A Subtractive Photoresist Platform for Micro‐ and Macroscopic 3D Printed Structures

The selective removal of structural elements plays a decisive role in 3D printing applications enabling complex geometries. To date, the fabrication of complex structures on the microscale is severely limited by multistep processes. Herein, a subtractive photoresist platform technology that is trans...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Advanced functional materials 2018-07, Vol.28 (29), p.n/a
Hauptverfasser: Zieger, Markus M., Müller, Patrick, Blasco, Eva, Petit, Charlotte, Hahn, Vincent, Michalek, Lukas, Mutlu, Hatice, Wegener, Martin, Barner‐Kowollik, Christopher
Format: Artikel
Sprache:eng
Schlagworte:
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
container_end_page n/a
container_issue 29
container_start_page
container_title Advanced functional materials
container_volume 28
creator Zieger, Markus M.
Müller, Patrick
Blasco, Eva
Petit, Charlotte
Hahn, Vincent
Michalek, Lukas
Mutlu, Hatice
Wegener, Martin
Barner‐Kowollik, Christopher
description The selective removal of structural elements plays a decisive role in 3D printing applications enabling complex geometries. To date, the fabrication of complex structures on the microscale is severely limited by multistep processes. Herein, a subtractive photoresist platform technology that is transferable from microscopic 3D printing via direct laser writing to macroscopic structures via stereolithography is reported. All resist components are readily accessible and exchangeable, offering fast adaptation of the resist's property profile. The micro‐ and macroprinted structures can be removed in a facile fashion, without affecting objects based on standard photoresists. The cleavage is analyzed by time‐lapse optical microscopy as well as via in‐depth spectroscopic assessment. The mechanical properties of the printed materials are investigated by nanoindentation. Critically, the power of the subtractive resist platform is demonstrated by constructing complex 3D objects with flying features on the microscale. A readily accessible and removable photoresist platform is pioneered for 3D micro‐ to macroscopic printing applications, offering fast adaptation of the resist's property profile. The micro‐ and macroprinted structures can be removed in a facile fashion, without affecting objects based on standard photoresists.
doi_str_mv 10.1002/adfm.201801405
format Article
fullrecord <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_journals_2070170230</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>2070170230</sourcerecordid><originalsourceid>FETCH-LOGICAL-c4765-4af7a7d0e955930e9a88628fab7864d4e5ec5c8aa3b85175577acfdd7723b0ac3</originalsourceid><addsrcrecordid>eNqFkMtKAzEUhoMoWKtb1wHXU08mk0m6LK1VocVCLbgLZzIZnNJ2apJRuvMRfEafxJRKXbo5F_i_c_kJuWbQYwDpLZbVupcCU8AyECekw3KWJxxSdXqs2cs5ufB-CcCk5FmHLAZ03hbBoQn1u6Wz1yY0zvraBzpbYagat6Yx0GltXPP9-UVxU9IpxsabZlsbykd05upNsCWdB9ea0Eb8kpxVuPL26jd3yWJ89zx8SCZP94_DwSQxmcxFkmElUZZg-0L0eUyoVJ6qCgup8qzMrLBGGIXICyWYFEJKNFVZSpnyAtDwLrk5zN265q21Puhl07pNXKlTkPFHSDlEVe-g2l_tna301tVrdDvNQO-t03vr9NG6CPQPwEe9srt_1HowGk__2B8TJ3OY</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2070170230</pqid></control><display><type>article</type><title>A Subtractive Photoresist Platform for Micro‐ and Macroscopic 3D Printed Structures</title><source>Access via Wiley Online Library</source><creator>Zieger, Markus M. ; Müller, Patrick ; Blasco, Eva ; Petit, Charlotte ; Hahn, Vincent ; Michalek, Lukas ; Mutlu, Hatice ; Wegener, Martin ; Barner‐Kowollik, Christopher</creator><creatorcontrib>Zieger, Markus M. ; Müller, Patrick ; Blasco, Eva ; Petit, Charlotte ; Hahn, Vincent ; Michalek, Lukas ; Mutlu, Hatice ; Wegener, Martin ; Barner‐Kowollik, Christopher</creatorcontrib><description>The selective removal of structural elements plays a decisive role in 3D printing applications enabling complex geometries. To date, the fabrication of complex structures on the microscale is severely limited by multistep processes. Herein, a subtractive photoresist platform technology that is transferable from microscopic 3D printing via direct laser writing to macroscopic structures via stereolithography is reported. All resist components are readily accessible and exchangeable, offering fast adaptation of the resist's property profile. The micro‐ and macroprinted structures can be removed in a facile fashion, without affecting objects based on standard photoresists. The cleavage is analyzed by time‐lapse optical microscopy as well as via in‐depth spectroscopic assessment. The mechanical properties of the printed materials are investigated by nanoindentation. Critically, the power of the subtractive resist platform is demonstrated by constructing complex 3D objects with flying features on the microscale. A readily accessible and removable photoresist platform is pioneered for 3D micro‐ to macroscopic printing applications, offering fast adaptation of the resist's property profile. The micro‐ and macroprinted structures can be removed in a facile fashion, without affecting objects based on standard photoresists.