C^sub 1^-symmetrical cis-bis(di-2-pyridylamine)chloro(dimethyl sulfoxide-S)ruthenium(II) complex: Synthesis, crystal structure, and anion recognition using the NH groups in the chelating ligands

The C1-symmetrical cis-bis(Hdpa)Ru(II) complex, cis-[RuCl(Hdpa)2(dmso-S)]X (1·X; X = Cl or OTf, Hdpa = di-2-pyridylamine, dmso = dimethyl sulfoxide, OTf− = CF3SO3−), was synthesized and spectroscopically and crystallographically characterized. The crystal structures of 1·Cl and 1·(OTf) revealed that...

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