Efficient Solar‐Assisted O2 Reduction Using a Cofacial Iron Porphyrin Dimer Catalyst Integrated into a p‐CuBi2O4 Photocathode
A cofacial iron porphyrin heterodimer, Fe2TPFPP‐TMP showed high electrocatalytic activity, selectivity, and stability for O2 reduction to H2O both in homogeneous non‐aqueous and heterogeneous neutral aqueous solutions. When it is integrated to FTO/p‐CuBi2O4 (FTO=fluorine doped tin oxide) photocathod...
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| Veröffentlicht in: | Chemistry : a European journal 2018-07, Vol.24 (42), p.10606-10611 |
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| container_issue | 42 |
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| container_title | Chemistry : a European journal |
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| creator | Zahran, Zaki N. Mohamed, Eman A. Haleem, Ashraf Abdel Naruta, Yoshinori |
| description | A cofacial iron porphyrin heterodimer, Fe2TPFPP‐TMP showed high electrocatalytic activity, selectivity, and stability for O2 reduction to H2O both in homogeneous non‐aqueous and heterogeneous neutral aqueous solutions. When it is integrated to FTO/p‐CuBi2O4 (FTO=fluorine doped tin oxide) photocathode prepared by a simple novel method, a remarkable efficient solar‐assisted O2 reduction is achieved in neutral potassium phosphate (KPi) or basic NaOH solutions saturated with O2.
An efficient cofacial Fe porphyrin heterodimer catalyst was integrated into the FTO/p‐CuBi2O4 photocathode to achieve efficient solar‐assisted O2 reduction in both neutral and basic media. |
| doi_str_mv | 10.1002/chem.201704143 |
| format | Article |
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An efficient cofacial Fe porphyrin heterodimer catalyst was integrated into the FTO/p‐CuBi2O4 photocathode to achieve efficient solar‐assisted O2 reduction in both neutral and basic media.</description><identifier>ISSN: 0947-6539</identifier><identifier>EISSN: 1521-3765</identifier><identifier>DOI: 10.1002/chem.201704143</identifier><language>eng</language><publisher>Weinheim: Wiley Subscription Services, Inc</publisher><subject>Chemistry ; copper ; Dimers ; electrocatalysis ; Fluorine ; Iron ; iron porphyrin ; oxygen reduction ; photocatalysis ; Photocathodes ; Potassium ; Potassium phosphate ; Potassium phosphates ; Reduction ; Sodium hydroxide ; Tin ; Tin oxide ; Tin oxides</subject><ispartof>Chemistry : a European journal, 2018-07, Vol.24 (42), p.10606-10611</ispartof><rights>2018 Wiley‐VCH Verlag GmbH & Co. KGaA, Weinheim</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><orcidid>0000-0003-0371-1089</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fchem.201704143$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fchem.201704143$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,776,780,1411,27901,27902,45550,45551</link.rule.ids></links><search><creatorcontrib>Zahran, Zaki N.</creatorcontrib><creatorcontrib>Mohamed, Eman A.</creatorcontrib><creatorcontrib>Haleem, Ashraf Abdel</creatorcontrib><creatorcontrib>Naruta, Yoshinori</creatorcontrib><title>Efficient Solar‐Assisted O2 Reduction Using a Cofacial Iron Porphyrin Dimer Catalyst Integrated into a p‐CuBi2O4 Photocathode</title><title>Chemistry : a European journal</title><description>A cofacial iron porphyrin heterodimer, Fe2TPFPP‐TMP showed high electrocatalytic activity, selectivity, and stability for O2 reduction to H2O both in homogeneous non‐aqueous and heterogeneous neutral aqueous solutions. When it is integrated to FTO/p‐CuBi2O4 (FTO=fluorine doped tin oxide) photocathode prepared by a simple novel method, a remarkable efficient solar‐assisted O2 reduction is achieved in neutral potassium phosphate (KPi) or basic NaOH solutions saturated with O2.
