[Ru(tpy)(bpy)Cl]-Catalyzed reduction of carbon dioxide. Mechanistic insights by carbon-13 kinetic isotope effects

In this work, we examine the use of competitive 13 C kinetic isotope effects ( 13 C KIEs) on CO 2 reduction reactions that produce CO and formic acid as a means to formulate reaction mechanisms. The findings reported here mark a further advancement in the combined 13 C KIE measurements and theoretic...

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Veröffentlicht in:	Chemical communications (Cambridge, England) England), 2018, Vol.54 (61), p.8518-8521
Hauptverfasser:	Schneider, T. W, Hren, M. T, Ertem, M. Z, Angeles-Boza, A. M
Format:	Artikel
Sprache:	eng
Schlagworte:	Carbon 13 Carbon dioxide Carbon monoxide Chemical reduction Formic acid INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY Isotopes Reaction mechanisms
Online-Zugang:	Volltext
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