Microstructure and Electrical Transport Properties of Bi3TiNbO9 High-Temperature Piezoceramics

High-density ceramic samples of the Bi 3 TiNbO 9 ferroelectric phase with a layered perovskite-like structure have been produced by tape casting slurry technology and hot pressing processes. The samples have been characterized by X-ray diffraction and dielectric, piezoelectric, and pyroelectric meas...

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Veröffentlicht in:Inorganic materials 2018-07, Vol.54 (7), p.736-743
Hauptverfasser: Spitsin, A. I., Bush, A. A., Kamentsev, K. E., Segalla, A. G., Khramtsov, A. M., Chistyakova, N. A.
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container_end_page 743
container_issue 7
container_start_page 736
container_title Inorganic materials
container_volume 54
creator Spitsin, A. I.
Bush, A. A.
Kamentsev, K. E.
Segalla, A. G.
Khramtsov, A. M.
Chistyakova, N. A.
description High-density ceramic samples of the Bi 3 TiNbO 9 ferroelectric phase with a layered perovskite-like structure have been produced by tape casting slurry technology and hot pressing processes. The samples have been characterized by X-ray diffraction and dielectric, piezoelectric, and pyroelectric measurements. The results demonstrate that the samples have a well-defined texture due to the preferential orientation of the basal planes of their platelike grains across the pressing axis or along the film casting direction. The Curie temperature of the samples has been determined to be T C = 1180 K. The samples have anisotropic electrical transport characteristics. Their piezoelectric constants d 33 in directions perpendicular and parallel to the texture plane is 22 and 5 pC/N, respectively. The conclusion has been drawn that the synthesized materials are potentially attractive for producing high-temperature piezoelectric elements.
doi_str_mv 10.1134/S0020168518070191
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subjects Casting
Chemistry
Chemistry and Materials Science
Curie temperature
Ferroelectric materials
Ferroelectricity
Hot pressing
Industrial Chemistry/Chemical Engineering
Inorganic Chemistry
Materials Science
Perovskite structure
Perovskites
Piezoelectric ceramics
Piezoelectricity
Slurries
Tape casting
Texture
Transport properties
X-ray diffraction
title Microstructure and Electrical Transport Properties of Bi3TiNbO9 High-Temperature Piezoceramics
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