A. V.</au><au>Roznyatovskii, V. A.</au><au>Ivchenko, P. V.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Copolymers of Maleic Anhydride and Methylene Alkanes: Synthesis, Modification, and Pour Point Depressant Properties</atitle><jtitle>Polymer science. Series B</jtitle><stitle>Polym. Sci. Ser. B</stitle><date>2018-07-01</date><risdate>2018</risdate><volume>60</volume><issue>4</issue><spage>469</spage><epage>480</epage><pages>469-480</pages><issn>1560-0904</issn><eissn>1555-6123</eissn><abstract>Copolymers with the equimolar composition and presumably alternating microstructure are synthesized by the radical copolymerization of methylene alkanes, the products of dimerization of α-olefins with the general formula RCH
2
CH
2
C(=CH
2
)R (R =
n
-C
4
H
7
,
n
-C
6
H
13
,
n
-C
8
H
17
,
n
-C
10
H
21
,
n
-C
12
H
25
), with maleic anhydride. The products of reactions between the obtained copolymers and 1-octadecanamine or 1-octadecanol are isolated and spectrally characterized. The depressor efficiency of the copolymers with respect to the solutions of paraffins in
n
-alkanes is studied. Qualitative differences between the copolymers of maleic anhydride with methylene alkanes and reference copolymers based on 1-octadecene are estimated using vibrational viscometry combined with analysis of the size and morphology of paraffin crystals. It is shown that the copolymers with methylene alkanes more effectively decrease the cold filter plugging point (CFPP) of paraffin solutions in
n
-decane.</abstract><cop>Moscow</cop><pub>Pleiades Publishing</pub><doi>10.1134/S1560090418040061</doi><tpages>12</tpages></addata></record> |
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| issn | 1560-0904 1555-6123 |
| language | eng |
| recordid | cdi_proquest_journals_2092891245 |
| source | SpringerLink Journals - AutoHoldings |
| subjects | Alkanes Alkenes Anhydrides Chemical synthesis Chemistry Chemistry and Materials Science Copolymerization Copolymers Dimerization Functional Polymers Maleic anhydride Methylene Morphology Paraffins Polymer Sciences Viscometry |
| title | Copolymers of Maleic Anhydride and Methylene Alkanes: Synthesis, Modification, and Pour Point Depressant Properties |
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