Three atropisomers of biphenyl: twist by tunable para substituents
The geometrical twist of aryl-aryl bond in biphenyl by weakly coordinating anion and selone at the para position has not been clear so far. We report here the synthesis and investigation into the diverse structural properties of biphenyl with weakly coordinating biphenyl imidazolium salts and neutra...
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| Veröffentlicht in: | Journal of chemical sciences (Bangalore, India) India), 2018-07, Vol.130 (7), p.1-7, Article 82 |
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| container_title | Journal of chemical sciences (Bangalore, India) |
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| creator | Karupnaswamy, Ramesh Ganesan, Prabusankar |
| description | The geometrical twist of aryl-aryl bond in biphenyl by weakly coordinating anion and selone at the
para
position has not been clear so far. We report here the synthesis and investigation into the diverse structural properties of biphenyl with weakly coordinating biphenyl imidazolium salts and neutral imidazole selone that exhibit three atropisomers of biphenyl. The approaches underline the diversity of the effects of
para
substituent with dynamic nature at biphenyl molecule.
Graphical Abstract
SYNOPSIS
The synthesis and investigation into the diverse structural properties of three atropisomers of biphenyl tuned by
para
substituted weakly coordinating imidazolium salts and neutral imidazole selone are reported. |
| doi_str_mv | 10.1007/s12039-018-1482-8 |
| format | Article |
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para
position has not been clear so far. We report here the synthesis and investigation into the diverse structural properties of biphenyl with weakly coordinating biphenyl imidazolium salts and neutral imidazole selone that exhibit three atropisomers of biphenyl. The approaches underline the diversity of the effects of
para
substituent with dynamic nature at biphenyl molecule.
Graphical Abstract
SYNOPSIS
The synthesis and investigation into the diverse structural properties of three atropisomers of biphenyl tuned by
para
substituted weakly coordinating imidazolium salts and neutral imidazole selone are reported.</description><identifier>ISSN: 0974-3626</identifier><identifier>EISSN: 0973-7103</identifier><identifier>DOI: 10.1007/s12039-018-1482-8</identifier><language>eng</language><publisher>New Delhi: Springer India</publisher><subject>Aromatic compounds ; Chemical synthesis ; Chemistry ; Chemistry and Materials Science ; Chemistry/Food Science ; Imidazole ; Molecular chains ; Regular Article</subject><ispartof>Journal of chemical sciences (Bangalore, India), 2018-07, Vol.130 (7), p.1-7, Article 82</ispartof><rights>Indian Academy of Sciences 2018</rights><rights>Copyright Springer Science & Business Media 2018</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c359t-eddd9f5cfa27a2630ec1752cd31376a660a079d787f2525a07418697f9b12e8b3</citedby><cites>FETCH-LOGICAL-c359t-eddd9f5cfa27a2630ec1752cd31376a660a079d787f2525a07418697f9b12e8b3</cites><orcidid>0000-0003-1772-135X</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s12039-018-1482-8$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s12039-018-1482-8$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,776,780,27901,27902,41464,42533,51294</link.rule.ids></links><search><creatorcontrib>Karupnaswamy, Ramesh</creatorcontrib><creatorcontrib>Ganesan, Prabusankar</creatorcontrib><title>Three atropisomers of biphenyl: twist by tunable para substituents</title><title>Journal of chemical sciences (Bangalore, India)</title><addtitle>J Chem Sci</addtitle><description>The geometrical twist of aryl-aryl bond in biphenyl by weakly coordinating anion and selone at the
para
position has not been clear so far. We report here the synthesis and investigation into the diverse structural properties of biphenyl with weakly coordinating biphenyl imidazolium salts and neutral imidazole selone that exhibit three atropisomers of biphenyl. The approaches underline the diversity of the effects of
para
substituent with dynamic nature at biphenyl molecule.
