Seasonal temperatures from δ18O in recent Spanish tufa stromatolites: Equilibrium redux
This study focuses on recent debate over the value of stable isotope‐based environmental proxies recorded in riverine tufa stromatolites. A twelve‐year record (1999 to 2012) of river‐bed tufa stromatolites in the River Piedra (north‐east Spain) was recovered in this study, along with a partly overla...
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| Veröffentlicht in: | Sedimentology 2018-08, Vol.65 (5), p.1611-1630 |
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| creator | Arenas, Concha Osácar, MARÍA Cinta Auqué, Luis Francisco Andrews, Julian E. Pardo, Gonzalo Marca, Alina Martín‐Bello, Leticia Pérez‐Rivarés, Francisco Javier Brasier, Alexander |
| description | This study focuses on recent debate over the value of stable isotope‐based environmental proxies recorded in riverine tufa stromatolites. A twelve‐year record (1999 to 2012) of river‐bed tufa stromatolites in the River Piedra (north‐east Spain) was recovered in this study, along with a partly overlapping fifteen‐year record (1994 to 2009) of accumulations in a drainage pipe: both deposits formed in water with near identical physico/chemical parameters. Measured water temperature data and near‐constant δ18Owater composition allowed selection of an ‘equilibrium’ palaeotemperature equation that best replicated actual temperatures. This study, as in some previous studies, found that just two published formulas for water temperature calculation from equilibrium calcite δ18O compositions were appropriate for the River Piedra, where tufa deposition rates are high, with means between 5·6 mm and 10·8 mm in six months. The δ18Ocalcite in both the river and the pipe deposits essentially records the full actual seasonal water temperature range. Only the coldest times (water temperature |
| doi_str_mv | 10.1111/sed.12440 |
| format | Article |
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A twelve‐year record (1999 to 2012) of river‐bed tufa stromatolites in the River Piedra (north‐east Spain) was recovered in this study, along with a partly overlapping fifteen‐year record (1994 to 2009) of accumulations in a drainage pipe: both deposits formed in water with near identical physico/chemical parameters. Measured water temperature data and near‐constant δ18Owater composition allowed selection of an ‘equilibrium’ palaeotemperature equation that best replicated actual temperatures. This study, as in some previous studies, found that just two published formulas for water temperature calculation from equilibrium calcite δ18O compositions were appropriate for the River Piedra, where tufa deposition rates are high, with means between 5·6 mm and 10·8 mm in six months. The δ18Ocalcite in both the river and the pipe deposits essentially records the full actual seasonal water temperature range. Only the coldest times (water temperature <10°C), when calcite precipitation mass decreased to minimum, are likely to be unrepresented, an effect most noticeable in the pipe where depositional masses are smaller and below sample resolution. While kinetic effects on δ18Ocalcite‐based calculated water temperature cannot be ruled out, the good fit between measured water temperature and δ18Ocalcite‐calculated water temperature indicates that temperature is the principal control. Textural and deposition rate variability between the river and pipe settings are caused by differences in flow velocity and illumination. In the river, calcification of growing cyanobacterial mat occurred throughout the year, producing composite dense and porous laminae, whereas in the pipe, discontinuous cyanobacterial growth in winter promoted more abiogenic calcification. High‐resolution δ18Ocalcite data from synchronous pipe and river laminae show that reversals in water temperature occur within laminae, not at lamina boundaries, a pattern consistent with progressive increase in calcite precipitation rate as cyanobacterial growth re‐established in spring.