Tip-enhanced Raman spectroscopy studies of nanodiamonds and carbon onions

Nanodiamond powder was annealed at temperatures ranging between 700 and 1700 °C and deposited by electrophoretic deposition on steel substrates. Far-field Raman spectroscopy and tip-enhanced Raman spectroscopy were used to investigate structural changes after the transformation from nanodiamonds to...

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Veröffentlicht in:Carbon (New York) 2018-06, Vol.132, p.495-502
Hauptverfasser: Rosenkranz, Andreas, Freeman, Lindsay, Fleischmann, Simon, Lasserre, Federico, Fainman, Yeshaiahu, Talke, Frank E.
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container_end_page 502
container_issue
container_start_page 495
container_title Carbon (New York)
container_volume 132
creator Rosenkranz, Andreas
Freeman, Lindsay
Fleischmann, Simon
Lasserre, Federico
Fainman, Yeshaiahu
Talke, Frank E.
description Nanodiamond powder was annealed at temperatures ranging between 700 and 1700 °C and deposited by electrophoretic deposition on steel substrates. Far-field Raman spectroscopy and tip-enhanced Raman spectroscopy were used to investigate structural changes after the transformation from nanodiamonds to carbon onions as a function of the annealing temperature. Enhancement of the Raman signal was observed for all samples irrespective of the hybridization state. The largest enhancement on the order of 105 was found for non-annealed nanodiamonds. Far-field Raman spectroscopy and tip-enhanced Raman spectroscopy showed similar results as a function of the annealing temperature for peak position and width of the D- and G-peaks, intensity ratio ID/IG, and area integrated intensity ratio AD/AG. [Display omitted]
doi_str_mv 10.1016/j.carbon.2018.02.088
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Far-field Raman spectroscopy and tip-enhanced Raman spectroscopy were used to investigate structural changes after the transformation from nanodiamonds to carbon onions as a function of the annealing temperature. Enhancement of the Raman signal was observed for all samples irrespective of the hybridization state. The largest enhancement on the order of 105 was found for non-annealed nanodiamonds. Far-field Raman spectroscopy and tip-enhanced Raman spectroscopy showed similar results as a function of the annealing temperature for peak position and width of the D- and G-peaks, intensity ratio ID/IG, and area integrated intensity ratio AD/AG. 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subjects Annealing
Carbon
Diamonds
Electrophoretic deposition
Ions
Nanodiamonds
Nanoparticles
Nanostructure
Onion-like carbon
Onions
Raman spectroscopy
Spectrum analysis
Steel
Substrates
Tip-enhanced Raman spectroscopy
Transformation
title Tip-enhanced Raman spectroscopy studies of nanodiamonds and carbon onions
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