Refinement Mechanism of Bi Addition on the Microstructure of Rapidly Solidified Sn-3.5Ag Eutectic Solder for Microelectronic Packaging

The effects of Bi on the microstructure of Sn-3.5Ag eutectic solder ribbon prepared by rapid solidification was investigated by optical microscopy, scanning electron microscopy and energy dispersive spectroscopy. Bi refines the primary β-Sn phase and eutectic structure. The mechanism was investigate...

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Veröffentlicht in:Journal of electronic materials 2018-09, Vol.47 (9), p.5588-5594
Hauptverfasser: Liu, Shengfa, Xiong, Wenyong, Xiong, Jieran, Tan, Guanghua, Hu, Zhebing, Chen, Chen, Huang, Shangyu
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container_issue 9
container_start_page 5588
container_title Journal of electronic materials
container_volume 47
creator Liu, Shengfa
Xiong, Wenyong
Xiong, Jieran
Tan, Guanghua
Hu, Zhebing
Chen, Chen
Huang, Shangyu
description The effects of Bi on the microstructure of Sn-3.5Ag eutectic solder ribbon prepared by rapid solidification was investigated by optical microscopy, scanning electron microscopy and energy dispersive spectroscopy. Bi refines the primary β-Sn phase and eutectic structure. The mechanism was investigated using differential scanning calorimetry and classical nucleation theory, respectively. The results show that the primary β-Sn phase and eutectic structure can be refined by adding a small amount of Bi. The refinement of the primary β-Sn phase is attributed to high compositional undercooling by Bi addition. The refinement of eutectic structure is caused by the reduction of critical nucleation radius and critical nucleation energy due to Bi segregation. With the addition of 0.3 wt.% Bi, the shear strength of solder joints increases by 12.15%.
doi_str_mv 10.1007/s11664-018-6448-6
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Bi refines the primary β-Sn phase and eutectic structure. The mechanism was investigated using differential scanning calorimetry and classical nucleation theory, respectively. The results show that the primary β-Sn phase and eutectic structure can be refined by adding a small amount of Bi. The refinement of the primary β-Sn phase is attributed to high compositional undercooling by Bi addition. The refinement of eutectic structure is caused by the reduction of critical nucleation radius and critical nucleation energy due to Bi segregation. With the addition of 0.3 wt.% Bi, the shear strength of solder joints increases by 12.15%.</description><identifier>ISSN: 0361-5235</identifier><identifier>EISSN: 1543-186X</identifier><identifier>DOI: 10.1007/s11664-018-6448-6</identifier><language>eng</language><publisher>New York: Springer US</publisher><subject>Bismuth ; Characterization and Evaluation of Materials ; Chemistry and Materials Science ; Electronic packaging ; Electronics and Microelectronics ; Instrumentation ; Materials Science ; Microstructure ; Nucleation ; Optical and Electronic Materials ; Optical microscopy ; Rapid solidification ; Scanning electron microscopy ; Shear strength ; Solid State Physics ; Supercooling ; Tin base alloys</subject><ispartof>Journal of electronic materials, 2018-09, Vol.47 (9), p.5588-5594</ispartof><rights>The Minerals, Metals &amp; Materials Society 2018</rights><rights>Journal of Electronic Materials is a copyright of Springer, (2018). 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subjects Bismuth
Characterization and Evaluation of Materials
Chemistry and Materials Science
Electronic packaging
Electronics and Microelectronics
Instrumentation
Materials Science
Microstructure
Nucleation
Optical and Electronic Materials
Optical microscopy
Rapid solidification
Scanning electron microscopy
Shear strength
Solid State Physics
Supercooling
Tin base alloys
title Refinement Mechanism of Bi Addition on the Microstructure of Rapidly Solidified Sn-3.5Ag Eutectic Solder for Microelectronic Packaging
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