Tip-enhanced Raman spectroscopy studies of nanodiamonds and carbon onions
Nanodiamond powder was annealed at temperatures ranging between 700 and 1700 °C and deposited by electrophoretic deposition on steel substrates. Far-field Raman spectroscopy and tip-enhanced Raman spectroscopy were used to investigate structural changes after the transformation from nanodiamonds to...
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Veröffentlicht in: | Carbon (New York) 2018-06, Vol.132, p.495-502 |
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creator | Rosenkranz, Andreas Freeman, Lindsay Fleischmann, Simon Lasserre, Federico Fainman, Yeshaiahu Talke, Frank E. |
description | Nanodiamond powder was annealed at temperatures ranging between 700 and 1700 °C and deposited by electrophoretic deposition on steel substrates. Far-field Raman spectroscopy and tip-enhanced Raman spectroscopy were used to investigate structural changes after the transformation from nanodiamonds to carbon onions as a function of the annealing temperature. Enhancement of the Raman signal was observed for all samples irrespective of the hybridization state. The largest enhancement on the order of 105 was found for non-annealed nanodiamonds. Far-field Raman spectroscopy and tip-enhanced Raman spectroscopy showed similar results as a function of the annealing temperature for peak position and width of the D- and G-peaks, intensity ratio ID/IG, and area integrated intensity ratio AD/AG.
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doi_str_mv | 10.1016/j.carbon.2018.02.088 |
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[Display omitted]</description><subject>Annealing</subject><subject>Carbon</subject><subject>Diamonds</subject><subject>Electrophoretic deposition</subject><subject>Ions</subject><subject>Nanodiamonds</subject><subject>Nanoparticles</subject><subject>Nanostructure</subject><subject>Onion-like carbon</subject><subject>Onions</subject><subject>Raman spectroscopy</subject><subject>Spectrum analysis</subject><subject>Steel</subject><subject>Substrates</subject><subject>Tip-enhanced Raman spectroscopy</subject><subject>Transformation</subject><issn>0008-6223</issn><issn>1873-3891</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2018</creationdate><recordtype>article</recordtype><recordid>eNp9kMtKxDAUhoMoWEffwEXAdWtuTdKNIIOXgQFBxnVIkxRTnKQmHWHe3gx17epw4L-c8wFwi1GDEeb3Y2N06mNoCMKyQaRBUp6BCktBayo7fA4qhJCsOSH0ElzlPJaVScwqsNn5qXbhUwfjLHzXex1gnpyZU8wmTkeY54P1LsM4wKBDtF7vY7AZ6mDh0gpj8DHka3Ax6K_sbv7mCnw8P-3Wr_X27WWzftzWhjE-15pZIbgh3BHMcGtaIjhxVKPe6AEN0ra9NlwMXU-wI5RxK2UrKe0kEawnjK7A3ZI7pfh9cHlWYzykUCoVQQJ1WOKiXwG2qEx5JCc3qCn5vU5HhZE6QVOjWs5XJ2gKEVWgFdvDYnPlgx_vksrGuxMbnwoUZaP_P-AXOhR2yw</recordid><startdate>201806</startdate><enddate>201806</enddate><creator>Rosenkranz, Andreas</creator><creator>Freeman, Lindsay</creator><creator>Fleischmann, Simon</creator><creator>Lasserre, Federico</creator><creator>Fainman, Yeshaiahu</creator><creator>Talke, Frank E.</creator><general>Elsevier Ltd</general><general>Elsevier BV</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8FD</scope><scope>JG9</scope></search><sort><creationdate>201806</creationdate><title>Tip-enhanced Raman spectroscopy studies of nanodiamonds and carbon onions</title><author>Rosenkranz, Andreas ; Freeman, Lindsay ; Fleischmann, Simon ; Lasserre, Federico ; Fainman, Yeshaiahu ; Talke, Frank E.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c446t-a4d776c26e21415c52762e3a0bcaf0f8d5bac67f9b21e2346d88583398274b243</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2018</creationdate><topic>Annealing</topic><topic>Carbon</topic><topic>Diamonds</topic><topic>Electrophoretic deposition</topic><topic>Ions</topic><topic>Nanodiamonds</topic><topic>Nanoparticles</topic><topic>Nanostructure</topic><topic>Onion-like carbon</topic><topic>Onions</topic><topic>Raman spectroscopy</topic><topic>Spectrum analysis</topic><topic>Steel</topic><topic>Substrates</topic><topic>Tip-enhanced Raman spectroscopy</topic><topic>Transformation</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Rosenkranz, Andreas</creatorcontrib><creatorcontrib>Freeman, Lindsay</creatorcontrib><creatorcontrib>Fleischmann, Simon</creatorcontrib><creatorcontrib>Lasserre, Federico</creatorcontrib><creatorcontrib>Fainman, Yeshaiahu</creatorcontrib><creatorcontrib>Talke, Frank E.</creatorcontrib><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Carbon (New York)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Rosenkranz, Andreas</au><au>Freeman, Lindsay</au><au>Fleischmann, Simon</au><au>Lasserre, Federico</au><au>Fainman, Yeshaiahu</au><au>Talke, Frank E.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Tip-enhanced Raman spectroscopy studies of nanodiamonds and carbon onions</atitle><jtitle>Carbon (New York)</jtitle><date>2018-06</date><risdate>2018</risdate><volume>132</volume><spage>495</spage><epage>502</epage><pages>495-502</pages><issn>0008-6223</issn><eissn>1873-3891</eissn><abstract>Nanodiamond powder was annealed at temperatures ranging between 700 and 1700 °C and deposited by electrophoretic deposition on steel substrates. Far-field Raman spectroscopy and tip-enhanced Raman spectroscopy were used to investigate structural changes after the transformation from nanodiamonds to carbon onions as a function of the annealing temperature. Enhancement of the Raman signal was observed for all samples irrespective of the hybridization state. The largest enhancement on the order of 105 was found for non-annealed nanodiamonds. Far-field Raman spectroscopy and tip-enhanced Raman spectroscopy showed similar results as a function of the annealing temperature for peak position and width of the D- and G-peaks, intensity ratio ID/IG, and area integrated intensity ratio AD/AG.
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subjects | Annealing Carbon Diamonds Electrophoretic deposition Ions Nanodiamonds Nanoparticles Nanostructure Onion-like carbon Onions Raman spectroscopy Spectrum analysis Steel Substrates Tip-enhanced Raman spectroscopy Transformation |
title | Tip-enhanced Raman spectroscopy studies of nanodiamonds and carbon onions |
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