A Study of Adsorption of 5-Mercaptopentyl-3-amino-1,2,4-triazole on Copper in Neutral Solutions

The inhibiting action by 5-mercaptopetyl-3-amino-1,2,4-triazole and its adsorption on copper in neutral borate buffer solutions were studied. The potentiodynamic curves were used to detect the influence of the inhibitor concentration on the anodic dissolution current and activation potential of pass...

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Veröffentlicht in:Protection of metals and physical chemistry of surfaces 2017-12, Vol.53 (7), p.1252-1258
Hauptverfasser: Arkhipushkin, I. A., Vagramyan, T. A., Shikhalev, Kh. S., Kazansky, L. P.
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container_issue 7
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container_title Protection of metals and physical chemistry of surfaces
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creator Arkhipushkin, I. A.
Vagramyan, T. A.
Shikhalev, Kh. S.
Kazansky, L. P.
description The inhibiting action by 5-mercaptopetyl-3-amino-1,2,4-triazole and its adsorption on copper in neutral borate buffer solutions were studied. The potentiodynamic curves were used to detect the influence of the inhibitor concentration on the anodic dissolution current and activation potential of passive state. X-ray photoelectron spectroscopy was applied to determine both the composition and thickness of surface films as a function of the exposure time of the sample in a solution containing the inhibitor. Quantum-chemical calculations made it possible to identify the most probable structure of a copper–inhibitor complex.
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subjects Adsorption
Anodic dissolution
Buffer solutions
Characterization and Evaluation of Materials
Chemistry and Materials Science
Coordination compounds
Copper
Corrosion and Coatings
Corrosion Inhibitors
Dissolution
Industrial Chemistry/Chemical Engineering
Inhibitors
Inorganic Chemistry
Materials Science
Metallic Materials
Organic chemistry
Quantum chemistry
Thickness
Tribology
title A Study of Adsorption of 5-Mercaptopentyl-3-amino-1,2,4-triazole on Copper in Neutral Solutions
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