A Study of Adsorption of 5-Mercaptopentyl-3-amino-1,2,4-triazole on Copper in Neutral Solutions
The inhibiting action by 5-mercaptopetyl-3-amino-1,2,4-triazole and its adsorption on copper in neutral borate buffer solutions were studied. The potentiodynamic curves were used to detect the influence of the inhibitor concentration on the anodic dissolution current and activation potential of pass...
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Veröffentlicht in: | Protection of metals and physical chemistry of surfaces 2017-12, Vol.53 (7), p.1252-1258 |
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creator | Arkhipushkin, I. A. Vagramyan, T. A. Shikhalev, Kh. S. Kazansky, L. P. |
description | The inhibiting action by 5-mercaptopetyl-3-amino-1,2,4-triazole and its adsorption on copper in neutral borate buffer solutions were studied. The potentiodynamic curves were used to detect the influence of the inhibitor concentration on the anodic dissolution current and activation potential of passive state. X-ray photoelectron spectroscopy was applied to determine both the composition and thickness of surface films as a function of the exposure time of the sample in a solution containing the inhibitor. Quantum-chemical calculations made it possible to identify the most probable structure of a copper–inhibitor complex. |
doi_str_mv | 10.1134/S2070205117070036 |
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A. ; Vagramyan, T. A. ; Shikhalev, Kh. S. ; Kazansky, L. P.</creator><creatorcontrib>Arkhipushkin, I. A. ; Vagramyan, T. A. ; Shikhalev, Kh. S. ; Kazansky, L. P.</creatorcontrib><description>The inhibiting action by 5-mercaptopetyl-3-amino-1,2,4-triazole and its adsorption on copper in neutral borate buffer solutions were studied. The potentiodynamic curves were used to detect the influence of the inhibitor concentration on the anodic dissolution current and activation potential of passive state. X-ray photoelectron spectroscopy was applied to determine both the composition and thickness of surface films as a function of the exposure time of the sample in a solution containing the inhibitor. Quantum-chemical calculations made it possible to identify the most probable structure of a copper–inhibitor complex.</description><identifier>ISSN: 2070-2051</identifier><identifier>EISSN: 2070-206X</identifier><identifier>DOI: 10.1134/S2070205117070036</identifier><language>eng</language><publisher>Moscow: Pleiades Publishing</publisher><subject>Adsorption ; Anodic dissolution ; Buffer solutions ; Characterization and Evaluation of Materials ; Chemistry and Materials Science ; Coordination compounds ; Copper ; Corrosion and Coatings ; Corrosion Inhibitors ; Dissolution ; Industrial Chemistry/Chemical Engineering ; Inhibitors ; Inorganic Chemistry ; Materials Science ; Metallic Materials ; Organic chemistry ; Quantum chemistry ; Thickness ; Tribology</subject><ispartof>Protection of metals and physical chemistry of surfaces, 2017-12, Vol.53 (7), p.1252-1258</ispartof><rights>Pleiades Publishing, Ltd. 2017</rights><rights>Copyright Springer Science & Business Media 2017</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c316t-51858d583866e7a549fa2dc123b94ce4c946ae23ddb23463165321ffd81b0f13</citedby><cites>FETCH-LOGICAL-c316t-51858d583866e7a549fa2dc123b94ce4c946ae23ddb23463165321ffd81b0f13</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1134/S2070205117070036$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1134/S2070205117070036$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,776,780,27903,27904,41467,42536,51297</link.rule.ids></links><search><creatorcontrib>Arkhipushkin, I. A.</creatorcontrib><creatorcontrib>Vagramyan, T. A.</creatorcontrib><creatorcontrib>Shikhalev, Kh. S.</creatorcontrib><creatorcontrib>Kazansky, L. P.