Synthesis and reactivity of an N-triphos Mo(0) dinitrogen complex

The preparation and reactivity of a novel molybdenum dinitrogen complex supported by a nitrogen-centred tripodal phosphine ligand (N-triphos, N(CH 2 PPh 2 ) 3 , NP 3 Ph ) are reported. Reaction of N-triphos with [MoX 3 (THF) 3 ] (X = Cl, Br, I) gave the Mo( iii ) complex [MoX 3 (κ 2 -NP 3 Ph )(THF)]...

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Veröffentlicht in:	Dalton transactions : an international journal of inorganic chemistry 2018, Vol.47 (33), p.11386-11396
Hauptverfasser:	Apps, Samantha L, White, Andrew J. P, Miller, Philip W, Long, Nicholas J
Format:	Artikel
Sprache:	eng
Schlagworte:	Alkali metals Crystal structure Lewis acid Ligands Molybdenum Nitrogen compounds Reactivity Reduction Single crystals X-ray diffraction
Online-Zugang:	Volltext
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