The effect of papermaking sludge as an additive to biomass pellets on the final quality of the fuel
•Paper sludge increases characteristic ash melting temperatures of straw pellets.•Combustion of wheat straw with 20% of sludge does not cause any ash sintering.•Sludge significantly increases mechanical properties of wheat straw pellets.•Composite fuel has higher quality properties for use in small...
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description | •Paper sludge increases characteristic ash melting temperatures of straw pellets.•Combustion of wheat straw with 20% of sludge does not cause any ash sintering.•Sludge significantly increases mechanical properties of wheat straw pellets.•Composite fuel has higher quality properties for use in small boilers.
The ever increasing demand on top quality solid biofuel in form of biopellets is limited by the sources and properties of raw materials. The best quality biopellets are suitable for burning in small scale boilers up to 100 kWt. The most limiting factor of this fuel is the ash melting temperature. Therefore the use of cheaper and readily available phytomass as a raw material is considerably restrictive. The research in this paper is based on the theory of the chemical process of ash creation and on the effect of additives on this process. The objective of the study is to find and apply an effective and available additive to produce the best quality phytomass-based fuel pellets, suitable for small scale boilers. A by-product of the paper recycling process, papermaking sludge was used as the most effective additive to wheat straw. This is due to the high content of calcite and kaolin in the sludge. It was also confirmed by experiments that the composition of sludge including cellulose fibres very positively affects the physical and mechanical properties of the composite pellets. Our research deals with an experiment concerning an appropriate production process of composite fuel based on wheat straw. Different weight proportions of papermaking sludge were added and the effect of the sludge on the fuel parameters, especially on the ash melting behaviour, was observed. The final quality of the composite fuel was thoroughly tested by physical, mechanical and thermal methods, and its properties were compared to European and International Standards for Biofuels. The results of the experiments demonstrate that the composite pellets produced by the above-mentioned process have a high level of fuel quality and, due to high ash melting temperature, they are suitable for small scale boilers. The results have shown that the appropriate range of papermaking sludge content for producing high quality wheat straw composite pellets ranges from 10% to 20%. |
doi_str_mv | 10.1016/j.fuel.2018.01.089 |
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The ever increasing demand on top quality solid biofuel in form of biopellets is limited by the sources and properties of raw materials. The best quality biopellets are suitable for burning in small scale boilers up to 100 kWt. The most limiting factor of this fuel is the ash melting temperature. Therefore the use of cheaper and readily available phytomass as a raw material is considerably restrictive. The research in this paper is based on the theory of the chemical process of ash creation and on the effect of additives on this process. The objective of the study is to find and apply an effective and available additive to produce the best quality phytomass-based fuel pellets, suitable for small scale boilers. A by-product of the paper recycling process, papermaking sludge was used as the most effective additive to wheat straw. This is due to the high content of calcite and kaolin in the sludge. It was also confirmed by experiments that the composition of sludge including cellulose fibres very positively affects the physical and mechanical properties of the composite pellets. Our research deals with an experiment concerning an appropriate production process of composite fuel based on wheat straw. Different weight proportions of papermaking sludge were added and the effect of the sludge on the fuel parameters, especially on the ash melting behaviour, was observed. The final quality of the composite fuel was thoroughly tested by physical, mechanical and thermal methods, and its properties were compared to European and International Standards for Biofuels. The results of the experiments demonstrate that the composite pellets produced by the above-mentioned process have a high level of fuel quality and, due to high ash melting temperature, they are suitable for small scale boilers. The results have shown that the appropriate range of papermaking sludge content for producing high quality wheat straw composite pellets ranges from 10% to 20%.</description><identifier>ISSN: 0016-2361</identifier><identifier>EISSN: 1873-7153</identifier><identifier>DOI: 10.1016/j.fuel.2018.01.089</identifier><language>eng</language><publisher>Kidlington: Elsevier Ltd</publisher><subject>Additives ; Ash ; Ash melting ; Ashes ; Biodiesel fuels ; Biofuels ; Biomass ; Boilers ; Burning ; Calcite ; Cellulose ; Cellulose fibers ; Fuels ; International standards ; Kaolin ; Mechanical properties ; Melt temperature ; Melting ; Organic chemistry ; Paper recycling ; Papermaking ; Papermaking sludge ; Pellets ; Raw materials ; Sludge ; Straw ; Wheat</subject><ispartof>Fuel (Guildford), 2018-05, Vol.219, p.196-204</ispartof><rights>2018 Elsevier Ltd</rights><rights>Copyright Elsevier BV May 1, 2018</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c367t-d36d050c79c7c8e93bcaa7f1c2e76551e1e36de1a896aff6c1703fba4936fe383</citedby><cites>FETCH-LOGICAL-c367t-d36d050c79c7c8e93bcaa7f1c2e76551e1e36de1a896aff6c1703fba4936fe383</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://dx.doi.org/10.1016/j.fuel.2018.01.089$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>314,777,781,3537,27905,27906,45976</link.rule.ids></links><search><creatorcontrib>Matúš, Miloš</creatorcontrib><creatorcontrib>Križan, Peter</creatorcontrib><creatorcontrib>Šooš, Ľubomír</creatorcontrib><creatorcontrib>Beniak, Juraj</creatorcontrib><title>The effect of papermaking sludge as an additive to biomass pellets on the final quality of the fuel</title><title>Fuel (Guildford)</title><description>•Paper sludge increases characteristic ash melting temperatures of straw pellets.•Combustion of wheat straw with 20% of sludge does not cause any ash sintering.•Sludge significantly increases mechanical properties of wheat straw pellets.•Composite fuel has higher quality properties for use in small boilers.
