Selective and sensitive morpholine-type rhodamine B-based colorimetric and fluorescent chemosensor for Fe(III) and Fe(II)
[Display omitted] •Rhodamine B derivatives bearing a morpholine-type 6-membered ring were synthesized.•Fluorescence sensitivities for metal ions, e.g., Fe2+ and Fe3+, were investigated.•Rh-OS, Rh-OO, and Rh-SO exhibited high sensitivity to Fe2+ and Fe3+.•Job’s plot indicated the formation of a 1:1 (...
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| Veröffentlicht in: | Sensors and actuators. B, Chemical Chemical, 2017-09, Vol.248, p.646-656 |
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| container_title | Sensors and actuators. B, Chemical |
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| creator | Lee, Sanghyuck Jang, Hoeun Lee, Jisuk Jeon, Sun Hee Sohn, Youngku Ra, Choon Sup |
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•Rhodamine B derivatives bearing a morpholine-type 6-membered ring were synthesized.•Fluorescence sensitivities for metal ions, e.g., Fe2+ and Fe3+, were investigated.•Rh-OS, Rh-OO, and Rh-SO exhibited high sensitivity to Fe2+ and Fe3+.•Job’s plot indicated the formation of a 1:1 (ligand:metal) complex.•2D and 3D photoluminescence imaging was used for selection of Fe2+ and Fe3+.
The development of chemosensor materials is crucial for the early detection of hazardous materials, such as heavy metal ions and infectious viruses. In this study, three rhodamine B (RhB) derivatives (referred to as Rh-OS, Rh-OO, and Rh-SO) bearing a morpholine-type 6-membered ring as colorimetric, fluorescent sensors were synthesized, and fluorescence responses to various metal ions (Fe3+, Fe2+, Pb2+, Cr6+, Ce2+, Mn2+, Cd2+, Hg2+, K+, Na+, Mg2+, Li+, Ca2+, As3+, Co2+, Cu2+, Ni2+, and Zn2+) were investigated. Rh-OS, Rh-OO, and Rh-SO exhibited high sensitivity to Fe2+ and Fe3+, with the formation of a 1:1 (ligand: metal) complex, as evidenced by the UV–vis absorption and photoluminescence spectra. Luminescence turn-on was explained by the transfer of resonance energy from the morpholine-type moiety to the RhB framework. In addition, the selectivity of Fe3+ and Fe2+ was evaluated by 2D and 3D photoluminescence imaging. |
| doi_str_mv | 10.1016/j.snb.2017.04.046 |
| format | Article |
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•Rhodamine B derivatives bearing a morpholine-type 6-membered ring were synthesized.•Fluorescence sensitivities for metal ions, e.g., Fe2+ and Fe3+, were investigated.•Rh-OS, Rh-OO, and Rh-SO exhibited high sensitivity to Fe2+ and Fe3+.•Job’s plot indicated the formation of a 1:1 (ligand:metal) complex.•2D and 3D photoluminescence imaging was used for selection of Fe2+ and Fe3+.