</description><identifier>ISSN: 0037-0746</identifier><identifier>EISSN: 1365-3091</identifier><identifier>DOI: 10.1111/sed.12440</identifier><language>eng</language><publisher>Madrid: Wiley Subscription Services, Inc</publisher><subject>Calcification ; Calcite ; Chemical precipitation ; Composition ; Deposition ; Equilibrium ; Flow velocity ; Fluvial deposits ; Laminates ; Mathematical analysis ; Mathematical models ; Organic chemistry ; Palaeotemperature ; Palaeotemperature equation ; Pipes ; Precipitation rate ; recent tufa stromatolites ; Resolution ; Rivers ; seasonal pattern ; Stable isotopes ; Stromatolites ; Temperature data ; Temperature effects ; textural and deposition rate variability ; Water ; Water temperature ; Water temperature data</subject><ispartof>Sedimentology, 2018-08, Vol.65 (5), p.1611-1630</ispartof><rights>2017 The Authors. Sedimentology © 2017 International Association of Sedimentologists</rights><rights>Journal compilation © 2018 International Association of Sedimentologists</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><orcidid>0000-0002-4212-0524</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1111%2Fsed.12440$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1111%2Fsed.12440$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>315,782,786,1419,27931,27932,45581,45582</link.rule.ids></links><search><creatorcontrib>Arenas, Concha</creatorcontrib><creatorcontrib>Osácar, MARÍA Cinta</creatorcontrib><creatorcontrib>Auqué, Luis Francisco</creatorcontrib><creatorcontrib>Andrews, Julian E.</creatorcontrib><creatorcontrib>Pardo, Gonzalo</creatorcontrib><creatorcontrib>Marca, Alina</creatorcontrib><creatorcontrib>Martín‐Bello, Leticia</creatorcontrib><creatorcontrib>Pérez‐Rivarés, Francisco Javier</creatorcontrib><creatorcontrib>Brasier, Alexander</creatorcontrib><title>Seasonal temperatures from δ18O in recent Spanish tufa stromatolites: Equilibrium redux</title><title>Sedimentology</title><description>This study focuses on recent debate over the value of stable isotope‐based environmental proxies recorded in riverine tufa stromatolites. A twelve‐year record (1999 to 2012) of river‐bed tufa stromatolites in the River Piedra (north‐east Spain) was recovered in this study, along with a partly overlapping fifteen‐year record (1994 to 2009) of accumulations in a drainage pipe: both deposits formed in water with near identical physico/chemical parameters. Measured water temperature data and near‐constant δ18Owater composition allowed selection of an ‘equilibrium’ palaeotemperature equation that best replicated actual temperatures. This study, as in some previous studies, found that just two published formulas for water temperature calculation from equilibrium calcite δ18O compositions were appropriate for the River Piedra, where tufa deposition rates are high, with means between 5·6 mm and 10·8 mm in six months. The δ18Ocalcite in both the river and the pipe deposits essentially records the full actual seasonal water temperature range. Only the coldest times (water temperature <10°C), when calcite precipitation mass decreased to minimum, are likely to be unrepresented, an effect most noticeable in the pipe where depositional masses are smaller and below sample resolution. While kinetic effects on δ18Ocalcite‐based calculated water temperature cannot be ruled out, the good fit between measured water temperature and δ18Ocalcite‐calculated water temperature indicates that temperature is the principal control. Textural and deposition rate variability between the river and pipe settings are caused by differences in flow velocity and illumination. In the river, calcification of growing cyanobacterial mat occurred throughout the year, producing composite dense and porous laminae, whereas in the pipe, discontinuous cyanobacterial growth in winter promoted more abiogenic calcification. High‐resolution δ18Ocalcite data from synchronous pipe and river laminae show that reversals in water temperature occur within laminae, not at lamina boundaries, a pattern consistent with progressive increase in calcite precipitation rate as cyanobacterial growth re‐established in spring.