Simple route for the preparation of graphene/poly(styrene‐b‐butadiene‐b‐styrene) nanocomposite films with enhanced electrical conductivity and hydrophobicity
This paper reports a simple route for the preparation of graphene/poly(styrene‐b‐butadiene‐b‐styrene) (SBS) nanocomposite films employing a vacuum filtration method. Graphene is exfoliated well by an electrochemical procedure and homogeneously dispersed in the polymer matrix. The prepared nanocompos...
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| Veröffentlicht in: | Polymer international 2018-08, Vol.67 (8), p.1118-1127 |
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| creator | Kepić, Dejan P Ristić, Ivan S Marinović‐Cincović, Milena T Peruško, Davor B Špitálsky, Zdenko Pavlović, Vladimir B Budimir, Milica D Šiffalovič, Peter Dramićanin, Miroslav D Mičušík, Matej Kleinová, Angela Janigová, Ivica Marković, Zoran M Todorović Marković, Biljana M |
| description | This paper reports a simple route for the preparation of graphene/poly(styrene‐b‐butadiene‐b‐styrene) (SBS) nanocomposite films employing a vacuum filtration method. Graphene is exfoliated well by an electrochemical procedure and homogeneously dispersed in the polymer matrix. The prepared nanocomposite films were characterized by XRD, Fourier transform IR (FTIR) spectroscopy, X‐ray photoelectron spectroscopy (XPS), Raman spectroscopy, AFM and SEM. Morphological studies showed that graphene formed a smooth coating over the surface of SBS. The increase in graphene concentration induces the wrinkling of graphene sheets at the composite surface which causes a further increase in surface roughness. The FTIR, Raman and XPS spectra of graphene/SBS nanocomposite films indicate the strong interactions between graphene and the polymer matrix. According to the XRD patterns, introducing SBS into graphene did not modify the graphene structure additionally, i.e. the crystal lattice parameters do not depend on SBS content in graphene/SBS nanocomposite films. The graphene/SBS nanocomposite films also exhibited better hydrophobicity due to the increased surface roughness and lower sheet resistivity (reduced 10 times) compared to exfoliated graphene. © 2018 Society of Chemical Industry
Graphene/poly(styrene‐b‐butadiene‐b‐styrene) films were prepared by the vacuum filtration method. An increase in graphene concentration causes the surface roughness to increase, which leads to better hydrophobicity and lower sheet resistivity. |
| doi_str_mv | 10.1002/pi.5620 |
| format | Article |
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Graphene/poly(styrene‐b‐butadiene‐b‐styrene) films were prepared by the vacuum filtration method. An increase in graphene concentration causes the surface roughness to increase, which leads to better hydrophobicity and lower sheet resistivity.</description><identifier>ISSN: 0959-8103</identifier><identifier>EISSN: 1097-0126</identifier><identifier>DOI: 10.1002/pi.5620</identifier><language>eng</language><publisher>Chichester, UK: John Wiley & Sons, Ltd</publisher><subject>Butadiene ; Crystal lattices ; Crystal structure ; Electrical conductivity ; electrical properties ; Electrical resistivity ; Fourier transforms ; Graphene ; Hydrophobicity ; Infrared spectroscopy ; Lattice parameters ; layered structures ; microstructures ; Nanocomposites ; Nanotubes ; Organic chemistry ; Parameter modification ; Photoelectron spectroscopy ; Polystyrene resins ; Raman spectroscopy ; Spectrum analysis ; Styrene ; Styrenes ; surface analysis ; Surface roughness ; Vacuum ; Vacuum filtration ; X ray photoelectron spectroscopy</subject><ispartof>Polymer international, 2018-08, Vol.67 (8), p.1118-1127</ispartof><rights>2018 Society of Chemical