Acidic ionic liquids: an alternative to HF for {001} reactive facet controlled synthesis of anatase titania
This is a report on the facet controlled synthesis of TiO 2 , which has been achieved using the acidic room temperature ionic liquids (AILs) 1-butyl-3-methylimidazolium hydrogen sulphate and 3-methyl-1-(3-sulfonyl propyl)imidazolium trifluoro methane sulphonate as the templating and hydrolysing agen...
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| Veröffentlicht in: | New journal of chemistry 2018, Vol.42 (15), p.12762-12765 |
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| container_end_page | 12765 |
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| container_issue | 15 |
| container_start_page | 12762 |
| container_title | New journal of chemistry |
| container_volume | 42 |
| creator | Sandhu, Sofia Shahi, Satwant Kaur Singh, Vasundhara |
| description | This is a report on the facet controlled synthesis of TiO
2
, which has been achieved using the acidic room temperature ionic liquids (AILs) 1-butyl-3-methylimidazolium hydrogen sulphate and 3-methyl-1-(3-sulfonyl propyl)imidazolium trifluoro methane sulphonate as the templating and hydrolysing agents. The effect of the change of concentration of the AIL, amount of the AIL and calcination temperature demonstrated good phase control and a higher number of exposed {001} facets in the TiO
2
nanocatalysts with a higher photocatalytic activity. |
| doi_str_mv | 10.1039/C8NJ01481G |
| format | Article |
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2
, which has been achieved using the acidic room temperature ionic liquids (AILs) 1-butyl-3-methylimidazolium hydrogen sulphate and 3-methyl-1-(3-sulfonyl propyl)imidazolium trifluoro methane sulphonate as the templating and hydrolysing agents. The effect of the change of concentration of the AIL, amount of the AIL and calcination temperature demonstrated good phase control and a higher number of exposed {001} facets in the TiO
2
nanocatalysts with a higher photocatalytic activity.</description><identifier>ISSN: 1144-0546</identifier><identifier>EISSN: 1369-9261</identifier><identifier>DOI: 10.1039/C8NJ01481G</identifier><language>eng</language><publisher>Cambridge: Royal Society of Chemistry</publisher><subject>Anatase ; Catalytic activity ; Ionic liquids ; Ions ; Phase control ; Photocatalysis ; Solvents ; Synthesis ; Titanium dioxide</subject><ispartof>New journal of chemistry, 2018, Vol.42 (15), p.12762-12765</ispartof><rights>Copyright Royal Society of Chemistry 2018</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c259t-832f2839103e08712ec030842146aedeedc201671880579ad17a91f4df98d13c3</citedby><cites>FETCH-LOGICAL-c259t-832f2839103e08712ec030842146aedeedc201671880579ad17a91f4df98d13c3</cites><orcidid>0000-0002-5819-4579</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,776,780,4010,27900,27901,27902</link.rule.ids></links><search><creatorcontrib>Sandhu, Sofia</creatorcontrib><creatorcontrib>Shahi, Satwant Kaur</creatorcontrib><creatorcontrib>Singh, Vasundhara</creatorcontrib><title>Acidic ionic liquids: an alternative to HF for {001} reactive facet controlled synthesis of anatase titania</title><title>New journal of chemistry</title><description>This is a report on the facet controlled synthesis of TiO
2
, which has been achieved using the acidic room temperature ionic liquids (AILs) 1-butyl-3-methylimidazolium hydrogen sulphate and 3-methyl-1-(3-sulfonyl propyl)imidazolium trifluoro methane sulphonate as the templating and hydrolysing agents. The effect of the change of concentration of the AIL, amount of the AIL and calcination temperature demonstrated good phase control and a higher number of exposed {001} facets in the TiO
2