</description><subject>Calcification</subject><subject>Calcite</subject><subject>Chemical precipitation</subject><subject>Composition</subject><subject>Deposition</subject><subject>Equilibrium</subject><subject>Flow velocity</subject><subject>Fluvial deposits</subject><subject>Laminates</subject><subject>Mathematical analysis</subject><subject>Mathematical models</subject><subject>Organic chemistry</subject><subject>Palaeotemperature</subject><subject>Palaeotemperature equation</subject><subject>Pipes</subject><subject>Precipitation rate</subject><subject>recent tufa stromatolites</subject><subject>Resolution</subject><subject>Rivers</subject><subject>seasonal pattern</subject><subject>Stable isotopes</subject><subject>Stromatolites</subject><subject>Temperature data</subject><subject>Temperature effects</subject><subject>textural and deposition rate variability</subject><subject>Water</subject><subject>Water temperature</subject><subject>Water temperature data</subject><issn>0037-0746</issn><issn>1365-3091</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2018</creationdate><recordtype>article</recordtype><recordid>eNotkMtKAzEUhoMoWKsL3yDgemxOk5lM3EmtFyh0UQV3ITNzBlPm1lzQvpfP4TM5tp7NfxYfP_wfIdfAbmG8mcfqFuZCsBMyAZ6lCWcKTsmEMS4TJkV2Ti683zIGmcjVhLxv0Pi-Mw0N2A7oTIgOPa1d39Kfb8jX1HbUYYldoJvBdNZ_0BBrQ30YERP6xgb0d3S5i7axhbOxHfEqfl2Ss9o0Hq_-c0reHpevi-dktX56WdyvkgHynCVFKUyGAiSmTEgUBQhuWG1krgphOCrFiiLLeAoIYFQ5B5A1SlVXUFYIhk_JzbF3cP0uog9620c3DvJ6ziTjKpWQjtTsSH3aBvd6cLY1bq-B6T9rerSmD9b0ZvlwePgvMERi1A</recordid><startdate>201808</startdate><enddate>201808</enddate><creator>Arenas, Concha</creator><creator>Osácar, MARÍA Cinta</creator><creator>Auqué, Luis Francisco</creator><creator>Andrews, Julian E.</creator><creator>Pardo, Gonzalo</creator><creator>Marca, Alina</creator><creator>Martín‐Bello, Leticia</creator><creator>Pérez‐Rivarés, Francisco Javier</creator><creator>Brasier, Alexander</creator><general>Wiley Subscription Services, Inc</general><scope>7ST</scope><scope>7TN</scope><scope>7UA</scope><scope>C1K</scope><scope>F1W</scope><scope>H96</scope><scope>L.G</scope><scope>SOI</scope><orcidid>https://orcid.org/0000-0002-4212-0524</orcidid></search><sort><creationdate>201808</creationdate><title>Seasonal temperatures from δ18O in recent Spanish tufa stromatolites: Equilibrium redux</title><author>Arenas, Concha ; Osácar, MARÍA Cinta ; Auqué, Luis Francisco ; Andrews, Julian E. ; Pardo, Gonzalo ; Marca, Alina ; Martín‐Bello, Leticia ; Pérez‐Rivarés, Francisco Javier ; Brasier, Alexander</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-p1880-bc4a6e417e5047e4b143a0fa789b4a3e990bb66351e11a9c2117fe79fd1cde1a3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2018</creationdate><topic>Calcification</topic><topic>Calcite</topic><topic>Chemical precipitation</topic><topic>Composition</topic><topic>Deposition</topic><topic>Equilibrium</topic><topic>Flow velocity</topic><topic>Fluvial deposits</topic><topic>Laminates</topic><topic>Mathematical analysis</topic><topic>Mathematical models</topic><topic>Organic chemistry</topic><topic>Palaeotemperature</topic><topic>Palaeotemperature equation</topic><topic>Pipes</topic><topic>Precipitation rate</topic><topic>recent tufa stromatolites</topic><topic>Resolution</topic><topic>Rivers</topic><topic>seasonal pattern</topic><topic>Stable isotopes</topic><topic>Stromatolites</topic><topic>Temperature data</topic><topic>Temperature effects</topic><topic>textural and deposition rate variability</topic><topic>Water</topic><topic>Water temperature</topic><topic>Water temperature data</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Arenas, Concha</creatorcontrib><creatorcontrib>Osácar, MARÍA Cinta</creatorcontrib><creatorcontrib>Auqué, Luis Francisco</creatorcontrib><creatorcontrib>Andrews, Julian E.