Industry</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c3260-d582c20ad4ca85f1cd9138305b68da31a6edbb4b2ddba54c7f5a2d6ca749c5c83</citedby><cites>FETCH-LOGICAL-c3260-d582c20ad4ca85f1cd9138305b68da31a6edbb4b2ddba54c7f5a2d6ca749c5c83</cites><orcidid>0000-0003-2777-6864 ; 0000-0002-9807-0810</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fpi.5620$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fpi.5620$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,776,780,1411,27901,27902,45550,45551</link.rule.ids></links><search><creatorcontrib>Kepić, Dejan P</creatorcontrib><creatorcontrib>Ristić, Ivan S</creatorcontrib><creatorcontrib>Marinović‐Cincović, Milena T</creatorcontrib><creatorcontrib>Peruško, Davor B</creatorcontrib><creatorcontrib>Špitálsky, Zdenko</creatorcontrib><creatorcontrib>Pavlović, Vladimir B</creatorcontrib><creatorcontrib>Budimir, Milica D</creatorcontrib><creatorcontrib>Šiffalovič, Peter</creatorcontrib><creatorcontrib>Dramićanin, Miroslav D</creatorcontrib><creatorcontrib>Mičušík, Matej</creatorcontrib><creatorcontrib>Kleinová, Angela</creatorcontrib><creatorcontrib>Janigová, Ivica</creatorcontrib><creatorcontrib>Marković, Zoran M</creatorcontrib><creatorcontrib>Todorović Marković, Biljana M</creatorcontrib><title>Simple route for the preparation of graphene/poly(styrene‐b‐butadiene‐b‐styrene) nanocomposite films with enhanced electrical conductivity and hydrophobicity</title><title>Polymer international</title><description>This paper reports a simple route for the preparation of graphene/poly(styrene‐b‐butadiene‐b‐styrene) (SBS) nanocomposite films employing a vacuum filtration method. Graphene is exfoliated well by an electrochemical procedure and homogeneously dispersed in the polymer matrix. The prepared nanocomposite films were characterized by XRD, Fourier transform IR (FTIR) spectroscopy, X‐ray photoelectron spectroscopy (XPS), Raman spectroscopy, AFM and SEM. Morphological studies showed that graphene formed a smooth coating over the surface of SBS. The increase in graphene concentration induces the wrinkling of graphene sheets at the composite surface which causes a further increase in surface roughness. The FTIR, Raman and XPS spectra of graphene/SBS nanocomposite films indicate the strong interactions between graphene and the polymer matrix. According to the XRD patterns, introducing SBS into graphene did not modify the graphene structure additionally, i.e. the crystal lattice parameters do not depend on SBS content in graphene/SBS nanocomposite films. The graphene/SBS nanocomposite films also exhibited better hydrophobicity due to the increased surface roughness and lower sheet resistivity (reduced 10 times) compared to exfoliated graphene. © 2018 Society of Chemical Industry
Graphene/poly(styrene‐b‐butadiene‐b‐styrene) films were prepared by the vacuum filtration method. An increase in graphene concentration causes the surface roughness to increase, which leads to better hydrophobicity and lower sheet resistivity.</description><subject>Butadiene</subject><subject>Crystal lattices</subject><subject>Crystal structure</subject><subject>Electrical conductivity</subject><subject>electrical properties</subject><subject>Electrical resistivity</subject><subject>Fourier transforms</subject><subject>Graphene</subject><subject>Hydrophobicity</subject><subject>Infrared spectroscopy</subject><subject>Lattice parameters</subject><subject>layered structures</subject><subject>microstructures</subject><subject>Nanocomposites</subject><subject>Nanotubes</subject><subject>Organic chemistry</subject><subject>Parameter modification</subject><subject>Photoelectron spectroscopy</subject><subject>Polystyrene resins</subject><subject>Raman spectroscopy</subject><subject>Spectrum analysis</subject><subject>Styrene</subject><subject>Styrenes</subject><subject>surface analysis</subject><subject>Surface roughness</subject><subject>Vacuum</subject><subject>Vacuum filtration</subject><subject>X ray photoelectron