Design for a small molecule based chemosensor containing boron and pyridine moieties to detect HF

[Display omitted] •A novel triarylborane compound 1 is reported for detection of HF with high sensitivity and selectivity.•The appended pyridyl groups were efficiently enhanced the complexation ability of 1 towards HF.•The spin-coated compound 1 film was applied to detect HF gas via a unique capacit...

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Veröffentlicht in:Sensors and actuators. B, Chemical Chemical, 2018-02, Vol.255, p.2621-2627
Hauptverfasser: Hu, Ying, Kye, Mahnseok, Jung, Ji Young, Lim, Yong-beom, Yoon, Juyoung
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container_title Sensors and actuators. B, Chemical
container_volume 255
creator Hu, Ying
Kye, Mahnseok
Jung, Ji Young
Lim, Yong-beom
Yoon, Juyoung
description [Display omitted] •A novel triarylborane compound 1 is reported for detection of HF with high sensitivity and selectivity.•The appended pyridyl groups were efficiently enhanced the complexation ability of 1 towards HF.•The spin-coated compound 1 film was applied to detect HF gas via a unique capacitance change within a fast response time. A new triarylborane compound 1 is described as fluorescent probe for HF gas with high sensitivity and selectivity. The system utilized the coordination of a fluoride ion to the boron center in 1 to cause perturbation in the energy transfer pathway and the π conjugation, which induced distinct fluorescent quenching. A probe 1-coated film was further applied to detect HF gas via a unique capacitance change.
doi_str_mv 10.1016/j.snb.2017.09.072
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subjects Boron
Boron compounds
Chemical sensors
Chemoreceptors
Conjugation
Fluorescence
Fluorescent chemosensor
Fluorescent indicators
Fluorides
HF sensor
Molecules
Organic chemicals
Sensors
Spin-coating
Triarylborane
title Design for a small molecule based chemosensor containing boron and pyridine moieties to detect HF
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