Comprehensive investigation of the interfacial misfit array formation in GaSb/GaAs material system

A comprehensive investigation of the interfacial misfit (IMF) array formation has been carried out. The studies were based on the static phase diagram for GaAs (001) surface and As 2 dimers on the surface. Prior to the initiation of the GaSb growth two attempts of the temperature decreasing were per...

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Veröffentlicht in:Applied physics. A, Materials science & processing Materials science & processing, 2018-07, Vol.124 (7), p.1-12, Article 512
Hauptverfasser: Jasik, Agata, Sankowska, Iwona, Wawro, Andrzej, Ratajczak, Jacek, Jakieła, Rafał, Pierścińska, Dorota, Smoczyński, Dariusz, Czuba, Krzysztof, Regiński, Kazimierz
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container_title Applied physics. A, Materials science & processing
container_volume 124
creator Jasik, Agata
Sankowska, Iwona
Wawro, Andrzej
Ratajczak, Jacek
Jakieła, Rafał
Pierścińska, Dorota
Smoczyński, Dariusz
Czuba, Krzysztof
Regiński, Kazimierz
description A comprehensive investigation of the interfacial misfit (IMF) array formation has been carried out. The studies were based on the static phase diagram for GaAs (001) surface and As 2 dimers on the surface. Prior to the initiation of the GaSb growth two attempts of the temperature decreasing were performed: before and after the GaAs termination. The GaAs was grown in the optimal conditions for GaSb material. The influence of the interruption time on GaSb/GaAs heterostructure parameters was examined. Two cases were investigated: with and without Sb-soaking of the GaAs surface. The periodic array of edge dislocations at GaSb/GaAs interface was confirmed using Burger’s circuit theory. Careful examination of misfit surroundings revealed one uncompleted Burger’s vector that indicated one dislocation of mixed type among eight of the edge type. The distance between lattice sites of dislocations was 5.51 nm on average. The crystal quality of 5.0 µm GaSb layer was characterized by FWHM 2 θ / ω  = 42 arcsec, FWHM RC  = 125 arcsec. The EPD = 4 × 10 6 cm − 2 was estimated after etching in FeCl 3 :HCl solution. The Δ q z /Δ q x ratio of 0.60 for 5.0 µm GaSb layer was higher than for 2.5 µm GaSb layer of 0.59. The probable reason was the thickness-dependent 60° dislocation density. The electrical parameters measured for 2.5 µm GaSb were: p  = 4.0 × 10 16 cm −3 (2.0 × 10 16 cm −3 ) and µ  = 599 cm 2 /V s (3420 cm 2 /V s) at 300 K (77 K).
doi_str_mv 10.1007/s00339-018-1931-8
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The EPD = 4 × 10 6 cm − 2 was estimated after etching in FeCl 3 :HCl solution. The Δ q z /Δ q x ratio of 0.60 for 5.0 µm GaSb layer was higher than for 2.5 µm GaSb layer of 0.59. The probable reason was the thickness-dependent 60° dislocation density. The electrical parameters measured for 2.5 µm GaSb were: p  = 4.0 × 10 16 cm −3 (2.0 × 10 16 cm −3 ) and µ  = 599 cm 2 /V s (3420 cm 2 /V s) at 300 K (77 K).</description><identifier>ISSN: 0947-8396</identifier><identifier>EISSN: 1432-0630</identifier><identifier>DOI: 10.1007/s00339-018-1931-8</identifier><language>eng</language><publisher>Berlin/Heidelberg: Springer Berlin Heidelberg</publisher><subject>Applied physics ; Arrays ; Characterization and Evaluation of Materials ; Condensed Matter Physics ; Crystal lattices ; Dimers ; Dislocation density ; Edge dislocations ; Gallium antimonides ; Iron chlorides ; Lattice sites ; Machines ; Manufacturing ; Materials science ; Nanotechnology ; Optical and Electronic Materials ; Parameters ; Physics ; Physics and Astronomy ; Processes ; Surfaces and Interfaces ; Thin Films</subject><ispartof>Applied physics. 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A, Materials science &amp; processing</title><addtitle>Appl. Phys. A</addtitle><description>A comprehensive investigation of the interfacial misfit (IMF) array formation has been carried out. The studies were based on the static phase diagram for GaAs (001) surface and As 2 dimers on the surface. Prior to the initiation of the GaSb growth two attempts of the temperature decreasing were performed: before and after the GaAs termination. The GaAs was grown in the optimal conditions for GaSb material. The influence of the interruption time on GaSb/GaAs heterostructure parameters was examined. Two cases were investigated: with and without Sb-soaking of the GaAs surface. The periodic array of edge dislocations at GaSb/GaAs interface was confirmed using Burger’s circuit theory. Careful examination of misfit surroundings revealed one uncompleted Burger’s vector that indicated one dislocation of mixed type among eight of the edge type. 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The EPD = 4 × 10 6 cm − 2 was estimated after etching in FeCl 3 :HCl solution. The Δ q z /Δ q x ratio of 0.60 for 5.0 µm GaSb layer was higher than for 2.5 µm GaSb layer of 0.59. The probable reason was the thickness-dependent 60° dislocation density. The electrical parameters measured for 2.5 µm GaSb were: p  = 4.0 × 10 16 cm −3 (2.0 × 10 16 cm −3 ) and µ  = 599 cm 2 /V s (3420 cm 2 /V s) at 300 K (77 K).</abstract><cop>Berlin/Heidelberg</cop><pub>Springer Berlin Heidelberg</pub><doi>10.1007/s00339-018-1931-8</doi><tpages>12</tpages><orcidid>https://orcid.org/0000-0003-4051-499X</orcidid><oa>free_for_read</oa></addata></record>
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subjects Applied physics
Arrays
Characterization and Evaluation of Materials
Condensed Matter Physics
Crystal lattices
Dimers
Dislocation density
Edge dislocations
Gallium antimonides
Iron chlorides
Lattice sites
Machines
Manufacturing
Materials science
Nanotechnology
Optical and Electronic Materials
Parameters
Physics
Physics and Astronomy
Processes
Surfaces and Interfaces
Thin Films
title Comprehensive investigation of the interfacial misfit array formation in GaSb/GaAs material system
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