Investigation of inorganic nonlinear optical potassium penta borate tetra hydrate (PPBTH) single crystals grown by slow evaporation method
Borates family crystals were plays vital role in the field of non linear optics (NLO) due to needs of wide range of applications. In this report, NLO crystals (potassium penta borate tetra hydrate (KB5H8O12) are grown by slow evaporation method at room temperature (28° C) and studied their physical...
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| Veröffentlicht in: | Physica. B, Condensed matter Condensed matter, 2018-03, Vol.533, p.17-21 |
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| creator | Arivuselvi, R. Babu, P. Ramesh |
| description | Borates family crystals were plays vital role in the field of non linear optics (NLO) due to needs of wide range of applications. In this report, NLO crystals (potassium penta borate tetra hydrate (KB5H8O12) are grown by slow evaporation method at room temperature (28° C) and studied their physical properties. The harvested single crystals are transparent with the dimension of 12 × 10 × 6 mm3 and colourless. X-ray diffraction of single crystals reveals that the grown crystal belongs to orthorhombic system with non-centrosymmetric space group Pba2. All the absorbed functional groups are present in the order of inorganic compounds expect 1688 cm−1 because of water (OH O blending) molecule present in the pristine. Crystals show transparent in the entire visible region with 5.9 eV optical band gap and also it shows excellence in both second and third order nonlinear optical properties. Crystals can withstand upto 154 °C without any phase changes which is observed using thermal (TGA/DTA) analysis.
•Inorganic single crystals of PPBTH were grown by the slow evaporation technique.•The crystal structure was obtained by single crystal X-ray diffraction analysis.•Z-scan study was used to find the third order NLO parameters of the crystal.•The grown material is thermally stable up to 154 °C. |
| doi_str_mv | 10.1016/j.physb.2017.12.051 |
| format | Article |
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•Inorganic single crystals of PPBTH were grown by the slow evaporation technique.•The crystal structure was obtained by single crystal X-ray diffraction analysis.•Z-scan study was used to find the third order NLO parameters of the crystal.•The grown material is thermally stable up to 154 °C.</description><identifier>ISSN: 0921-4526</identifier><identifier>EISSN: 1873-2135</identifier><identifier>DOI: 10.1016/j.physb.2017.12.051</identifier><language>eng</language><publisher>Amsterdam: Elsevier B.V</publisher><subject>Borates ; Chemical compounds ; Crystal growth ; Differential thermal analysis ; Diffraction ; Evaporation ; Functional groups ; Inorganic compounds ; Kurtz-Perry powder test ; Molecular chains ; Non-centrosymmetric ; Nonlinear optical materials ; Nonlinear optics ; Optical properties ; Phase transitions ; Physical properties ; Potassium ; Single crystals ; Slow evaporation method ; Temperature ; TG-DTA ; X-ray diffraction ; Z-scan study</subject><ispartof>Physica. B, Condensed matter, 2018-03, Vol.533, p.17-21</ispartof><rights>2017 Elsevier B.V.</rights><rights>Copyright Elsevier BV Mar 15, 2018</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c331t-22dcc009f79e5416358a3e4b5a601d5c24df5913c51e9c38bbed39402d0811183</citedby><cites>FETCH-LOGICAL-c331t-22dcc009f79e5416358a3e4b5a601d5c24df5913c51e9c38bbed39402d0811183</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://dx.doi.org/10.1016/j.physb.2017.12.051$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>314,780,784,3550,27924,27925,45995</link.rule.ids></links><search><creatorcontrib>Arivuselvi, R.</creatorcontrib><creatorcontrib>Babu, P. Ramesh</creatorcontrib><title>Investigation of inorganic nonlinear optical potassium penta borate tetra hydrate (PPBTH) single crystals grown by slow evaporation method</title><title>Physica. B, Condensed matter</title><description>Borates family crystals were plays vital role in the field of non linear optics (NLO) due to needs of wide range of applications. In this report, NLO crystals (potassium penta borate tetra hydrate (KB5H8O12) are grown by slow evaporation method at room temperature (28° C) and studied their physical properties. The harvested single crystals are transparent with the dimension of 12 × 10 × 6 mm3 and colourless. X-ray diffraction of single crystals reveals that the grown crystal belongs to orthorhombic system with non-centrosymmetric space group Pba2. All the absorbed functional groups are present in the order of inorganic compounds expect 1688 cm−1 because of water (OH O blending) molecule present in the pristine. Crystals show transparent in the entire visible region with 5.9 eV optical band gap and also it shows excellence in both second and third order nonlinear optical properties. Crystals can withstand upto 154 °C without any phase changes which is observed using thermal (TGA/DTA) analysis.