nanocatalysts with a higher photocatalytic activity.</description><subject>Anatase</subject><subject>Catalytic activity</subject><subject>Ionic liquids</subject><subject>Ions</subject><subject>Phase control</subject><subject>Photocatalysis</subject><subject>Solvents</subject><subject>Synthesis</subject><subject>Titanium dioxide</subject><issn>1144-0546</issn><issn>1369-9261</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2018</creationdate><recordtype>article</recordtype><recordid>eNpFUE1LAzEUDKJgrV78BQFvwmpekt1NvJViW6XoRc9LyAemrps2SYUi_e9GK3iZN_BmBmYQugRyA4TJ26l4eiTABcyP0AhYIytJGzguHDivSM2bU3SW0ooQgLaBEXqfaG-8xj4MBXu_2XqT7rAasOqzjYPK_tPiHPBihl2I-Ks49zhapX8fTmmbsQ5DjqHvrcFpN-Q3m3zCwZUUlVUqdp_V4NU5OnGqT_bi747R6-z-Zbqols_zh-lkWWlay1wJRh0VTJZClogWqNWEEcEp8EZZY63RlEDTghCkbqUy0CoJjhsnhQGm2RhdHXLXMWy2NuVuFbalSp86SlpWt1xKXlTXB5WOIaVoXbeO_kPFXQek-xmz-x-TfQO2T2Xm</recordid><startdate>2018</startdate><enddate>2018</enddate><creator>Sandhu, Sofia</creator><creator>Shahi, Satwant Kaur</creator><creator>Singh, Vasundhara</creator><general>Royal Society of Chemistry</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8BQ</scope><scope>8FD</scope><scope>H9R</scope><scope>JG9</scope><scope>KA0</scope><orcidid>https://orcid.org/0000-0002-5819-4579</orcidid></search><sort><creationdate>2018</creationdate><title>Acidic ionic liquids: an alternative to HF for {001} reactive facet controlled synthesis of anatase titania</title><author>Sandhu, Sofia ; Shahi, Satwant Kaur ; Singh, Vasundhara</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c259t-832f2839103e08712ec030842146aedeedc201671880579ad17a91f4df98d13c3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2018</creationdate><topic>Anatase</topic><topic>Catalytic activity</topic><topic>Ionic liquids</topic><topic>Ions</topic><topic>Phase control</topic><topic>Photocatalysis</topic><topic>Solvents</topic><topic>Synthesis</topic><topic>Titanium dioxide</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Sandhu, Sofia</creatorcontrib><creatorcontrib>Shahi, Satwant Kaur</creatorcontrib><creatorcontrib>Singh, Vasundhara</creatorcontrib><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Illustrata: Natural Sciences</collection><collection>Materials Research Database</collection><collection>ProQuest Illustrata: Technology Collection</collection><jtitle>New journal of chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Sandhu, Sofia</au><au>Shahi, Satwant Kaur</au><au>Singh, Vasundhara</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Acidic ionic liquids: an alternative to HF for {001} reactive facet controlled synthesis of anatase titania</atitle><jtitle>New journal of chemistry</jtitle><date>2018</date><risdate>2018</risdate><volume>42</volume><issue>15</issue><spage>12762</spage><epage>12765</epage><pages>12762-12765</pages><issn>1144-0546</issn><eissn>1369-9261</eissn><abstract>This is a report on the facet controlled synthesis of TiO
2
, which has been achieved using the acidic room temperature ionic liquids (AILs) 1-butyl-3-methylimidazolium hydrogen sulphate and 3-methyl-1-(3-sulfonyl propyl)imidazolium trifluoro methane sulphonate as the templating and hydrolysing agents. The effect of the change of concentration of the AIL, amount of the AIL and calcination temperature demonstrated good phase control and a higher number of exposed {001} facets in the TiO
2
nanocatalysts with a higher photocatalytic activity.</abstract><cop>Cambridge</cop><pub>Royal Society of Chemistry</pub><doi>10.1039/C8NJ01481G</doi><tpages>4</tpages><orcidid>https://orcid.org/0000-0002-5819-4579</orcidid></addata></record> |
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| ispartof | New journal of chemistry, 2018, Vol.42 (15), p.12762-12765 |
| issn | 1144-0546 1369-9261 |
| language | eng |
| recordid | cdi_proquest_journals_2073574994 |
| source | Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
| subjects | Anatase Catalytic activity Ionic liquids Ions Phase control Photocatalysis Solvents Synthesis Titanium dioxide |
| title | Acidic ionic liquids: an alternative to HF for {001} reactive facet controlled synthesis of anatase titania |
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