Ultra-rapid combustion synthesis of Na2FePO4F fluorophosphate host for Li-ion and Na-ion insertion
Exploring soft-chemistry synthesis of Fe-based battery cathode materials, we have optimized combustion synthesis as an ultra-rapid approach to produce Na 2 FePO 4 F fluorophosphate cathode. It yields nanoscale, carbon-coated target product by annealing (at 600 °C) for just 1 min. The purity of the m...
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| Veröffentlicht in: | Ionics 2018-08, Vol.24 (8), p.2187-2192 |
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| container_title | Ionics |
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| creator | Sharma, Lalit Bhatia, Ankush Assaud, Loïc Franger, Sylvain Barpanda, Prabeer |
| description | Exploring soft-chemistry synthesis of Fe-based battery cathode materials, we have optimized combustion synthesis as an ultra-rapid approach to produce Na
2
FePO
4
F fluorophosphate cathode. It yields nanoscale, carbon-coated target product by annealing (at 600 °C) for just 1 min. The purity of the material crystallizing in the orthorhombic structure was confirmed by powder X-ray diffraction pattern and XPS analysis, while the morphology was studied by scanning electron microscopy. The as-synthesized material exhibits good electrochemical performance delivering a first discharge capacity of more than 70 mAh/g at C/10 rate versus both Li
+
/Li and Na
+
/Na, hence acting as an efficient host for both Li-ion and Na-ion insertion. Combustion synthesis can be employed as an economic route for synthesis and rapid screening of various phosphate-based insertion materials. |
| doi_str_mv | 10.1007/s11581-017-2376-3 |
| format | Article |
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2
FePO
4
F fluorophosphate cathode. It yields nanoscale, carbon-coated target product by annealing (at 600 °C) for just 1 min. The purity of the material crystallizing in the orthorhombic structure was confirmed by powder X-ray diffraction pattern and XPS analysis, while the morphology was studied by scanning electron microscopy. The as-synthesized material exhibits good electrochemical performance delivering a first discharge capacity of more than 70 mAh/g at C/10 rate versus both Li
+
/Li and Na
+
/Na, hence acting as an efficient host for both Li-ion and Na-ion insertion. Combustion synthesis can be employed as an economic route for synthesis and rapid screening of various phosphate-based insertion materials.</description><identifier>ISSN: 0947-7047</identifier><identifier>EISSN: 1862-0760</identifier><identifier>DOI: 10.1007/s11581-017-2376-3</identifier><language>eng</language><publisher>Berlin/Heidelberg: Springer Berlin Heidelberg</publisher><subject>1st World Conference on Solid Electrolytes for Advanced Applications: Garnets and Competitors ; Batteries ; Cathodes ; Chemistry ; Chemistry and Materials Science ; Combustion synthesis ; Condensed Matter Physics ; Diffraction ; Diffraction patterns ; Electrochemical analysis ; Electrochemistry ; Electrode materials ; Energy Storage ; Insertion ; Morphology ; Optical and Electronic Materials ; Organic chemistry ; Original Paper ; Pattern analysis ; Renewable and Green Energy ; Scanning electron microscopy ; X ray photoelectron spectroscopy ; X ray powder diffraction ; X-ray diffraction</subject><ispartof>Ionics, 2018-08, Vol.24 (8), p.2187-2192</ispartof><rights>Springer-Verlag GmbH Germany, part of Springer Nature 2017</rights><rights>Copyright Springer Science & Business Media 2018</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c316t-944fc00e207657f12cf2db85df4ada62b29c0dc9147fabeed723a199479004903</citedby><cites>FETCH-LOGICAL-c316t-944fc00e207657f12cf2db85df4ada62b29c0dc9147fabeed723a199479004903</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s11581-017-2376-3$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s11581-017-2376-3$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,776,780,27901,27902,41464,42533,51294</link.rule.ids></links><search><creatorcontrib>Sharma, Lalit</creatorcontrib><creatorcontrib>Bhatia, Ankush</creatorcontrib><creatorcontrib>Assaud, Loïc</creatorcontrib><creatorcontrib>Franger, Sylvain</creatorcontrib><creatorcontrib>Barpanda, Prabeer</creatorcontrib><title>Ultra-rapid combustion synthesis of Na2FePO4F fluorophosphate host for Li-ion and Na-ion insertion</title><title>Ionics</title><addtitle>Ionics</addtitle><description>Exploring soft-chemistry synthesis of Fe-based battery cathode materials, we have optimized combustion synthesis as an ultra-rapid approach to produce Na
2
FePO
4
F fluorophosphate cathode. It yields nanoscale, carbon-coated target product by annealing (at 600 °C) for just 1 min. The purity of the material crystallizing in the orthorhombic structure was confirmed by powder X-ray diffraction pattern and XPS analysis, while the morphology was studied by scanning electron microscopy. The as-synthesized material exhibits good electrochemical performance delivering a first discharge capacity of more than 70 mAh/g at C/10 rate versus both Li
+
/Li and Na
+