spectroscopy</subject><issn>0959-8103</issn><issn>1097-0126</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2018</creationdate><recordtype>article</recordtype><recordid>eNp1kUtKBDEQhoMoOD7wCgEXKtJjkn4vZfAxICio66Y6SduRniQmaYfeeQQv4cU8iT3OgCsXRfFXffwF9SN0RMmUEsIurJqmGSNbaEJJmUeEsmwbTUiZllFBSbyL9rx_JYQUZVlO0NejWthOYmf6IHFjHA6txNZJCw6CMhqbBr84sK3U8sKabjj1YXCj-P74rFfVBxDqT2-2Z1iDNtwsrPFq5ay6hcdLFVosdQuaS4FlJ3lwikOHudGi50G9qzBg0AK3g3DGtqZWfBwdoJ0GOi8PN30fPV9fPc1uo7v7m_ns8i7iMctIJNKCcUZAJByKtKFclDQuYpLWWSEgppBJUddJzYSoIU143qTARMYhT0qe8iLeR8drX-vMWy99qF5N7_R4smIky_PxrywZqZM1xZ3x3smmsk4twA0VJdUqg8qqapXBSJ6vyaXq5PAfVj3Mf-kf37WQhg</recordid><startdate>201808</startdate><enddate>201808</enddate><creator>Kepić, Dejan P</creator><creator>Ristić, Ivan S</creator><creator>Marinović‐Cincović, Milena T</creator><creator>Peruško, Davor B</creator><creator>Špitálsky, Zdenko</creator><creator>Pavlović, Vladimir B</creator><creator>Budimir, Milica D</creator><creator>Šiffalovič, Peter</creator><creator>Dramićanin, Miroslav D</creator><creator>Mičušík, Matej</creator><creator>Kleinová, Angela</creator><creator>Janigová, Ivica</creator><creator>Marković, Zoran M</creator><creator>Todorović Marković, Biljana M</creator><general>John Wiley & Sons, Ltd</general><general>Wiley Subscription Services, Inc</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8FD</scope><scope>F28</scope><scope>FR3</scope><scope>JG9</scope><orcidid>https://orcid.org/0000-0003-2777-6864</orcidid><orcidid>https://orcid.org/0000-0002-9807-0810</orcidid></search><sort><creationdate>201808</creationdate><title>Simple route for the preparation of graphene/poly(styrene‐b‐butadiene‐b‐styrene) nanocomposite films with enhanced electrical conductivity and hydrophobicity</title><author>Kepić, Dejan P ; Ristić, Ivan S ; Marinović‐Cincović, Milena T ; Peruško, Davor B ; Špitálsky, Zdenko ; Pavlović, Vladimir B ; Budimir, Milica D ; Šiffalovič, Peter ; Dramićanin, Miroslav D ; Mičušík, Matej ; Kleinová, Angela ; Janigová, Ivica ; Marković, Zoran M ; Todorović Marković, Biljana M</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c3260-d582c20ad4ca85f1cd9138305b68da31a6edbb4b2ddba54c7f5a2d6ca749c5c83</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2018</creationdate><topic>Butadiene</topic><topic>Crystal lattices</topic><topic>Crystal structure</topic><topic>Electrical conductivity</topic><topic>electrical properties</topic><topic>Electrical resistivity</topic><topic>Fourier transforms</topic><topic>Graphene</topic><topic>Hydrophobicity</topic><topic>Infrared spectroscopy</topic><topic>Lattice parameters</topic><topic>layered structures</topic><topic>microstructures</topic><topic>Nanocomposites</topic><topic>Nanotubes</topic><topic>Organic chemistry</topic><topic>Parameter modification</topic><topic>Photoelectron spectroscopy</topic><topic>Polystyrene resins</topic><topic>Raman spectroscopy</topic><topic>Spectrum analysis</topic><topic>Styrene</topic><topic>Styrenes</topic><topic>surface analysis</topic><topic>Surface roughness</topic><topic>Vacuum</topic><topic>Vacuum filtration</topic><topic>X ray photoelectron spectroscopy</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Kepić, Dejan P</creatorcontrib><creatorcontrib>Ristić, Ivan S</creatorcontrib><creatorcontrib>Marinović‐Cincović, Milena T</creatorcontrib><creatorcontrib>Peruško, Davor B</creatorcontrib><creatorcontrib>Špitálsky, Zdenko</creatorcontrib><creatorcontrib>Pavlović, Vladimir B</creatorcontrib><creatorcontrib>Budimir, Milica D</creatorcontrib><creatorcontrib>Šiffalovič, Peter</creatorcontrib><creatorcontrib>Dramićanin, Miroslav D</creatorcontrib><creatorcontrib>Mičušík, Matej</creatorcontrib><creatorcontrib>Kleinová, Angela</creatorcontrib><creatorcontrib>Janigová, Ivica</creatorcontrib><creatorcontrib>Marković, Zoran M</creatorcontrib><creatorcontrib>Todorović Marković, Biljana