Graphical Abstract
SYNOPSIS
The synthesis and investigation into the diverse structural properties of three atropisomers of biphenyl tuned by
para
substituted weakly coordinating imidazolium salts and neutral imidazole selone are reported.</description><subject>Aromatic compounds</subject><subject>Chemical synthesis</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Chemistry/Food Science</subject><subject>Imidazole</subject><subject>Molecular chains</subject><subject>Regular Article</subject><issn>0974-3626</issn><issn>0973-7103</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2018</creationdate><recordtype>article</recordtype><recordid>eNp1kMFKxDAQhoMouK4-gLeA5-gkaZPUmy6uCgte1nNI28TtstvWTIrs29u1gidPMwPf_w98hFxzuOUA-g65AFkw4IbxzAhmTsgMCi2Z5iBPf_aMSSXUOblA3AJIk2k5I4_rTfSeuhS7vsFu7yPSLtCy6Te-PezuafpqMNHyQNPQunLnae-ioziUmJo0-DbhJTkLbof-6nfOyfvyab14Yau359fFw4pVMi8S83VdFyGvghPaCSXBV1znoqoll1o5pcCBLmptdBC5yMcj40YVOhQlF96Uck5upt4-dp-Dx2S33RDb8aUVoIQArlQ-UnyiqtghRh9sH5u9iwfLwR5V2UmVHVXZoyprxoyYMjiy7YePf83_h74BP5VrbQ</recordid><startdate>20180701</startdate><enddate>20180701</enddate><creator>Karupnaswamy, Ramesh</creator><creator>Ganesan, Prabusankar</creator><general>Springer India</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><orcidid>https://orcid.org/0000-0003-1772-135X</orcidid></search><sort><creationdate>20180701</creationdate><title>Three atropisomers of biphenyl: twist by tunable para substituents</title><author>Karupnaswamy, Ramesh ; Ganesan, Prabusankar</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c359t-eddd9f5cfa27a2630ec1752cd31376a660a079d787f2525a07418697f9b12e8b3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2018</creationdate><topic>Aromatic compounds</topic><topic>Chemical synthesis</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Chemistry/Food Science</topic><topic>Imidazole</topic><topic>Molecular chains</topic><topic>Regular Article</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Karupnaswamy, Ramesh</creatorcontrib><creatorcontrib>Ganesan, Prabusankar</creatorcontrib><collection>CrossRef</collection><jtitle>Journal of chemical sciences (Bangalore, India)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Karupnaswamy, Ramesh</au><au>Ganesan, Prabusankar</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Three atropisomers of biphenyl: twist by tunable para substituents</atitle><jtitle>Journal of chemical sciences (Bangalore, India)</jtitle><stitle>J Chem Sci</stitle><date>2018-07-01</date><risdate>2018</risdate><volume>130</volume><issue>7</issue><spage>1</spage><epage>7</epage><pages>1-7</pages><artnum>82</artnum><issn>0974-3626</issn><eissn>0973-7103</eissn><abstract>The geometrical twist of aryl-aryl bond in biphenyl by weakly coordinating anion and selone at the
para
position has not been clear so far. We report here the synthesis and investigation into the diverse structural properties of biphenyl with weakly coordinating biphenyl imidazolium salts and neutral imidazole selone that exhibit three atropisomers of biphenyl. The approaches underline the diversity of the effects of
para
substituent with dynamic nature at biphenyl molecule.
Graphical Abstract
SYNOPSIS
The synthesis and investigation into the diverse structural properties of three atropisomers of biphenyl tuned by
para
substituted weakly coordinating imidazolium salts and neutral imidazole selone are reported.</abstract><cop>New Delhi</cop><pub>Springer India</pub><doi>10.1007/s12039-018-1482-8</doi><tpages>7</tpages><orcidid>https://orcid.org/0000-0003-1772-135X</orcidid><oa>free_for_read</oa></addata></record> |
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| ispartof | Journal of chemical sciences (Bangalore, India), 2018-07, Vol.130 (7), p.1-7, Article 82 |
| issn | 0974-3626 0973-7103 |
| language | eng |
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| source | SpringerLink Journals; EZB-FREE-00999 freely available EZB journals; Alma/SFX Local Collection; Free Full-Text Journals in Chemistry |
| subjects | Aromatic compounds Chemical synthesis Chemistry Chemistry and Materials Science Chemistry/Food Science Imidazole Molecular chains Regular Article |
| title | Three atropisomers of biphenyl: twist by tunable para substituents |
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