Investigation of electrochemical performance on carbon supported tin-selenium bimetallic anodes in lithium-ion batteries
Bimetallic compound, composed of two different metal elements, has emerged as an important class of electrode system. Amorphous carbon materials are widely used in anodes to reduce the internal resistance of electrodes. Therefore, SnSe bimetallic compound uniformly dispersed in acetylene black as a...
Gespeichert in:
| Veröffentlicht in: | Electrochimica acta 2018-03, Vol.266, p.193-201 |
|---|---|
| Hauptverfasser: | , , , , , , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 201 |
|---|---|
| container_issue | |
| container_start_page | 193 |
| container_title | Electrochimica acta |
| container_volume | 266 |
| creator | Yoon, Young Hoon Kim, Doo Soo Kim, MinJung Park, Min Sang Lee, Young-Chul Kim, Kwang Ho Kim, Il Tae Hur, Jaehyun Lee, Seung Geol |
| description | Bimetallic compound, composed of two different metal elements, has emerged as an important class of electrode system. Amorphous carbon materials are widely used in anodes to reduce the internal resistance of electrodes. Therefore, SnSe bimetallic compound uniformly dispersed in acetylene black as a carbon-support has been fabricated for lithium ion batteries by high energy mechanical milling (HEMM) process under argon atmosphere. The SnSe-C composite retains a reversible capacity of 564 mAh g−1 with a coulombic efficiency of 99.8%, at a current rate of 100 mA g−1 after 50 cycles. In the high rate capability test, the SnSe-C composite exhibits the charge capacity of 530 mAh g−1 at 5000 mA g−1 charge rate. Electrochemical impedance spectroscopy (EIS) results indicate that SnSe-C composite shows small increase of surface resistance than that of plain SnSe composite. The enhanced cycle stability of SnSe-C composite can be attributed to the amorphous carbon additive that offers high electrical conductivity as well as a buffer matrix that prevents the volume change during cycling. |
| doi_str_mv | 10.1016/j.electacta.2017.12.188 |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_journals_2065057957</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><els_id>S0013468617327627</els_id><sourcerecordid>2065057957</sourcerecordid><originalsourceid>FETCH-LOGICAL-c380t-91d19af78320e50cde1ffc1f6d2d73051db363ae57ea0f6e2c314f47326a9b7c3</originalsourceid><addsrcrecordid>eNqFkEFr3DAQhUVoodttfkMFPdsZWWvJPobQJAsLuSRnIUujRIttOZJ2af59tN2Qa2BgDvPeG95HyG8GNQMmrvY1jmiyLlM3wGTNmpp13QVZsU7yindt_42sABivNqITP8jPlPYAIIWEFfm3nY-Ysn_W2YeZBkf_p8VgXnDyRo90wehCnPRskBaF0XEoKx2WJcSMlmY_V6mYZn-Y6OAnzHocvaF6DhYT9TMdfX4px-r0YNA5Y_SYfpHvTo8JLz_2mjzd_n28ua92D3fbm-tdZXgHueqZZb12suMNYAvGInPOMCdsYyWHltmBC66xlajBCWwMZxu3kbwRuh-k4Wvy55y7xPB6KFXVPhziXF6qBkQLrexbWVTyrDIxpBTRqSX6Scc3xUCdMKu9-sSsTpgVa1TBXJzXZyeWEkePUSXjscCyPha9ssF_mfEOBWqN6g</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2065057957</pqid></control><display><type>article</type><title>Investigation of electrochemical performance on carbon supported tin-selenium bimetallic anodes in lithium-ion batteries</title><source>Elsevier ScienceDirect Journals</source><creator>Yoon, Young Hoon ; Kim, Doo Soo ; Kim, MinJung ; Park, Min Sang ; Lee, Young-Chul ; Kim, Kwang Ho ; Kim, Il Tae ; Hur, Jaehyun ; Lee, Seung Geol</creator><creatorcontrib>Yoon, Young Hoon ; Kim, Doo Soo ; Kim, MinJung ; Park, Min Sang ; Lee, Young-Chul ; Kim, Kwang Ho ; Kim, Il Tae ; Hur, Jaehyun ; Lee, Seung Geol</creatorcontrib><description>Bimetallic compound, composed of two different metal elements, has emerged as an important class of electrode