</creatorcontrib><creatorcontrib>Pardo, Gonzalo</creatorcontrib><creatorcontrib>Marca, Alina</creatorcontrib><creatorcontrib>Martín‐Bello, Leticia</creatorcontrib><creatorcontrib>Pérez‐Rivarés, Francisco Javier</creatorcontrib><creatorcontrib>Brasier, Alexander</creatorcontrib><collection>Environment Abstracts</collection><collection>Oceanic Abstracts</collection><collection>Water Resources Abstracts</collection><collection>Environmental Sciences and Pollution Management</collection><collection>ASFA: Aquatic Sciences and Fisheries Abstracts</collection><collection>Aquatic Science & Fisheries Abstracts (ASFA) 2: Ocean Technology, Policy & Non-Living Resources</collection><collection>Aquatic Science & Fisheries Abstracts (ASFA) Professional</collection><collection>Environment Abstracts</collection><jtitle>Sedimentology</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Arenas, Concha</au><au>Osácar, MARÍA Cinta</au><au>Auqué, Luis Francisco</au><au>Andrews, Julian E.</au><au>Pardo, Gonzalo</au><au>Marca, Alina</au><au>Martín‐Bello, Leticia</au><au>Pérez‐Rivarés, Francisco Javier</au><au>Brasier, Alexander</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Seasonal temperatures from δ18O in recent Spanish tufa stromatolites: Equilibrium redux</atitle><jtitle>Sedimentology</jtitle><date>2018-08</date><risdate>2018</risdate><volume>65</volume><issue>5</issue><spage>1611</spage><epage>1630</epage><pages>1611-1630</pages><issn>0037-0746</issn><eissn>1365-3091</eissn><abstract>This study focuses on recent debate over the value of stable isotope‐based environmental proxies recorded in riverine tufa stromatolites. A twelve‐year record (1999 to 2012) of river‐bed tufa stromatolites in the River Piedra (north‐east Spain) was recovered in this study, along with a partly overlapping fifteen‐year record (1994 to 2009) of accumulations in a drainage pipe: both deposits formed in water with near identical physico/chemical parameters. Measured water temperature data and near‐constant δ18Owater composition allowed selection of an ‘equilibrium’ palaeotemperature equation that best replicated actual temperatures. This study, as in some previous studies, found that just two published formulas for water temperature calculation from equilibrium calcite δ18O compositions were appropriate for the River Piedra, where tufa deposition rates are high, with means between 5·6 mm and 10·8 mm in six months. The δ18Ocalcite in both the river and the pipe deposits essentially records the full actual seasonal water temperature range. Only the coldest times (water temperature <10°C), when calcite precipitation mass decreased to minimum, are likely to be unrepresented, an effect most noticeable in the pipe where depositional masses are smaller and below sample resolution. While kinetic effects on δ18Ocalcite‐based calculated water temperature cannot be ruled out, the good fit between measured water temperature and δ18Ocalcite‐calculated water temperature indicates that temperature is the principal control. Textural and deposition rate variability between the river and pipe settings are caused by differences in flow velocity and illumination. In the river, calcification of growing cyanobacterial mat occurred throughout the year, producing composite dense and porous laminae, whereas in the pipe, discontinuous cyanobacterial growth in winter promoted more abiogenic calcification. High‐resolution δ18Ocalcite data from synchronous pipe and river laminae show that reversals in water temperature occur within laminae, not at lamina boundaries, a pattern consistent with progressive increase in calcite precipitation rate as cyanobacterial growth re‐established in spring.</abstract><cop>Madrid</cop><pub>Wiley Subscription Services, Inc</pub><doi>10.1111/sed.12440</doi><tpages>20</tpages><orcidid>https://orcid.org/0000-0002-4212-0524</orcidid><oa>free_for_read</oa></addata></record> |
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| subjects | Calcification Calcite Chemical precipitation Composition Deposition Equilibrium Flow velocity Fluvial deposits Laminates Mathematical analysis Mathematical models Organic chemistry Palaeotemperature Palaeotemperature equation Pipes Precipitation rate recent tufa stromatolites Resolution Rivers seasonal pattern Stable isotopes Stromatolites Temperature data Temperature effects textural and deposition rate variability Water Water temperature Water temperature data |
| title | Seasonal temperatures from δ18O in recent Spanish tufa stromatolites: Equilibrium redux |
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