</creatorcontrib><title>A Study of Adsorption of 5-Mercaptopentyl-3-amino-1,2,4-triazole on Copper in Neutral Solutions</title><title>Protection of metals and physical chemistry of surfaces</title><addtitle>Prot Met Phys Chem Surf</addtitle><description>The inhibiting action by 5-mercaptopetyl-3-amino-1,2,4-triazole and its adsorption on copper in neutral borate buffer solutions were studied. The potentiodynamic curves were used to detect the influence of the inhibitor concentration on the anodic dissolution current and activation potential of passive state. X-ray photoelectron spectroscopy was applied to determine both the composition and thickness of surface films as a function of the exposure time of the sample in a solution containing the inhibitor. Quantum-chemical calculations made it possible to identify the most probable structure of a copper–inhibitor complex.</description><subject>Adsorption</subject><subject>Anodic dissolution</subject><subject>Buffer solutions</subject><subject>Characterization and Evaluation of Materials</subject><subject>Chemistry and Materials Science</subject><subject>Coordination compounds</subject><subject>Copper</subject><subject>Corrosion and Coatings</subject><subject>Corrosion Inhibitors</subject><subject>Dissolution</subject><subject>Industrial Chemistry/Chemical Engineering</subject><subject>Inhibitors</subject><subject>Inorganic Chemistry</subject><subject>Materials Science</subject><subject>Metallic Materials</subject><subject>Organic chemistry</subject><subject>Quantum chemistry</subject><subject>Thickness</subject><subject>Tribology</subject><issn>2070-2051</issn><issn>2070-206X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2017</creationdate><recordtype>article</recordtype><recordid>eNp1kD9PwzAQxS0EEqXwAdgisdbg8784Y1VBQSowtAOb5SYOSpXGwXaG8ulxVAQDYrp3p997Jz2EroHcAjB-t6YkJ5QIgDwJwuQJmownTIl8O_3RAs7RRQg7QqTMVT5Bep6t41AdMldn8yo438fGdeMm8LP1pemj620XDy1m2OybzmGY0RnH0Tfm07U2S_TC9b31WdNlL3aI3rTZ2rXDGBQu0Vlt2mCvvucUbR7uN4tHvHpdPi3mK1wykBELUEJVQjElpc2N4EVtaFUCZduCl5aXBZfGUlZVW8q4TB7BKNR1pWBLamBTdHOM7b37GGyIeucG36WPOhXAuCqU4omCI1V6F4K3te59szf-oIHosUb9p8bkoUdPSGz3bv1v8v-mL8Zycgw</recordid><startdate>20171201</startdate><enddate>20171201</enddate><creator>Arkhipushkin, I. 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A.</creatorcontrib><creatorcontrib>Vagramyan, T. A.</creatorcontrib><creatorcontrib>Shikhalev, Kh. S.</creatorcontrib><creatorcontrib>Kazansky, L. P.</creatorcontrib><collection>CrossRef</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Protection of metals and physical chemistry of surfaces</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Arkhipushkin, I. A.</au><au>Vagramyan, T. A.</au><au>Shikhalev, Kh. S.</au><au>Kazansky, L. P.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>A Study of Adsorption of 5-Mercaptopentyl-3-amino-1,2,4-triazole on Copper in Neutral Solutions</atitle><jtitle>Protection of metals and physical chemistry of surfaces</jtitle><stitle>Prot Met Phys Chem Surf</stitle><date>2017-12-01</date><risdate>2017</risdate><volume>53</volume><issue>7</issue><spage>1252</spage><epage>1258</epage><pages>1252-1258</pages><issn>2070-2051</issn><eissn>2070-206X</eissn><abstract>The inhibiting action by 5-mercaptopetyl-3-amino-1,2,4-triazole and its adsorption on copper in neutral borate buffer solutions were studied. The potentiodynamic curves were used to detect the influence of the inhibitor concentration on the anodic dissolution current and activation potential of passive state. X-ray photoelectron spectroscopy was applied to determine both the composition and thickness of surface films as a function of the exposure time of the sample in a solution containing the inhibitor. Quantum-chemical calculations made it possible to identify the most probable structure of a copper–inhibitor complex.</abstract><cop>Moscow</cop><pub>Pleiades Publishing</pub><doi>10.1134/S2070205117070036</doi><tpages>7</tpages></addata></record> |
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subjects | Adsorption Anodic dissolution Buffer solutions Characterization and Evaluation of Materials Chemistry and Materials Science Coordination compounds Copper Corrosion and Coatings Corrosion Inhibitors Dissolution Industrial Chemistry/Chemical Engineering Inhibitors Inorganic Chemistry Materials Science Metallic Materials Organic chemistry Quantum chemistry Thickness Tribology |
title | A Study of Adsorption of 5-Mercaptopentyl-3-amino-1,2,4-triazole on Copper in Neutral Solutions |
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