M</creatorcontrib><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>ANTE: Abstracts in New Technology & Engineering</collection><collection>Engineering Research Database</collection><collection>Materials Research Database</collection><jtitle>Polymer international</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Kepić, Dejan P</au><au>Ristić, Ivan S</au><au>Marinović‐Cincović, Milena T</au><au>Peruško, Davor B</au><au>Špitálsky, Zdenko</au><au>Pavlović, Vladimir B</au><au>Budimir, Milica D</au><au>Šiffalovič, Peter</au><au>Dramićanin, Miroslav D</au><au>Mičušík, Matej</au><au>Kleinová, Angela</au><au>Janigová, Ivica</au><au>Marković, Zoran M</au><au>Todorović Marković, Biljana M</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Simple route for the preparation of graphene/poly(styrene‐b‐butadiene‐b‐styrene) nanocomposite films with enhanced electrical conductivity and hydrophobicity</atitle><jtitle>Polymer international</jtitle><date>2018-08</date><risdate>2018</risdate><volume>67</volume><issue>8</issue><spage>1118</spage><epage>1127</epage><pages>1118-1127</pages><issn>0959-8103</issn><eissn>1097-0126</eissn><abstract>This paper reports a simple route for the preparation of graphene/poly(styrene‐b‐butadiene‐b‐styrene) (SBS) nanocomposite films employing a vacuum filtration method. Graphene is exfoliated well by an electrochemical procedure and homogeneously dispersed in the polymer matrix. The prepared nanocomposite films were characterized by XRD, Fourier transform IR (FTIR) spectroscopy, X‐ray photoelectron spectroscopy (XPS), Raman spectroscopy, AFM and SEM. Morphological studies showed that graphene formed a smooth coating over the surface of SBS. The increase in graphene concentration induces the wrinkling of graphene sheets at the composite surface which causes a further increase in surface roughness. The FTIR, Raman and XPS spectra of graphene/SBS nanocomposite films indicate the strong interactions between graphene and the polymer matrix. According to the XRD patterns, introducing SBS into graphene did not modify the graphene structure additionally, i.e. the crystal lattice parameters do not depend on SBS content in graphene/SBS nanocomposite films. The graphene/SBS nanocomposite films also exhibited better hydrophobicity due to the increased surface roughness and lower sheet resistivity (reduced 10 times) compared to exfoliated graphene. © 2018 Society of Chemical Industry
Graphene/poly(styrene‐b‐butadiene‐b‐styrene) films were prepared by the vacuum filtration method. An increase in graphene concentration causes the surface roughness to increase, which leads to better hydrophobicity and lower sheet resistivity.</abstract><cop>Chichester, UK</cop><pub>John Wiley & Sons, Ltd</pub><doi>10.1002/pi.5620</doi><tpages>10</tpages><orcidid>https://orcid.org/0000-0003-2777-6864</orcidid><orcidid>https://orcid.org/0000-0002-9807-0810</orcidid></addata></record> |
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| issn | 0959-8103 1097-0126 |
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| source | Wiley Online Library Journals Frontfile Complete |
| subjects | Butadiene Crystal lattices Crystal structure Electrical conductivity electrical properties Electrical resistivity Fourier transforms Graphene Hydrophobicity Infrared spectroscopy Lattice parameters layered structures microstructures Nanocomposites Nanotubes Organic chemistry Parameter modification Photoelectron spectroscopy Polystyrene resins Raman spectroscopy Spectrum analysis Styrene Styrenes surface analysis Surface roughness Vacuum Vacuum filtration X ray photoelectron spectroscopy |
| title | Simple route for the preparation of graphene/poly(styrene‐b‐butadiene‐b‐styrene) nanocomposite films with enhanced electrical conductivity and hydrophobicity |
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