Dielectric and thermal features of zinc ion conducting gel polymer electrolytes (GPEs) containing PVC / PEMA blend and EMIMTFSI ionic liquid
A new series of gel polymer electrolytes (GPEs) based on an optimized composition of polymer blend-salt matrix [poly(vinyl chloride) (PVC) (30 wt%) / poly(ethyl methacrylate) (PEMA) (70 wt%): 30 wt% zinc triflate Zn(CF 3 SO 3 ) 2 ] containing different concentrations of 1-ethyl-3-methylimidazolium b...
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| Veröffentlicht in: | Ionics 2018-09, Vol.24 (9), p.2631-2646 |
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| creator | Prasanna, C. M. Sai Suthanthiraraj, S. Austin |
| description | A new series of gel polymer electrolytes (GPEs) based on an optimized composition of polymer blend-salt matrix [poly(vinyl chloride) (PVC) (30 wt%) / poly(ethyl methacrylate) (PEMA) (70 wt%): 30 wt% zinc triflate Zn(CF
3
SO
3
)
2
] containing different concentrations of 1-ethyl-3-methylimidazolium bis(trifluoromethylsulfonyl) imide (EMIMTFSI) ionic liquid has been prepared by simple solution casting technique. The prepared films of gel polymer membranes have been characterized utilizing complex impedance spectroscopy, differential scanning calorimetry (DSC), thermogravimetric (TG), and cyclic voltammetry (CV) analyses. The dielectric constant and ionic conductivity pursue similar trend with increasing EMIMTFSI concentration. The addition of ionic liquid in varied amounts into the optimized polymer blend-salt system effectively reduces the glass transition temperature (
T
g
) of the film as revealed from differential scanning calorimetry results. The origin of an improved thermal stability and feasible cyclic performance in respect of the best conducting sample of the resultant gel polymer electrolytes was also examined by utilizing thermogravimetric and cyclic voltammetry measurements. |
| doi_str_mv | 10.1007/s11581-017-2421-2 |
| format | Article |
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3
SO
3
)
2
] containing different concentrations of 1-ethyl-3-methylimidazolium bis(trifluoromethylsulfonyl) imide (EMIMTFSI) ionic liquid has been prepared by simple solution casting technique. The prepared films of gel polymer membranes have been characterized utilizing complex impedance spectroscopy, differential scanning calorimetry (DSC), thermogravimetric (TG), and cyclic voltammetry (CV) analyses. The dielectric constant and ionic conductivity pursue similar trend with increasing EMIMTFSI concentration. The addition of ionic liquid in varied amounts into the optimized polymer blend-salt system effectively reduces the glass transition temperature (
T
g
) of the film as revealed from differential scanning calorimetry results. The origin of an improved thermal stability and feasible cyclic performance in respect of the best conducting sample of the resultant gel polymer electrolytes was also examined by utilizing thermogravimetric and cyclic voltammetry measurements.</description><identifier>ISSN: 0947-7047</identifier><identifier>EISSN: 1862-0760</identifier><identifier>DOI: 10.1007/s11581-017-2421-2</identifier><language>eng</language><publisher>Berlin/Heidelberg: Springer Berlin Heidelberg</publisher><subject>Chemistry ; Chemistry and Materials Science ; Condensed Matter Physics ; Conducting polymers ; Differential scanning calorimetry ; Electrochemistry ; Electrolytes ; Energy Storage ; Glass transition temperature ; Heat measurement ; Ion currents ; Ionic liquids ; Ions ; Optical and Electronic Materials ; Original Paper ; Polymer blends ; Polyvinyl chloride ; Renewable and Green Energy ; Thermal stability ; Thermogravimetric analysis ; Voltammetry ; Zinc</subject><ispartof>Ionics, 2018-09, Vol.24 (9), p.2631-2646</ispartof><rights>Springer-Verlag GmbH Germany, part of Springer Nature 2018</rights><rights>Copyright Springer Science & Business Media 2018</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c316t-e883d36318d9edd72ce77a1f18def70a9664132b8cbc76b276e96334f2e210313</citedby><cites>FETCH-LOGICAL-c316t-e883d36318d9edd72ce77a1f18def70a9664132b8cbc76b276e96334f2e210313</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s11581-017-2421-2$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s11581-017-2421-2$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,778,782,27911,27912,41475,42544,51306</link.rule.ids></links><search><creatorcontrib>Prasanna, C. M. Sai</creatorcontrib><creatorcontrib>Suthanthiraraj, S. Austin</creatorcontrib><title>Dielectric and thermal features of zinc ion conducting gel polymer electrolytes (GPEs) containing PVC / PEMA blend and EMIMTFSI ionic liquid</title><title>Ionics</title><addtitle>Ionics</addtitle><description>A new series of gel polymer electrolytes (GPEs) based on an optimized composition of polymer blend-salt matrix [poly(vinyl chloride) (PVC) (30 wt%) / poly(ethyl methacrylate) (PEMA) (70 wt%): 30 wt% zinc triflate Zn(CF
3
SO
3
)
2
] containing different concentrations of 1-ethyl-3-methylimidazolium bis(trifluoromethylsulfonyl) imide (EMIMTFSI) ionic liquid has been prepared by simple solution casting technique. The prepared films of gel polymer membranes have been characterized utilizing complex impedance spectroscopy, differential scanning calorimetry (DSC), thermogravimetric (TG), and cyclic voltammetry (CV) analyses. The dielectric constant and ionic conductivity pursue similar trend with increasing EMIMTFSI concentration. The addition of ionic liquid in varied amounts into the optimized polymer blend-salt system effectively reduces the glass transition temperature (
T
g
) of the film as revealed from differential scanning calorimetry results. The origin of an improved thermal stability and feasible cyclic performance in respect of the best conducting sample of the resultant gel polymer electrolytes was also examined by utilizing thermogravimetric and cyclic voltammetry measurements.</description><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Condensed Matter Physics</subject><subject>Conducting polymers</subject><subject>Differential scanning calorimetry</subject><subject>Electrochemistry</subject><subject>Electrolytes</subject><subject>Energy Storage</subject><subject>Glass transition temperature</subject><subject>Heat measurement</subject><subject>Ion currents</subject><subject>Ionic liquids</subject><subject>Ions</subject><subject>Optical and Electronic Materials</subject><subject>Original Paper</subject><subject>Polymer blends</subject><subject>Polyvinyl chloride</subject><subject>Renewable and Green Energy</subject><subject>Thermal stability</subject><subject>Thermogravimetric analysis</subject><subject>Voltammetry</subject><subject>Zinc</subject><issn>0947-7047</issn><issn>1862-0760</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2018</creationdate><recordtype>article</recordtype><recordid>eNp1kEFLwzAYhoMoOKc_wFvAix7q8iU16Y5jbnOw4cDpNXTp15nRtVvSHuZv8EebUsGTp48Pnvd54SXkFtgjMKYGHuApgYiBinjMIeJnpAeJ5BFTkp2THhvGKlIsVpfkyvsdY1ICVz3y_WyxQFM7a2haZrT-RLdPC5pjWjcOPa1y-mVLQ21VUlOVWWNqW27pFgt6qIrTHh3tBOGpA38_W038Q4vWqS1bdPUxpgO6mixHdFNg6Gh7Jsv5cj19m7feUF3YY2Oza3KRp4XHm9_bJ-_TyXr8Ei1eZ_PxaBEZAbKOMElEJqSAJBtililuUKkU8vBjrlg6lDIGwTeJ2RglN1xJHEoh4pwjByZA9Mld5z246tigr_WualwZKjVnScIguGWgoKOMq7x3mOuDs_vUnTQw3Y6uu9F1GF23o2seMrzL-MCWW3R_5v9DPwx3g64</recordid><startdate>20180901</startdate><enddate>20180901</enddate><creator>Prasanna, C. M. Sai</creator><creator>Suthanthiraraj, S. Austin</creator><general>Springer Berlin Heidelberg</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20180901</creationdate><title>Dielectric and thermal features of zinc ion conducting gel polymer electrolytes (GPEs) containing PVC / PEMA blend and EMIMTFSI ionic liquid</title><author>Prasanna, C. M. Sai ; Suthanthiraraj, S. Austin</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c316t-e883d36318d9edd72ce77a1f18def70a9664132b8cbc76b276e96334f2e210313</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2018</creationdate><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Condensed Matter Physics</topic><topic>Conducting polymers</topic><topic>Differential scanning calorimetry</topic><topic>Electrochemistry</topic><topic>Electrolytes</topic><topic>Energy Storage</topic><topic>Glass transition temperature</topic><topic>Heat measurement</topic><topic>Ion currents</topic><topic>Ionic liquids</topic><topic>Ions</topic><topic>Optical and Electronic Materials</topic><topic>Original Paper</topic><topic>Polymer blends</topic><topic>Polyvinyl chloride</topic><topic>Renewable and Green Energy</topic><topic>Thermal stability</topic><topic>Thermogravimetric analysis</topic><topic>Voltammetry</topic><topic>Zinc</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Prasanna, C. M. Sai</creatorcontrib><creatorcontrib>Suthanthiraraj, S. Austin</creatorcontrib><collection>CrossRef</collection><jtitle>Ionics</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Prasanna, C. M. Sai</au><au>Suthanthiraraj, S. Austin</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Dielectric and thermal features of zinc ion conducting gel polymer electrolytes (GPEs) containing PVC / PEMA blend and EMIMTFSI ionic liquid</atitle><jtitle>Ionics</jtitle><stitle>Ionics</stitle><date>2018-09-01</date><risdate>2018</risdate><volume>24</volume><issue>9</issue><spage>2631</spage><epage>2646</epage><pages>2631-2646</pages><issn>0947-7047</issn><eissn>1862-0760</eissn><abstract>A new series of gel polymer electrolytes (GPEs) based on an optimized composition of polymer blend-salt matrix [poly(vinyl chloride) (PVC) (30 wt%) / poly(ethyl methacrylate) (PEMA) (70 wt%): 30 wt% zinc triflate Zn(CF
3
SO
3
)
2
] containing different concentrations of 1-ethyl-3-methylimidazolium bis(trifluoromethylsulfonyl) imide (EMIMTFSI) ionic liquid has been prepared by simple solution casting technique. The prepared films of gel polymer membranes have been characterized utilizing complex impedance spectroscopy, differential scanning calorimetry (DSC), thermogravimetric (TG), and cyclic voltammetry (CV) analyses. The dielectric constant and ionic conductivity pursue similar trend with increasing EMIMTFSI concentration. The addition of ionic liquid in varied amounts into the optimized polymer blend-salt system effectively reduces the glass transition temperature (
T
g
) of the film as revealed from differential scanning calorimetry results. The origin of an improved thermal stability and feasible cyclic performance in respect of the best conducting sample of the resultant gel polymer electrolytes was also examined by utilizing thermogravimetric and cyclic voltammetry measurements.</abstract><cop>Berlin/Heidelberg</cop><pub>Springer Berlin Heidelberg</pub><doi>10.1007/s11581-017-2421-2</doi><tpages>16</tpages></addata></record> |
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| ispartof | Ionics, 2018-09, Vol.24 (9), p.2631-2646 |
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| source | Springer Nature - Complete Springer Journals |
| subjects | Chemistry Chemistry and Materials Science Condensed Matter Physics Conducting polymers Differential scanning calorimetry Electrochemistry Electrolytes Energy Storage Glass transition temperature Heat measurement Ion currents Ionic liquids Ions Optical and Electronic Materials Original Paper Polymer blends Polyvinyl chloride Renewable and Green Energy Thermal stability Thermogravimetric analysis Voltammetry Zinc |
| title | Dielectric and thermal features of zinc ion conducting gel polymer electrolytes (GPEs) containing PVC / PEMA blend and EMIMTFSI ionic liquid |
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