system. Amorphous carbon materials are widely used in anodes to reduce the internal resistance of electrodes. Therefore, SnSe bimetallic compound uniformly dispersed in acetylene black as a carbon-support has been fabricated for lithium ion batteries by high energy mechanical milling (HEMM) process under argon atmosphere. The SnSe-C composite retains a reversible capacity of 564 mAh g−1 with a coulombic efficiency of 99.8%, at a current rate of 100 mA g−1 after 50 cycles. In the high rate capability test, the SnSe-C composite exhibits the charge capacity of 530 mAh g−1 at 5000 mA g−1 charge rate. Electrochemical impedance spectroscopy (EIS) results indicate that SnSe-C composite shows small increase of surface resistance than that of plain SnSe composite. The enhanced cycle stability of SnSe-C composite can be attributed to the amorphous carbon additive that offers high electrical conductivity as well as a buffer matrix that prevents the volume change during cycling.</description><identifier>ISSN: 0013-4686</identifier><identifier>EISSN: 1873-3859</identifier><identifier>DOI: 10.1016/j.electacta.2017.12.188</identifier><language>eng</language><publisher>Oxford: Elsevier Ltd</publisher><subject>Acetylene ; Amorphous materials ; Anode material ; Anodes ; Batteries ; Bimetallic system ; Bimetals ; Carbon-support ; Conductivity ; Electrical resistivity ; Electrochemical analysis ; Electrochemical impedance spectroscopy ; Electrochemical performance ; Electrodes ; Lithium ; Lithium-ion batteries ; Mechanical milling ; Rechargeable batteries ; Selenium ; Surface resistance ; Tin ; Tin-selenium</subject><ispartof>Electrochimica acta, 2018-03, Vol.266, p.193-201</ispartof><rights>2018 Elsevier Ltd</rights><rights>Copyright Elsevier BV Mar 10, 2018</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c380t-91d19af78320e50cde1ffc1f6d2d73051db363ae57ea0f6e2c314f47326a9b7c3</citedby><cites>FETCH-LOGICAL-c380t-91d19af78320e50cde1ffc1f6d2d73051db363ae57ea0f6e2c314f47326a9b7c3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://www.sciencedirect.com/science/article/pii/S0013468617327627$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>314,776,780,3537,27901,27902,65306</link.rule.ids></links><search><creatorcontrib>Yoon, Young Hoon</creatorcontrib><creatorcontrib>Kim, Doo Soo</creatorcontrib><creatorcontrib>Kim, MinJung</creatorcontrib><creatorcontrib>Park, Min Sang</creatorcontrib><creatorcontrib>Lee, Young-Chul</creatorcontrib><creatorcontrib>Kim, Kwang Ho</creatorcontrib><creatorcontrib>Kim, Il Tae</creatorcontrib><creatorcontrib>Hur, Jaehyun</creatorcontrib><creatorcontrib>Lee, Seung Geol</creatorcontrib><title>Investigation of electrochemical performance on carbon supported tin-selenium bimetallic anodes in lithium-ion batteries</title><title>Electrochimica acta</title><description>Bimetallic compound, composed of two different metal elements, has emerged as an important class of electrode system. Amorphous carbon materials are widely used in anodes to reduce the internal resistance of electrodes. Therefore, SnSe bimetallic compound uniformly dispersed in acetylene black as a carbon-support has been fabricated for lithium ion batteries by high energy mechanical milling (HEMM) process under argon atmosphere. The SnSe-C composite retains a reversible capacity of 564 mAh g−1 with a coulombic efficiency of 99.8%, at a current rate of 100 mA g−1 after 50 cycles. In the high rate capability test, the SnSe-C composite exhibits the charge capacity of 530 mAh g−1 at 5000 mA g−1 charge rate. Electrochemical impedance spectroscopy (EIS) results indicate that SnSe-C composite shows small increase of surface resistance than that of plain SnSe composite. The enhanced cycle stability of SnSe-C composite can be attributed to the amorphous carbon additive that offers high electrical conductivity as well as a buffer matrix that prevents the volume change during cycling.