The development of chemosensor materials is crucial for the early detection of hazardous materials, such as heavy metal ions and infectious viruses. In this study, three rhodamine B (RhB) derivatives (referred to as Rh-OS, Rh-OO, and Rh-SO) bearing a morpholine-type 6-membered ring as colorimetric, fluorescent sensors were synthesized, and fluorescence responses to various metal ions (Fe3+, Fe2+, Pb2+, Cr6+, Ce2+, Mn2+, Cd2+, Hg2+, K+, Na+, Mg2+, Li+, Ca2+, As3+, Co2+, Cu2+, Ni2+, and Zn2+) were investigated. Rh-OS, Rh-OO, and Rh-SO exhibited high sensitivity to Fe2+ and Fe3+, with the formation of a 1:1 (ligand: metal) complex, as evidenced by the UV–vis absorption and photoluminescence spectra. Luminescence turn-on was explained by the transfer of resonance energy from the morpholine-type moiety to the RhB framework. In addition, the selectivity of Fe3+ and Fe2+ was evaluated by 2D and 3D photoluminescence imaging.</description><identifier>ISSN: 0925-4005</identifier><identifier>EISSN: 1873-3077</identifier><identifier>DOI: 10.1016/j.snb.2017.04.046</identifier><language>eng</language><publisher>Lausanne: Elsevier B.V</publisher><subject>Arsenic ions ; Calcium ions ; Chemical compounds ; Chemical sensors ; Chemical synthesis ; Chemoreceptors ; Chemosensor ; Cobalt ; Colorimetry ; Coordination compounds ; Copper ; Fe ion sensitivity ; Ferric ions ; Ferrous ions ; Fluorescence ; Hazardous materials ; Heavy metals ; Iron ; Lead ; Luminescence ; Mercury (metal) ; Metal ions ; Morpholine ; Morpholine-type moiety ; Photoluminescence ; Photoluminescence imaging ; Rhodamine ; Rhodamine derivative ; Selectivity ; Sensors ; Spectrum analysis</subject><ispartof>Sensors and actuators. B, Chemical, 2017-09, Vol.248, p.646-656</ispartof><rights>2017 Elsevier B.V.</rights><rights>Copyright Elsevier Science Ltd. Sep 2017</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c366t-f75a9490fd6c2a4ec2a1f0980a29e2565ed380253be2cf79b3f7ab30b87fa3fd3</citedby><cites>FETCH-LOGICAL-c366t-f75a9490fd6c2a4ec2a1f0980a29e2565ed380253be2cf79b3f7ab30b87fa3fd3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://dx.doi.org/10.1016/j.snb.2017.04.046$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>314,780,784,3550,27924,27925,45995</link.rule.ids></links><search><creatorcontrib>Lee, Sanghyuck</creatorcontrib><creatorcontrib>Jang, Hoeun</creatorcontrib><creatorcontrib>Lee, Jisuk</creatorcontrib><creatorcontrib>Jeon, Sun Hee</creatorcontrib><creatorcontrib>Sohn, Youngku</creatorcontrib><creatorcontrib>Ra, Choon Sup</creatorcontrib><title>Selective and sensitive morpholine-type rhodamine B-based colorimetric and fluorescent chemosensor for Fe(III) and Fe(II)</title><title>Sensors and actuators. B, Chemical</title><description>[Display omitted]
•Rhodamine B derivatives bearing a morpholine-type 6-membered ring were synthesized.•Fluorescence sensitivities for metal ions, e.g., Fe2+ and Fe3+, were investigated.•Rh-OS, Rh-OO, and Rh-SO exhibited high sensitivity to Fe2+ and Fe3+.•Job’s plot indicated the formation of a 1:1 (ligand:metal) complex.•2D and 3D photoluminescence imaging was used for selection of Fe2+ and Fe3+.
