Thermodynamic properties of the NdBr3–MBr binary systems (M = Na, K)

Phase equilibria in the NdBr 3 –MBr binary systems (M = Na, K) were established by differential scanning calorimetry. The system with NaBr is a simple eutectic system with two compounds that decompose in the solid state (NaNdBr 4 at 603 K and Na 3 NdBr 6 at 580 K). In the system with KBr, three stoi...

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Veröffentlicht in:Journal of thermal analysis and calorimetry 2018-09, Vol.133 (3), p.1589-1596
Hauptverfasser: Bounouri, Yassine, Berkani, Madjid, Zamouche, Abdelmalek, Dańczak, Anna, Chojnacka, Ida, Rycerz, Leszek
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container_issue 3
container_start_page 1589
container_title Journal of thermal analysis and calorimetry
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creator Bounouri, Yassine
Berkani, Madjid
Zamouche, Abdelmalek
Dańczak, Anna
Chojnacka, Ida
Rycerz, Leszek
description Phase equilibria in the NdBr 3 –MBr binary systems (M = Na, K) were established by differential scanning calorimetry. The system with NaBr is a simple eutectic system with two compounds that decompose in the solid state (NaNdBr 4 at 603 K and Na 3 NdBr 6 at 580 K). In the system with KBr, three stoichiometric compounds exist. First (K 3 NdBr 6 ) is formed from KBr and K 2 NdBr 5 at 680 K and melts congruently at 918 K. Second (KNd 2 Br 7 ) melts congruently at 814 K. Third compound (K 2 NdBr 5 ) melts incongruently at 822 K.
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The system with NaBr is a simple eutectic system with two compounds that decompose in the solid state (NaNdBr 4 at 603 K and Na 3 NdBr 6 at 580 K). In the system with KBr, three stoichiometric compounds exist. First (K 3 NdBr 6 ) is formed from KBr and K 2 NdBr 5 at 680 K and melts congruently at 918 K. Second (KNd 2 Br 7 ) melts congruently at 814 K. 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subjects Analytical Chemistry
Binary systems
Chemistry
Chemistry and Materials Science
Inorganic Chemistry
Measurement Science and Instrumentation
Melts
Phase equilibria
Physical Chemistry
Polymer Sciences
Potassium bromides
Thermodynamic properties
title Thermodynamic properties of the NdBr3–MBr binary systems (M = Na, K)
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