An efficient cofacial Fe porphyrin heterodimer catalyst was integrated into the FTO/p‐CuBi2O4 photocathode to achieve efficient solar‐assisted O2 reduction in both neutral and basic media.</description><subject>Chemistry</subject><subject>copper</subject><subject>Dimers</subject><subject>electrocatalysis</subject><subject>Fluorine</subject><subject>Iron</subject><subject>iron porphyrin</subject><subject>oxygen reduction</subject><subject>photocatalysis</subject><subject>Photocathodes</subject><subject>Potassium</subject><subject>Potassium phosphate</subject><subject>Potassium phosphates</subject><subject>Reduction</subject><subject>Sodium hydroxide</subject><subject>Tin</subject><subject>Tin oxide</subject><subject>Tin oxides</subject><issn>0947-6539</issn><issn>1521-3765</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2018</creationdate><recordtype>article</recordtype><recordid>eNo9kMFOAjEQhhujiYhePTfxvDhtt9vdI64oJBiIynlTdlsoWbbYdmO46Rv4jD6JSzCcJjP55p_Mh9AtgQEBoPflWm0HFIiAmMTsDPUIpyRiIuHnqAdZLKKEs-wSXXm_AYAsYayHvkdam9KoJuA3W0v3-_Uz9N74oCo8o_hVVW0ZjG3wwptmhSXOrZalkTWeuG46t2633jvT4EezVQ7nMsh67wOeNEGtnDzEmCbYbnHXReftg6GzGM_XNthShrWt1DW60LL26ua_9tHiafSej6Pp7HmSD6fRigpg0TKugItUiaRUS7KUkgqtS0ilAk3KZcwJ54wLRjTXKe1-A0JSKlNKE50lGWN9dHfM3Tn70Sofio1tXdOdLCiIBDqaxh2VHalPU6t9sXNmK92-IFAcHBcHx8XJcZGPRy-njv0Bc99z9A</recordid><startdate>20180725</startdate><enddate>20180725</enddate><creator>Zahran, Zaki N.</creator><creator>Mohamed, Eman A.</creator><creator>Haleem, Ashraf Abdel</creator><creator>Naruta, Yoshinori</creator><general>Wiley Subscription Services, Inc</general><scope>7SR</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>K9.</scope><orcidid>https://orcid.org/0000-0003-0371-1089</orcidid></search><sort><creationdate>20180725</creationdate><title>Efficient Solar‐Assisted O2 Reduction Using a Cofacial Iron Porphyrin Dimer Catalyst Integrated into a p‐CuBi2O4 Photocathode</title><author>Zahran, Zaki N. ; Mohamed, Eman A. ; Haleem, Ashraf Abdel ; Naruta, Yoshinori</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-g2703-b4d0578e76ceb1baa27ffc08ae0f1cb4515535731f5f8263301182a8226f96933</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2018</creationdate><topic>Chemistry</topic><topic>copper</topic><topic>Dimers</topic><topic>electrocatalysis</topic><topic>Fluorine</topic><topic>Iron</topic><topic>iron porphyrin</topic><topic>oxygen reduction</topic><topic>photocatalysis</topic><topic>Photocathodes</topic><topic>Potassium</topic><topic>Potassium phosphate</topic><topic>Potassium phosphates</topic><topic>Reduction</topic><topic>Sodium hydroxide</topic><topic>Tin</topic><topic>Tin oxide</topic><topic>Tin oxides</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Zahran, Zaki N.</creatorcontrib><creatorcontrib>Mohamed, Eman A.</creatorcontrib><creatorcontrib>Haleem, Ashraf Abdel</creatorcontrib><creatorcontrib>Naruta, Yoshinori</creatorcontrib><collection>Engineered Materials Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>ProQuest Health & Medical Complete (Alumni)</collection><jtitle>Chemistry : a European journal</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Zahran, Zaki N.</au><au>Mohamed, Eman A.</au><au>Haleem, Ashraf Abdel</au><au>Naruta, Yoshinori</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Efficient Solar‐Assisted O2 Reduction Using a Cofacial Iron Porphyrin Dimer Catalyst Integrated into a p‐CuBi2O4 Photocathode</atitle><jtitle>Chemistry : a European journal</jtitle><date>2018-07-25</date><risdate>2018</risdate><volume>24</volume><issue>42</issue><spage>10606</spage><epage>10611</epage><pages>10606-10611</pages><issn>0947-6539</issn><eissn>1521-3765</eissn><abstract>A cofacial iron porphyrin heterodimer, Fe2TPFPP‐TMP showed high electrocatalytic activity, selectivity, and stability for O2 reduction to H2O both in homogeneous non‐aqueous and heterogeneous neutral aqueous solutions. When it is integrated to FTO/p‐CuBi2O4 (FTO=fluorine doped tin oxide) photocathode prepared by a simple novel method, a remarkable efficient solar‐assisted O2 reduction is achieved in neutral potassium phosphate (KPi) or basic NaOH solutions saturated with O2.
An efficient cofacial Fe porphyrin heterodimer catalyst was integrated into the FTO/p‐CuBi2O4 photocathode to achieve efficient solar‐assisted O2 reduction in both neutral and basic media.</abstract><cop>Weinheim</cop><pub>Wiley Subscription Services, Inc</pub><doi>10.1002/chem.201704143</doi><tpages>6</tpages><orcidid>https://orcid.org/0000-0003-0371-1089</orcidid></addata></record> |
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| ispartof | Chemistry : a European journal, 2018-07, Vol.24 (42), p.10606-10611 |
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| source | Wiley Online Library Journals Frontfile Complete |
| subjects | Chemistry copper Dimers electrocatalysis Fluorine Iron iron porphyrin oxygen reduction photocatalysis Photocathodes Potassium Potassium phosphate Potassium phosphates Reduction Sodium hydroxide Tin Tin oxide Tin oxides |
| title | Efficient Solar‐Assisted O2 Reduction Using a Cofacial Iron Porphyrin Dimer Catalyst Integrated into a p‐CuBi2O4 Photocathode |
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