Metal‐coordinated Hydroxide as a Nucleophile: a Brief History
It is well known that a metal‐bound hydroxido ligand is an efficient nucleophile around neutral pH. In a mechanistic sense, the presence and chemical reactivity of the coordinated hydroxido nucleophile are frequently invoked both in biomimetic chemistry and in numerous examples of hydrolytic metallo...
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| Veröffentlicht in: | Zeitschrift für anorganische und allgemeine Chemie (1950) 2018-08, Vol.644 (14), p.616-629 |
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| container_title | Zeitschrift für anorganische und allgemeine Chemie (1950) |
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| creator | Blackman, Allan G. Gahan, Lawrence R. |
| description | It is well known that a metal‐bound hydroxido ligand is an efficient nucleophile around neutral pH. In a mechanistic sense, the presence and chemical reactivity of the coordinated hydroxido nucleophile are frequently invoked both in biomimetic chemistry and in numerous examples of hydrolytic metalloenzymes. In this review, we explore the background of this chemistry in order to attempt to trace the thinking which led to what is now a fully accepted mechanistic pathway. |
| doi_str_mv | 10.1002/zaac.201800045 |
| format | Article |
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In this review, we explore the background of this chemistry in order to attempt to trace the thinking which led to what is now a fully accepted mechanistic pathway.</description><subject>Biomimetics</subject><subject>Ligand</subject><subject>Mechanism</subject><subject>Metal‐coordinated hydroxide</subject><subject>Model complexes</subject><subject>Nucleophile</subject><subject>Organic chemistry</subject><issn>0044-2313</issn><issn>1521-3749</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2018</creationdate><recordtype>article</recordtype><recordid>eNqFkL9OwzAQxi0EEqWwMkdiTjnbcWKzoFIVilRggYXFcvxHpAp1sVNBmHgEnpEnwVURjEynu_t99-k-hI4xjDAAOX1XSo8IYA4ABdtBA8wIzmlViF00SKMiJxTTfXQQ4yIhGBgboPMb26n26-NTex9Ms1SdNdmsN8G_NcZmKmYqu13r1vrVU9Pas9RehMa6bNbEzof-EO051UZ79FOH6OFyej-Z5fO7q-vJeJ5riiuWl0DrigImVqkatCPgSGVcZYwzhnFScEEoTwtaKm4KYYqScVeLsubCaYXpEJ1s766Cf1nb2MmFX4dlspQEKsGBMiYSNdpSOvgYg3VyFZpnFXqJQW5CkpuQ5G9ISSC2gtf0XP8PLR_H48mf9htjTWs1</recordid><startdate>20180802</startdate><enddate>20180802</enddate><creator>Blackman, Allan G.</creator><creator>Gahan, Lawrence R.</creator><general>Wiley Subscription Services, Inc</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20180802</creationdate><title>Metal‐coordinated Hydroxide as a Nucleophile: a Brief History</title><author>Blackman, Allan G. ; Gahan, Lawrence R.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c3175-603b73012eaab0cf20f27df7ddfdd5824892380cf36a8d49d4658fb96b89fca13</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2018</creationdate><topic>Biomimetics</topic><topic>Ligand</topic><topic>Mechanism</topic><topic>Metal‐coordinated hydroxide</topic><topic>Model complexes</topic><topic>Nucleophile</topic><topic>Organic chemistry</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Blackman, Allan G.</creatorcontrib><creatorcontrib>Gahan, Lawrence R.</creatorcontrib><collection>CrossRef</collection><jtitle>Zeitschrift für anorganische und allgemeine Chemie (1950)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Blackman, Allan G.</au><au>Gahan, Lawrence R.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Metal‐coordinated Hydroxide as a Nucleophile: a Brief History</atitle><jtitle>Zeitschrift für anorganische und allgemeine Chemie (1950)</jtitle><date>2018-08-02</date><risdate>2018</risdate><volume>644</volume><issue>14</issue><spage>616</spage><epage>629</epage><pages>616-629</pages><issn>0044-2313</issn><eissn>1521-3749</eissn><abstract>It is well known that a metal‐bound hydroxido ligand is an efficient nucleophile around neutral pH. 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| ispartof | Zeitschrift für anorganische und allgemeine Chemie (1950), 2018-08, Vol.644 (14), p.616-629 |
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| source | Wiley-Blackwell Journals |
| subjects | Biomimetics Ligand Mechanism Metal‐coordinated hydroxide Model complexes Nucleophile Organic chemistry |
| title | Metal‐coordinated Hydroxide as a Nucleophile: a Brief History |
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