</description><subject>Acetylene</subject><subject>Amorphous materials</subject><subject>Anode material</subject><subject>Anodes</subject><subject>Batteries</subject><subject>Bimetallic system</subject><subject>Bimetals</subject><subject>Carbon-support</subject><subject>Conductivity</subject><subject>Electrical resistivity</subject><subject>Electrochemical analysis</subject><subject>Electrochemical impedance spectroscopy</subject><subject>Electrochemical performance</subject><subject>Electrodes</subject><subject>Lithium</subject><subject>Lithium-ion batteries</subject><subject>Mechanical milling</subject><subject>Rechargeable batteries</subject><subject>Selenium</subject><subject>Surface resistance</subject><subject>Tin</subject><subject>Tin-selenium</subject><issn>0013-4686</issn><issn>1873-3859</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2018</creationdate><recordtype>article</recordtype><recordid>eNqFkEFr3DAQhUVoodttfkMFPdsZWWvJPobQJAsLuSRnIUujRIttOZJ2af59tN2Qa2BgDvPeG95HyG8GNQMmrvY1jmiyLlM3wGTNmpp13QVZsU7yindt_42sABivNqITP8jPlPYAIIWEFfm3nY-Ysn_W2YeZBkf_p8VgXnDyRo90wehCnPRskBaF0XEoKx2WJcSMlmY_V6mYZn-Y6OAnzHocvaF6DhYT9TMdfX4px-r0YNA5Y_SYfpHvTo8JLz_2mjzd_n28ua92D3fbm-tdZXgHueqZZb12suMNYAvGInPOMCdsYyWHltmBC66xlajBCWwMZxu3kbwRuh-k4Wvy55y7xPB6KFXVPhziXF6qBkQLrexbWVTyrDIxpBTRqSX6Scc3xUCdMKu9-sSsTpgVa1TBXJzXZyeWEkePUSXjscCyPha9ssF_mfEOBWqN6g</recordid><startdate>20180310</startdate><enddate>20180310</enddate><creator>Yoon, Young Hoon</creator><creator>Kim, Doo Soo</creator><creator>Kim, MinJung</creator><creator>Park, Min Sang</creator><creator>Lee, Young-Chul</creator><creator>Kim, Kwang Ho</creator><creator>Kim, Il Tae</creator><creator>Hur, Jaehyun</creator><creator>Lee, Seung Geol</creator><general>Elsevier Ltd</general><general>Elsevier BV</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope></search><sort><creationdate>20180310</creationdate><title>Investigation of electrochemical performance on carbon supported tin-selenium bimetallic anodes in lithium-ion batteries</title><author>Yoon, Young Hoon ; Kim, Doo Soo ; Kim, MinJung ; Park, Min Sang ; Lee, Young-Chul ; Kim, Kwang Ho ; Kim, Il Tae ; Hur, Jaehyun ; Lee, Seung Geol</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c380t-91d19af78320e50cde1ffc1f6d2d73051db363ae57ea0f6e2c314f47326a9b7c3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2018</creationdate><topic>Acetylene</topic><topic>Amorphous materials</topic><topic>Anode material</topic><topic>Anodes</topic><topic>Batteries</topic><topic>Bimetallic system</topic><topic>Bimetals</topic><topic>Carbon-support</topic><topic>Conductivity</topic><topic>Electrical resistivity</topic><topic>Electrochemical analysis</topic><topic>Electrochemical impedance spectroscopy</topic><topic>Electrochemical performance</topic><topic>Electrodes</topic><topic>Lithium</topic><topic>Lithium-ion batteries</topic><topic>Mechanical milling</topic><topic>Rechargeable batteries</topic><topic>Selenium</topic><topic>Surface resistance</topic><topic>Tin</topic><topic>Tin-selenium</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Yoon, Young Hoon</creatorcontrib><creatorcontrib>Kim, Doo Soo</creatorcontrib><creatorcontrib>Kim, MinJung</creatorcontrib><creatorcontrib>Park, Min