</description><identifier>ISSN: 1616-301X</identifier><identifier>EISSN: 1616-3028</identifier><identifier>DOI: 10.1002/adfm.201801405</identifier><language>eng</language><publisher>Hoboken: Wiley Subscription Services, Inc</publisher><subject>3-D printers ; 3D printing ; Direct laser writing ; Lithography ; Materials science ; Mechanical properties ; microstructures ; Nanoindentation ; Optical microscopy ; photochemistry ; Photoresists ; polymeric materials ; stereolithography ; Structural members ; Three dimensional printing</subject><ispartof>Advanced functional materials, 2018-07, Vol.28 (29), p.n/a</ispartof><rights>2018 WILEY‐VCH Verlag GmbH &amp; Co. KGaA, Weinheim</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c4765-4af7a7d0e955930e9a88628fab7864d4e5ec5c8aa3b85175577acfdd7723b0ac3</citedby><cites>FETCH-LOGICAL-c4765-4af7a7d0e955930e9a88628fab7864d4e5ec5c8aa3b85175577acfdd7723b0ac3</cites><orcidid>0000-0002-6745-0570</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fadfm.201801405$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fadfm.201801405$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,780,784,1417,27924,27925,45574,45575</link.rule.ids></links><search><creatorcontrib>Zieger, Markus M.</creatorcontrib><creatorcontrib>Müller, Patrick</creatorcontrib><creatorcontrib>Blasco, Eva</creatorcontrib><creatorcontrib>Petit, Charlotte</creatorcontrib><creatorcontrib>Hahn, Vincent</creatorcontrib><creatorcontrib>Michalek, Lukas</creatorcontrib><creatorcontrib>Mutlu, Hatice</creatorcontrib><creatorcontrib>Wegener, Martin</creatorcontrib><creatorcontrib>Barner‐Kowollik, Christopher</creatorcontrib><title>A Subtractive Photoresist Platform for Micro‐ and Macroscopic 3D Printed Structures</title><title>Advanced functional materials</title><description>The selective removal of structural elements plays a decisive role in 3D printing applications enabling complex geometries. To date, the fabrication of complex structures on the microscale is severely limited by multistep processes. Herein, a subtractive photoresist platform technology that is transferable from microscopic 3D printing via direct laser writing to macroscopic structures via stereolithography is reported. All resist components are readily accessible and exchangeable, offering fast adaptation of the resist's property profile. The micro‐ and macroprinted structures can be removed in a facile fashion, without affecting objects based on standard photoresists. The cleavage is analyzed by time‐lapse optical microscopy as well as via in‐depth spectroscopic assessment. The mechanical properties of the printed materials are investigated by nanoindentation. Critically, the power of the subtractive resist platform is demonstrated by constructing complex 3D objects with flying features on the microscale. A readily accessible and removable photoresist platform is pioneered for 3D micro‐ to macroscopic printing applications, offering fast adaptation of the resist's property profile. The micro‐ and macroprinted structures can be removed in a facile fashion, without affecting objects based on standard photoresists.</description><subject>3-D printers</subject><subject>3D printing</subject><subject>Direct laser writing</subject><subject>Lithography</subject><subject>Materials science</subject><subject>Mechanical properties</subject><subject>microstructures</subject><subject>Nanoindentation</subject><subject>Optical microscopy</subject><subject>photochemistry</subject><subject>Photoresists</subject><subject>polymeric materials</subject><subject>stereolithography</subject><subject>Structural members</subject><subject>Three dimensional printing</subject><issn>1616-301X</issn><issn>1616-3028</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2018</creationdate><recordtype>article</recordtype><recordid>eNqFkMtKAzEUhoMoWKtb1wHXU08mk0m6LK1VocVCLbgLZzIZnNJ2apJRuvMRfEafxJRKXbo5F_i_c_kJuWbQYwDpLZbVupcCU8AyECekw3KWJxxSdXqs2cs5ufB-CcCk5FmHLAZ03hbBoQn1u6Wz1yY0zvraBzpbYagat6Yx0GltXPP9-UVxU9IpxsabZlsbykd05upNsCWdB9ea0Eb8kpxVuPL26jd3yWJ89zx8SCZP94_DwSQxmcxFkmElUZZg-0L0eUyoVJ6qCgup8qzMrLBGGIXICyWYFEJKNFVZSpnyAtDwLrk5zN265q21Puhl07pNXKlTkPFHSDlEVe-g2l_tna301tVrdDvNQO-t03vr9NG6CPQPwEe9srt_1HowGk__2B8TJ3OY</recordid><startdate>20180718</startdate><enddate>20180718</enddate><creator>Zieger, Markus M.