The ever increasing demand on top quality solid biofuel in form of biopellets is limited by the sources and properties of raw materials. The best quality biopellets are suitable for burning in small scale boilers up to 100 kWt. The most limiting factor of this fuel is the ash melting temperature. Therefore the use of cheaper and readily available phytomass as a raw material is considerably restrictive. The research in this paper is based on the theory of the chemical process of ash creation and on the effect of additives on this process. The objective of the study is to find and apply an effective and available additive to produce the best quality phytomass-based fuel pellets, suitable for small scale boilers. A by-product of the paper recycling process, papermaking sludge was used as the most effective additive to wheat straw. This is due to the high content of calcite and kaolin in the sludge. It was also confirmed by experiments that the composition of sludge including cellulose fibres very positively affects the physical and mechanical properties of the composite pellets. Our research deals with an experiment concerning an appropriate production process of composite fuel based on wheat straw. Different weight proportions of papermaking sludge were added and the effect of the sludge on the fuel parameters, especially on the ash melting behaviour, was observed. The final quality of the composite fuel was thoroughly tested by physical, mechanical and thermal methods, and its properties were compared to European and International Standards for Biofuels. The results of the experiments demonstrate that the composite pellets produced by the above-mentioned process have a high level of fuel quality and, due to high ash melting temperature, they are suitable for small scale boilers. The results have shown that the appropriate range of papermaking sludge content for producing high quality wheat straw composite pellets ranges from 10% to 20%.</description><subject>Additives</subject><subject>Ash</subject><subject>Ash melting</subject><subject>Ashes</subject><subject>Biodiesel fuels</subject><subject>Biofuels</subject><subject>Biomass</subject><subject>Boilers</subject><subject>Burning</subject><subject>Calcite</subject><subject>Cellulose</subject><subject>Cellulose fibers</subject><subject>Fuels</subject><subject>International standards</subject><subject>Kaolin</subject><subject>Mechanical properties</subject><subject>Melt temperature</subject><subject>Melting</subject><subject>Organic chemistry</subject><subject>Paper recycling</subject><subject>Papermaking</subject><subject>Papermaking sludge</subject><subject>Pellets</subject><subject>Raw materials</subject><subject>Sludge</subject><subject>Straw</subject><subject>Wheat</subject><issn>0016-2361</issn><issn>1873-7153</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2018</creationdate><recordtype>article</recordtype><recordid>eNp9kE1LAzEURYMoWKt_wFXA9YzJpJNkwI0Uv6Dgpq5DmnmpGaeTaZIp-O9NrWtXDx73Xg4HoVtKSkoov-9KO0FfVoTKktCSyOYMzagUrBC0ZudoRnKqqBinl-gqxo4QImS9mCGz_gQM1oJJ2Fs86hHCTn-5YYtjP7VbwDpiPWDdti65A-Dk8cb5nY4Rj9D3kCL2A055xbpB93g_6d6l7-PY7zNjXaMLq_sIN393jj6en9bL12L1_vK2fFwVhnGRipbxltTEiMYII6FhG6O1sNRUIHhdU6CQE0C1bLi2lhsqCLMbvWgYt8Akm6O70-4Y_H6CmFTnp5ChoqqIqASXbMFzqjqlTPAxBrBqDG6nw7eiRB1lqk4dqdVRpiJUZZm59HAqQeY_OAgqGgeDgdaFrE613v1X_wEJgX45</recordid><startdate>20180501</startdate><enddate>20180501</enddate><creator>Matúš, Miloš</creator><creator>Križan, Peter</creator><creator>Šooš, Ľubomír</creator><creator>Beniak, Juraj</creator><general>Elsevier Ltd</general><general>Elsevier BV</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7QF</scope><scope>7QO</scope><scope>7QQ</scope><scope>7SC</scope><scope>7SE</scope><scope>7SP</scope><scope>7SR</scope><scope>7T7</scope><scope>7TA</scope><scope>7TB</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>C1K</scope><scope>F28</scope><scope>FR3</scope><scope>H8D</scope><scope>H8G</scope><scope>JG9</scope><scope>JQ2</scope><scope>KR7</scope><scope>L7M</scope><scope>L~C</scope><scope>L~D</scope><scope>P64</scope></search><sort><creationdate>20180501</creationdate><title>The effect of papermaking sludge as an additive to biomass pellets on the final quality of the fuel</title><author>Matúš, Miloš ; Križan, Peter ; Šooš, Ľubomír ; Beniak, Juraj</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c367t-d36d050c79c7c8e93bcaa7f1c2e76551e1e36de1a896aff6c1703fba4936fe383</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2018</creationdate><topic>Additives</topic><topic>Ash</topic><topic>Ash melting</topic><topic>Ashes</topic><topic>Biodiesel fuels</topic><topic>Biofuels</topic><topic>Biomass</topic><topic>Boilers</topic><topic>Burning</topic><topic>Calcite</topic><topic>Cellulose</topic><topic>Cellulose fibers</topic><topic>Fuels</topic><topic>International standards</topic><topic>Kaolin</topic><topic>Mechanical properties</topic><topic>Melt temperature</topic><topic>Melting</topic><topic>Organic chemistry</topic><topic>Paper recycling</topic><topic>Papermaking</topic><topic>Papermaking sludge</topic><topic>Pellets</topic><topic>Raw