Directed Aminomethylation of Pyrrole, Indole, and Carbazole with N,N,N′,N′-Tetramethylmethanediamine

Catalytic aminomethylation of pyrrole and indole with N , N , N′ , N′ -tetramethylmethanediamine in the presence of 5 mol % of ZrOCl 2 ·8H 2 O proceeds selectively at the positions 2 , 5 of pyrrole and 1 , 3 of indole. Carbazole under the same conditions affords 3-formyl-9-aminomethyl derivative. Th...

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Veröffentlicht in:	Russian journal of organic chemistry 2018-05, Vol.54 (5), p.701-706
Hauptverfasser:	Akhmetova, V. R., Bikbulatova, E. M., Akhmadiev, N. S., Yanybin, V. M., Boiko, T. F., Kunakova, R. V., Ibragimov, A. G.
Format:	Artikel
Sprache:	eng
Schlagworte:	Carbazoles Catalysis Chemistry Chemistry and Materials Science Nitrogen Organic Chemistry Potassium carbonate Substrates
Online-Zugang:	Volltext
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