The development of chemosensor materials is crucial for the early detection of hazardous materials, such as heavy metal ions and infectious viruses. In this study, three rhodamine B (RhB) derivatives (referred to as Rh-OS, Rh-OO, and Rh-SO) bearing a morpholine-type 6-membered ring as colorimetric, fluorescent sensors were synthesized, and fluorescence responses to various metal ions (Fe3+, Fe2+, Pb2+, Cr6+, Ce2+, Mn2+, Cd2+, Hg2+, K+, Na+, Mg2+, Li+, Ca2+, As3+, Co2+, Cu2+, Ni2+, and Zn2+) were investigated. Rh-OS, Rh-OO, and Rh-SO exhibited high sensitivity to Fe2+ and Fe3+, with the formation of a 1:1 (ligand: metal) complex, as evidenced by the UV–vis absorption and photoluminescence spectra. Luminescence turn-on was explained by the transfer of resonance energy from the morpholine-type moiety to the RhB framework. In addition, the selectivity of Fe3+ and Fe2+ was evaluated by 2D and 3D photoluminescence imaging.</description><subject>Arsenic ions</subject><subject>Calcium ions</subject><subject>Chemical compounds</subject><subject>Chemical sensors</subject><subject>Chemical synthesis</subject><subject>Chemoreceptors</subject><subject>Chemosensor</subject><subject>Cobalt</subject><subject>Colorimetry</subject><subject>Coordination compounds</subject><subject>Copper</subject><subject>Fe ion sensitivity</subject><subject>Ferric ions</subject><subject>Ferrous ions</subject><subject>Fluorescence</subject><subject>Hazardous materials</subject><subject>Heavy metals</subject><subject>Iron</subject><subject>Lead</subject><subject>Luminescence</subject><subject>Mercury (metal)</subject><subject>Metal ions</subject><subject>Morpholine</subject><subject>Morpholine-type moiety</subject><subject>Photoluminescence</subject><subject>Photoluminescence imaging</subject><subject>Rhodamine</subject><subject>Rhodamine derivative</subject><subject>Selectivity</subject><subject>Sensors</subject><subject>Spectrum analysis</subject><issn>0925-4005</issn><issn>1873-3077</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2017</creationdate><recordtype>article</recordtype><recordid>eNp9UF1LwzAUDaLgnP4A3wq-6EPnTdKmLT7pcFoY-KA-hzS9YRldM5NusH9v1vks3E84534cQm4pzChQ8biehb6ZMaDFDLJo4oxMaFnwlENRnJMJVCxPM4D8klyFsAaAjAuYkMMndqgHu8dE9W0SsA927DbOb1eusz2mw2GLiV-5Vm1im7ykjQrYJtp1ztsNDt7qkWy6nfMYNPZDole4ccdpzicm-gLv67p-GHFj_XBNLozqAt785Sn5Xrx-zd_T5cdbPX9eppoLMaSmyFWVVWBaoZnKMAZqoCpBsQpZLnJseQks5w0ybYqq4aZQDYemLIzipuVTcneau_XuZ4dhkGu3831cKRmUouSM5lVE0RNKexeCRyO38TflD5KCPCos1zIqLI8KS8iiich5OnEwnr-36GXQFnuNrfVRU9k6-w_7FxhthMA</recordid><startdate>20170901</startdate><enddate>20170901</enddate><creator>Lee, Sanghyuck</creator><creator>Jang, Hoeun</creator><creator>Lee, Jisuk</creator><creator>Jeon, Sun Hee</creator><creator>Sohn, Youngku</creator><creator>Ra, Choon Sup</creator><general>Elsevier B.V</general><general>Elsevier Science Ltd</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SP</scope><scope>7SR</scope><scope>7TB</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>FR3</scope><scope>JG9</scope><scope>L7M</scope></search><sort><creationdate>20170901</creationdate><title>Selective and sensitive morpholine-type rhodamine B-based colorimetric and fluorescent chemosensor for Fe(III) and Fe(II)</title><author>Lee, Sanghyuck ; Jang, Hoeun ; Lee, Jisuk ; Jeon, Sun Hee ; Sohn, Youngku ; Ra, Choon Sup</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c366t-f75a9490fd6c2a4ec2a1f0980a29e2565ed380253be2cf79b3f7ab30b87fa3fd3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2017</creationdate><topic>Arsenic ions</topic><topic>Calcium ions</topic><topic>Chemical compounds</topic><topic>Chemical sensors</topic><topic>Chemical synthesis</topic><topic>Chemoreceptors</topic><topic>Chemosensor</topic><topic>Cobalt</topic><topic>Colorimetry</topic><topic>Coordination compounds</topic><topic>Copper</topic><topic>Fe ion sensitivity</topic><topic>Ferric ions</topic><topic>Ferrous