Sang</creatorcontrib><creatorcontrib>Lee, Young-Chul</creatorcontrib><creatorcontrib>Kim, Kwang Ho</creatorcontrib><creatorcontrib>Kim, Il Tae</creatorcontrib><creatorcontrib>Hur, Jaehyun</creatorcontrib><creatorcontrib>Lee, Seung Geol</creatorcontrib><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Electrochimica acta</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Yoon, Young Hoon</au><au>Kim, Doo Soo</au><au>Kim, MinJung</au><au>Park, Min Sang</au><au>Lee, Young-Chul</au><au>Kim, Kwang Ho</au><au>Kim, Il Tae</au><au>Hur, Jaehyun</au><au>Lee, Seung Geol</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Investigation of electrochemical performance on carbon supported tin-selenium bimetallic anodes in lithium-ion batteries</atitle><jtitle>Electrochimica acta</jtitle><date>2018-03-10</date><risdate>2018</risdate><volume>266</volume><spage>193</spage><epage>201</epage><pages>193-201</pages><issn>0013-4686</issn><eissn>1873-3859</eissn><abstract>Bimetallic compound, composed of two different metal elements, has emerged as an important class of electrode system. Amorphous carbon materials are widely used in anodes to reduce the internal resistance of electrodes. Therefore, SnSe bimetallic compound uniformly dispersed in acetylene black as a carbon-support has been fabricated for lithium ion batteries by high energy mechanical milling (HEMM) process under argon atmosphere. The SnSe-C composite retains a reversible capacity of 564 mAh g−1 with a coulombic efficiency of 99.8%, at a current rate of 100 mA g−1 after 50 cycles. In the high rate capability test, the SnSe-C composite exhibits the charge capacity of 530 mAh g−1 at 5000 mA g−1 charge rate. Electrochemical impedance spectroscopy (EIS) results indicate that SnSe-C composite shows small increase of surface resistance than that of plain SnSe composite. The enhanced cycle stability of SnSe-C composite can be attributed to the amorphous carbon additive that offers high electrical conductivity as well as a buffer matrix that prevents the volume change during cycling.</abstract><cop>Oxford</cop><pub>Elsevier Ltd</pub><doi>10.1016/j.electacta.2017.12.188</doi><tpages>9</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0013-4686 |
| ispartof | Electrochimica acta, 2018-03, Vol.266, p.193-201 |
| issn | 0013-4686 1873-3859 |
| language | eng |
| recordid | cdi_proquest_journals_2065057957 |
| source | Elsevier ScienceDirect Journals |
| subjects | Acetylene Amorphous materials Anode material Anodes Batteries Bimetallic system Bimetals Carbon-support Conductivity Electrical resistivity Electrochemical analysis Electrochemical impedance spectroscopy Electrochemical performance Electrodes Lithium Lithium-ion batteries Mechanical milling Rechargeable batteries Selenium Surface resistance Tin Tin-selenium |
| title | Investigation of electrochemical performance on carbon supported tin-selenium bimetallic anodes in lithium-ion batteries |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-31T15%3A10%3A38IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Investigation%20of%20electrochemical%20performance%20on%20carbon%20supported%20tin-selenium%20bimetallic%20anodes%20in%20lithium-ion%20batteries&rft.jtitle=Electrochimica%20acta&rft.au=Yoon,%20Young%20Hoon&rft.date=2018-03-10&rft.volume=266&rft.spage=193&rft.epage=201&rft.pages=193-201&rft.issn=0013-4686&rft.eissn=1873-3859&rft_id=info:doi/10.1016/j.electacta.2017.12.188&rft_dat=%3Cproquest_cross%3E2065057957%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=2065057957&rft_id=info:pmid/&rft_els_id=S0013468617327627&rfr_iscdi=true |