/Na, hence acting as an efficient host for both Li-ion and Na-ion insertion. Combustion synthesis can be employed as an economic route for synthesis and rapid screening of various phosphate-based insertion materials.</description><subject>1st World Conference on Solid Electrolytes for Advanced Applications: Garnets and Competitors</subject><subject>Batteries</subject><subject>Cathodes</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Combustion synthesis</subject><subject>Condensed Matter Physics</subject><subject>Diffraction</subject><subject>Diffraction patterns</subject><subject>Electrochemical analysis</subject><subject>Electrochemistry</subject><subject>Electrode materials</subject><subject>Energy Storage</subject><subject>Insertion</subject><subject>Morphology</subject><subject>Optical and Electronic Materials</subject><subject>Organic chemistry</subject><subject>Original Paper</subject><subject>Pattern analysis</subject><subject>Renewable and Green Energy</subject><subject>Scanning electron microscopy</subject><subject>X ray photoelectron spectroscopy</subject><subject>X ray powder diffraction</subject><subject>X-ray diffraction</subject><issn>0947-7047</issn><issn>1862-0760</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2018</creationdate><recordtype>article</recordtype><recordid>eNp1kDFPwzAQhS0EEqXwA9gsMRvOjmPHI6oIIFWUgc6Wk9g0VRsHOxn673EIEhPTveF97-4eQrcU7imAfIiU5gUlQCVhmRQkO0MLWghGQAo4RwtQXBIJXF6iqxj3AEJQJheo2h6GYEgwfdvg2h-rMQ6t73A8dcPOxjZi7_CbYaV93_ASu8Pog-93PvY7M1icxICdD3jdkgkzXZPcP7Ltog1T1jW6cOYQ7c3vXKJt-fSxeiHrzfPr6nFN6oyKgSjOXQ1gWbo4l46y2rGmKvLGcdMYwSqmamhqRbl0prK2kSwzVKW_FABXkC3R3ZzbB_812jjovR9Dl1ZqBiJXjAtaJBedXXXwMQbrdB_aowknTUFPVeq5Sp2q1FOVOksMm5mYvN2nDX_J_0PfDKp2fA</recordid><startdate>20180801</startdate><enddate>20180801</enddate><creator>Sharma, Lalit</creator><creator>Bhatia, Ankush</creator><creator>Assaud, Loïc</creator><creator>Franger, Sylvain</creator><creator>Barpanda, Prabeer</creator><general>Springer Berlin Heidelberg</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20180801</creationdate><title>Ultra-rapid combustion synthesis of Na2FePO4F fluorophosphate host for Li-ion and Na-ion insertion</title><author>Sharma, Lalit ; Bhatia, Ankush ; Assaud, Loïc ; Franger, Sylvain ; Barpanda, Prabeer</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c316t-944fc00e207657f12cf2db85df4ada62b29c0dc9147fabeed723a199479004903</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2018</creationdate><topic>1st World Conference on Solid Electrolytes for Advanced Applications: Garnets and Competitors</topic><topic>Batteries</topic><topic>Cathodes</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Combustion synthesis</topic><topic>Condensed Matter Physics</topic><topic>Diffraction</topic><topic>Diffraction patterns</topic><topic>Electrochemical analysis</topic><topic>Electrochemistry</topic><topic>Electrode materials</topic><topic>Energy Storage</topic><topic>Insertion</topic><topic>Morphology</topic><topic>Optical and Electronic Materials</topic><topic>Organic chemistry</topic><topic>Original Paper</topic><topic>Pattern analysis</topic><topic>Renewable and Green Energy</topic><topic>Scanning electron microscopy</topic><topic>X ray photoelectron spectroscopy</topic><topic>X ray powder diffraction</topic><topic>X-ray diffraction</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Sharma, Lalit</creatorcontrib><creatorcontrib>Bhatia, Ankush</creatorcontrib><creatorcontrib>Assaud, Loïc</creatorcontrib><creatorcontrib>Franger, Sylvain</creatorcontrib><creatorcontrib>Barpanda, Prabeer</creatorcontrib><collection>CrossRef</collection><jtitle>Ionics</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Sharma, Lalit</au><au>Bhatia, Ankush</au><au>Assaud, Loïc</au><au>Franger, Sylvain</au><au>Barpanda, Prabeer</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Ultra-rapid combustion synthesis of Na2FePO4F fluorophosphate host for Li-ion and Na-ion insertion</atitle><jtitle>Ionics</jtitle><stitle>Ionics</stitle><date>2018-08-01</date><risdate>2018</risdate><volume>24</volume><issue>8</issue><spage>2187</spage><epage>2192</epage><pages>2187-2192</pages><issn>0947-7047</issn><eissn>1862-0760</eissn><abstract>Exploring soft-chemistry synthesis of Fe-based battery cathode materials, we have optimized combustion synthesis as an ultra-rapid approach to produce Na
2
FePO
4
F fluorophosphate cathode. It yields nanoscale, carbon-coated target product by annealing (at 600 °C) for just 1 min. The purity of the material crystallizing in the orthorhombic structure was confirmed by powder X-ray diffraction pattern and XPS analysis, while the morphology was studied by scanning electron microscopy. The as-synthesized material exhibits good electrochemical performance delivering a first discharge capacity of more than 70 mAh/g at C/10 rate versus both Li
+
/Li and Na
+
/Na, hence acting as an efficient host for both Li-ion and Na-ion insertion. Combustion synthesis can be employed as an economic route for synthesis and rapid screening of various phosphate-based insertion materials.</abstract><cop>Berlin/Heidelberg</cop><pub>Springer Berlin Heidelberg</pub><doi>10.1007/s11581-017-2376-3</doi><tpages>6</tpages></addata></record> |
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| subjects | 1st World Conference on Solid Electrolytes for Advanced Applications: Garnets and Competitors Batteries Cathodes Chemistry Chemistry and Materials Science Combustion synthesis Condensed Matter Physics Diffraction Diffraction patterns Electrochemical analysis Electrochemistry Electrode materials Energy Storage Insertion Morphology Optical and Electronic Materials Organic chemistry Original Paper Pattern analysis Renewable and Green Energy Scanning electron microscopy X ray photoelectron spectroscopy X ray powder diffraction X-ray diffraction |
| title | Ultra-rapid combustion synthesis of Na2FePO4F fluorophosphate host for Li-ion and Na-ion insertion |
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