ions</topic><topic>Fluorescence</topic><topic>Hazardous materials</topic><topic>Heavy metals</topic><topic>Iron</topic><topic>Lead</topic><topic>Luminescence</topic><topic>Mercury (metal)</topic><topic>Metal ions</topic><topic>Morpholine</topic><topic>Morpholine-type moiety</topic><topic>Photoluminescence</topic><topic>Photoluminescence imaging</topic><topic>Rhodamine</topic><topic>Rhodamine derivative</topic><topic>Selectivity</topic><topic>Sensors</topic><topic>Spectrum analysis</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Lee, Sanghyuck</creatorcontrib><creatorcontrib>Jang, Hoeun</creatorcontrib><creatorcontrib>Lee, Jisuk</creatorcontrib><creatorcontrib>Jeon, Sun Hee</creatorcontrib><creatorcontrib>Sohn, Youngku</creatorcontrib><creatorcontrib>Ra, Choon Sup</creatorcontrib><collection>CrossRef</collection><collection>Electronics & Communications Abstracts</collection><collection>Engineered Materials Abstracts</collection><collection>Mechanical & Transportation Engineering Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Engineering Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Sensors and actuators. B, Chemical</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Lee, Sanghyuck</au><au>Jang, Hoeun</au><au>Lee, Jisuk</au><au>Jeon, Sun Hee</au><au>Sohn, Youngku</au><au>Ra, Choon Sup</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Selective and sensitive morpholine-type rhodamine B-based colorimetric and fluorescent chemosensor for Fe(III) and Fe(II)</atitle><jtitle>Sensors and actuators. B, Chemical</jtitle><date>2017-09-01</date><risdate>2017</risdate><volume>248</volume><spage>646</spage><epage>656</epage><pages>646-656</pages><issn>0925-4005</issn><eissn>1873-3077</eissn><abstract>[Display omitted]
•Rhodamine B derivatives bearing a morpholine-type 6-membered ring were synthesized.•Fluorescence sensitivities for metal ions, e.g., Fe2+ and Fe3+, were investigated.•Rh-OS, Rh-OO, and Rh-SO exhibited high sensitivity to Fe2+ and Fe3+.•Job’s plot indicated the formation of a 1:1 (ligand:metal) complex.•2D and 3D photoluminescence imaging was used for selection of Fe2+ and Fe3+.
The development of chemosensor materials is crucial for the early detection of hazardous materials, such as heavy metal ions and infectious viruses. In this study, three rhodamine B (RhB) derivatives (referred to as Rh-OS, Rh-OO, and Rh-SO) bearing a morpholine-type 6-membered ring as colorimetric, fluorescent sensors were synthesized, and fluorescence responses to various metal ions (Fe3+, Fe2+, Pb2+, Cr6+, Ce2+, Mn2+, Cd2+, Hg2+, K+, Na+, Mg2+, Li+, Ca2+, As3+, Co2+, Cu2+, Ni2+, and Zn2+) were investigated. Rh-OS, Rh-OO, and Rh-SO exhibited high sensitivity to Fe2+ and Fe3+, with the formation of a 1:1 (ligand: metal) complex, as evidenced by the UV–vis absorption and photoluminescence spectra. Luminescence turn-on was explained by the transfer of resonance energy from the morpholine-type moiety to the RhB framework. In addition, the selectivity of Fe3+ and Fe2+ was evaluated by 2D and 3D photoluminescence imaging.</abstract><cop>Lausanne</cop><pub>Elsevier B.V</pub><doi>10.1016/j.snb.2017.04.046</doi><tpages>11</tpages></addata></record> |
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| subjects | Arsenic ions Calcium ions Chemical compounds Chemical sensors Chemical synthesis Chemoreceptors Chemosensor Cobalt Colorimetry Coordination compounds Copper Fe ion sensitivity Ferric ions Ferrous ions Fluorescence Hazardous materials Heavy metals Iron Lead Luminescence Mercury (metal) Metal ions Morpholine Morpholine-type moiety Photoluminescence Photoluminescence imaging Rhodamine Rhodamine derivative Selectivity Sensors Spectrum analysis |
| title | Selective and sensitive morpholine-type rhodamine B-based colorimetric and fluorescent chemosensor for Fe(III) and Fe(II) |
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