materials</topic><topic>Sludge</topic><topic>Straw</topic><topic>Wheat</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Matúš, Miloš</creatorcontrib><creatorcontrib>Križan, Peter</creatorcontrib><creatorcontrib>Šooš, Ľubomír</creatorcontrib><creatorcontrib>Beniak, Juraj</creatorcontrib><collection>CrossRef</collection><collection>Aluminium Industry Abstracts</collection><collection>Biotechnology Research Abstracts</collection><collection>Ceramic Abstracts</collection><collection>Computer and Information Systems Abstracts</collection><collection>Corrosion Abstracts</collection><collection>Electronics & Communications Abstracts</collection><collection>Engineered Materials Abstracts</collection><collection>Industrial and Applied Microbiology Abstracts (Microbiology A)</collection><collection>Materials Business File</collection><collection>Mechanical & Transportation Engineering Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Environmental Sciences and Pollution Management</collection><collection>ANTE: Abstracts in New Technology & Engineering</collection><collection>Engineering Research Database</collection><collection>Aerospace Database</collection><collection>Copper Technical Reference Library</collection><collection>Materials Research Database</collection><collection>ProQuest Computer Science Collection</collection><collection>Civil Engineering Abstracts</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>Computer and Information Systems Abstracts Academic</collection><collection>Computer and Information Systems Abstracts Professional</collection><collection>Biotechnology and BioEngineering Abstracts</collection><jtitle>Fuel (Guildford)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Matúš, Miloš</au><au>Križan, Peter</au><au>Šooš, Ľubomír</au><au>Beniak, Juraj</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>The effect of papermaking sludge as an additive to biomass pellets on the final quality of the fuel</atitle><jtitle>Fuel (Guildford)</jtitle><date>2018-05-01</date><risdate>2018</risdate><volume>219</volume><spage>196</spage><epage>204</epage><pages>196-204</pages><issn>0016-2361</issn><eissn>1873-7153</eissn><abstract>•Paper sludge increases characteristic ash melting temperatures of straw pellets.•Combustion of wheat straw with 20% of sludge does not cause any ash sintering.•Sludge significantly increases mechanical properties of wheat straw pellets.•Composite fuel has higher quality properties for use in small boilers.
The ever increasing demand on top quality solid biofuel in form of biopellets is limited by the sources and properties of raw materials. The best quality biopellets are suitable for burning in small scale boilers up to 100 kWt. The most limiting factor of this fuel is the ash melting temperature. Therefore the use of cheaper and readily available phytomass as a raw material is considerably restrictive. The research in this paper is based on the theory of the chemical process of ash creation and on the effect of additives on this process. The objective of the study is to find and apply an effective and available additive to produce the best quality phytomass-based fuel pellets, suitable for small scale boilers. A by-product of the paper recycling process, papermaking sludge was used as the most effective additive to wheat straw. This is due to the high content of calcite and kaolin in the sludge. It was also confirmed by experiments that the composition of sludge including cellulose fibres very positively affects the physical and mechanical properties of the composite pellets. Our research deals with an experiment concerning an appropriate production process of composite fuel based on wheat straw. Different weight proportions of papermaking sludge were added and the effect of the sludge on the fuel parameters, especially on the ash melting behaviour, was observed. The final quality of the composite fuel was thoroughly tested by physical, mechanical and thermal methods, and its properties were compared to European and International Standards for Biofuels. The results of the experiments demonstrate that the composite pellets produced by the above-mentioned process have a high level of fuel quality and, due to high ash melting temperature, they are suitable for small scale boilers. The results have shown that the appropriate range of papermaking sludge content for producing high quality wheat straw composite pellets ranges from 10% to 20%.</abstract><cop>Kidlington</cop><pub>Elsevier Ltd</pub><doi>10.1016/j.fuel.2018.01.089</doi><tpages>9</tpages></addata></record> |
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subjects | Additives Ash Ash melting Ashes Biodiesel fuels Biofuels Biomass Boilers Burning Calcite Cellulose Cellulose fibers Fuels International standards Kaolin Mechanical properties Melt temperature Melting Organic chemistry Paper recycling Papermaking Papermaking sludge Pellets Raw materials Sludge Straw Wheat |
title | The effect of papermaking sludge as an additive to biomass pellets on the final quality of the fuel |
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