•Inorganic single crystals of PPBTH were grown by the slow evaporation technique.•The crystal structure was obtained by single crystal X-ray diffraction analysis.•Z-scan study was used to find the third order NLO parameters of the crystal.•The grown material is thermally stable up to 154 °C.</description><subject>Borates</subject><subject>Chemical compounds</subject><subject>Crystal growth</subject><subject>Differential thermal analysis</subject><subject>Diffraction</subject><subject>Evaporation</subject><subject>Functional groups</subject><subject>Inorganic compounds</subject><subject>Kurtz-Perry powder test</subject><subject>Molecular chains</subject><subject>Non-centrosymmetric</subject><subject>Nonlinear optical materials</subject><subject>Nonlinear optics</subject><subject>Optical properties</subject><subject>Phase transitions</subject><subject>Physical properties</subject><subject>Potassium</subject><subject>Single crystals</subject><subject>Slow evaporation method</subject><subject>Temperature</subject><subject>TG-DTA</subject><subject>X-ray diffraction</subject><subject>Z-scan study</subject><issn>0921-4526</issn><issn>1873-2135</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2018</creationdate><recordtype>article</recordtype><recordid>eNp9kL1u3DAQhInAAXJ28gRpCKRxCslcUtRPkcIxktiAAbtwaoIiV3c86EiF5J2hV_BTR-dz7W0WC8y3gxlCvgIrgUF9tS2nzZz6kjNoSuAlk_CBrKBtRMFByDOyYh2HopK8_kTOU9qyZaCBFXm58wdM2a11dsHTMFDnQ1xr7wz1wY_Oo440TNkZPdIpZJ2S2-_ohD5r2oeoM9KMOWq6me3rdfn4-PPp9jtNzq9HpCbOKesx0XUMz572M01jeKZ40NORPrruMG-C_Uw-DosOv7ztC_L396-nm9vi_uHP3c31fWGEgFxwbo1hrBuaDmUFtZCtFlj1UtcMrDS8soPsQBgJ2BnR9j1a0VWMW9YCQCsuyLfT3ymGf_slvNqGffSLpeKsFo2sWF0vKnFSmRhSijioKbqdjrMCpo6lq616LV0dS1fA1VL6Qv04UbgEODiMKhmH3qB1EU1WNrh3-f9ShI4r</recordid><startdate>20180315</startdate><enddate>20180315</enddate><creator>Arivuselvi, R.</creator><creator>Babu, P. Ramesh</creator><general>Elsevier B.V</general><general>Elsevier BV</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7U5</scope><scope>8FD</scope><scope>L7M</scope></search><sort><creationdate>20180315</creationdate><title>Investigation of inorganic nonlinear optical potassium penta borate tetra hydrate (PPBTH) single crystals grown by slow evaporation method</title><author>Arivuselvi, R. ; Babu, P. Ramesh</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c331t-22dcc009f79e5416358a3e4b5a601d5c24df5913c51e9c38bbed39402d0811183</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2018</creationdate><topic>Borates</topic><topic>Chemical compounds</topic><topic>Crystal growth</topic><topic>Differential thermal analysis</topic><topic>Diffraction</topic><topic>Evaporation</topic><topic>Functional groups</topic><topic>Inorganic compounds</topic><topic>Kurtz-Perry powder test</topic><topic>Molecular chains</topic><topic>Non-centrosymmetric</topic><topic>Nonlinear optical materials</topic><topic>Nonlinear optics</topic><topic>Optical properties</topic><topic>Phase transitions</topic><topic>Physical properties</topic><topic>Potassium</topic><topic>Single crystals</topic><topic>Slow evaporation method</topic><topic>Temperature</topic><topic>TG-DTA</topic><topic>X-ray diffraction</topic><topic>Z-scan study</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Arivuselvi, R.</creatorcontrib><creatorcontrib>Babu, P. Ramesh</creatorcontrib><collection>CrossRef</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>Technology Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Physica. B, Condensed matter</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Arivuselvi, R.</au><au>Babu, P. Ramesh</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Investigation of inorganic nonlinear optical potassium penta borate tetra hydrate (PPBTH) single crystals grown by slow evaporation method</atitle><jtitle>Physica. B, Condensed matter</jtitle><date>2018-03-15</date><risdate>2018</risdate><volume>533</volume><spage>17</spage><epage>21</epage><pages>17-21</pages><issn>0921-4526</issn><eissn>1873-2135</eissn><abstract>Borates family crystals were plays vital role in the field of non linear optics (NLO) due to needs of wide range of applications. In this report, NLO crystals (potassium penta borate tetra hydrate (KB5H8O12) are grown by slow evaporation method at room temperature (28° C) and studied their physical properties. The harvested single crystals are transparent with the dimension of 12 × 10 × 6 mm3 and colourless. X-ray diffraction of single crystals reveals that the grown crystal belongs to orthorhombic system with non-centrosymmetric space group Pba2. All the absorbed functional groups are present in the order of inorganic compounds expect 1688 cm−1 because of water (OH O blending) molecule present in the pristine. Crystals show transparent in the entire visible region with 5.9 eV optical band gap and also it shows excellence in both second and third order nonlinear optical properties. Crystals can withstand upto 154 °C without any phase changes which is observed using thermal (TGA/DTA) analysis.
•Inorganic single crystals of PPBTH were grown by the slow evaporation technique.•The crystal structure was obtained by single crystal X-ray diffraction analysis.•Z-scan study was used to find the third order NLO parameters of the crystal.•The grown material is thermally stable up to 154 °C.</abstract><cop>Amsterdam</cop><pub>Elsevier B.V</pub><doi>10.1016/j.physb.2017.12.051</doi><tpages>5</tpages></addata></record> |
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| subjects | Borates Chemical compounds Crystal growth Differential thermal analysis Diffraction Evaporation Functional groups Inorganic compounds Kurtz-Perry powder test Molecular chains Non-centrosymmetric Nonlinear optical materials Nonlinear optics Optical properties Phase transitions Physical properties Potassium Single crystals Slow evaporation method Temperature TG-DTA X-ray diffraction Z-scan study |
| title | Investigation of inorganic nonlinear optical potassium penta borate tetra hydrate (PPBTH) single crystals grown by slow evaporation method |
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