</creator><creator>Müller, Patrick</creator><creator>Blasco, Eva</creator><creator>Petit, Charlotte</creator><creator>Hahn, Vincent</creator><creator>Michalek, Lukas</creator><creator>Mutlu, Hatice</creator><creator>Wegener, Martin</creator><creator>Barner‐Kowollik, Christopher</creator><general>Wiley Subscription Services, Inc</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SP</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope><orcidid>https://orcid.org/0000-0002-6745-0570</orcidid></search><sort><creationdate>20180718</creationdate><title>A Subtractive Photoresist Platform for Micro‐ and Macroscopic 3D Printed Structures</title><author>Zieger, Markus M. ; Müller, Patrick ; Blasco, Eva ; Petit, Charlotte ; Hahn, Vincent ; Michalek, Lukas ; Mutlu, Hatice ; Wegener, Martin ; Barner‐Kowollik, Christopher</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c4765-4af7a7d0e955930e9a88628fab7864d4e5ec5c8aa3b85175577acfdd7723b0ac3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2018</creationdate><topic>3-D printers</topic><topic>3D printing</topic><topic>Direct laser writing</topic><topic>Lithography</topic><topic>Materials science</topic><topic>Mechanical properties</topic><topic>microstructures</topic><topic>Nanoindentation</topic><topic>Optical microscopy</topic><topic>photochemistry</topic><topic>Photoresists</topic><topic>polymeric materials</topic><topic>stereolithography</topic><topic>Structural members</topic><topic>Three dimensional printing</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Zieger, Markus M.</creatorcontrib><creatorcontrib>Müller, Patrick</creatorcontrib><creatorcontrib>Blasco, Eva</creatorcontrib><creatorcontrib>Petit, Charlotte</creatorcontrib><creatorcontrib>Hahn, Vincent</creatorcontrib><creatorcontrib>Michalek, Lukas</creatorcontrib><creatorcontrib>Mutlu, Hatice</creatorcontrib><creatorcontrib>Wegener, Martin</creatorcontrib><creatorcontrib>Barner‐Kowollik, Christopher</creatorcontrib><collection>CrossRef</collection><collection>Electronics &amp; Communications Abstracts</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Advanced functional materials</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Zieger, Markus M.</au><au>Müller, Patrick</au><au>Blasco, Eva</au><au>Petit, Charlotte</au><au>Hahn, Vincent</au><au>Michalek, Lukas</au><au>Mutlu, Hatice</au><au>Wegener, Martin</au><au>Barner‐Kowollik, Christopher</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>A Subtractive Photoresist Platform for Micro‐ and Macroscopic 3D Printed Structures</atitle><jtitle>Advanced functional materials</jtitle><date>2018-07-18</date><risdate>2018</risdate><volume>28</volume><issue>29</issue><epage>n/a</epage><issn>1616-301X</issn><eissn>1616-3028</eissn><abstract>The selective removal of structural elements plays a decisive role in 3D printing applications enabling complex geometries. To date, the fabrication of complex structures on the microscale is severely limited by multistep processes. Herein, a subtractive photoresist platform technology that is transferable from microscopic 3D printing via direct laser writing to macroscopic structures via stereolithography is reported. All resist components are readily accessible and exchangeable, offering fast adaptation of the resist's property profile. The micro‐ and macroprinted structures can be removed in a facile fashion, without affecting objects based on standard photoresists. The cleavage is analyzed by time‐lapse optical microscopy as well as via in‐depth spectroscopic assessment. The mechanical properties of the printed materials are investigated by nanoindentation. Critically, the power of the subtractive resist platform is demonstrated by constructing complex 3D objects with flying features on the microscale. A readily accessible and removable photoresist platform is pioneered for 3D micro‐ to macroscopic printing applications, offering fast adaptation of the resist's property profile. The micro‐ and macroprinted structures can be removed in a facile fashion, without affecting objects based on standard photoresists.</abstract><cop>Hoboken</cop><pub>Wiley Subscription Services, Inc</pub><doi>10.1002/adfm.201801405</doi><tpages>7</tpages><orcidid>https://orcid.org/0000-0002-6745-0570</orcidid><oa>free_for_read</oa></addata></record>
fulltext fulltext
identifier ISSN: 1616-301X
ispartof Advanced functional materials, 2018-07, Vol.28 (29), p.n/a
issn 1616-301X
1616-3028
language eng
recordid cdi_proquest_journals_2070170230
source Access via Wiley Online Library
subjects 3-D printers
3D printing
Direct laser writing
Lithography
Materials science
Mechanical properties
microstructures
Nanoindentation
Optical microscopy
photochemistry
Photoresists
polymeric materials
stereolithography
Structural members
Three dimensional printing
title A Subtractive Photoresist Platform for Micro‐ and Macroscopic 3D Printed Structures
url https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2024-12-23T01%3A59%3A06IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=A%20Subtractive%20Photoresist%20Platform%20for%20Micro%E2%80%90%20and%20Macroscopic%203D%20Printed%20Structures&rft.jtitle=Advanced%20functional%20materials&rft.au=Zieger,%20Markus%20M.&rft.date=2018-07-18&rft.volume=28&rft.issue=29&rft.epage=n/a&rft.issn=1616-301X&rft.eissn=1616-3028&rft_id=info:doi/10.1002/adfm.201801405&rft_dat=%3Cproquest_cross%3E2070170230%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=2070170230&rft_id=info:pmid/&rfr_iscdi=true