Wetting transitions in polydisperse fluids

Wetting transitions in polydisperse fluids

The properties of the coexisting bulk gas and liquid phases of a polydisperse fluid depend not only on the prevailing temperature, but also on the overall parent density. As a result, a polydisperse fluid near a wall will exhibit density-driven wetting transitions inside the coexistence region. We p...

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Veröffentlicht in:arXiv.org 2006-09
Hauptverfasser: Buzzacchi, Matteo, Wilding, Nigel B, Sollich, Peter
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Sprache:eng
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Computational fluid dynamics
Computer simulation
Density
Fluids
Liquid phases
Monte Carlo simulation
Phase diagrams
Topology
Wetting
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Wilding, Nigel B
Sollich, Peter
description The properties of the coexisting bulk gas and liquid phases of a polydisperse fluid depend not only on the prevailing temperature, but also on the overall parent density. As a result, a polydisperse fluid near a wall will exhibit density-driven wetting transitions inside the coexistence region. We propose a likely topology for the wetting phase diagram, which we test using Monte Carlo simulations of a model polydisperse fluid at an attractive wall, tracing the wetting line inside the cloud curve and identifying the relationship to prewetting.
doi_str_mv 10.48550/arxiv.0609118
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subjects Computational fluid dynamics
Computer simulation
Density
Fluids
Liquid phases
Monte Carlo simulation
Phase diagrams
Topology
Wetting
title Wetting transitions in polydisperse fluids
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