Dual superlyophobic surfaces with superhydrophobicity and underwater superoleophobicity
Lotus leaf-inspired superhydrophobic, fish scale-inspired underwater superoleophobic, and the switchable superwetting surfaces have been broadly developed by entire modification with water-repellent, water-loving, and smart components, respectively. Inspired by beetles, here a strategy of fractional...
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Veröffentlicht in: | Journal of materials chemistry. A, Materials for energy and sustainability Materials for energy and sustainability, 2018, Vol.6 (25), p.11682-11687 |
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container_title | Journal of materials chemistry. A, Materials for energy and sustainability |
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creator | Tie, Lu Li, Jing Liu, Mingming Guo, Zhiguang Liang, Yongmin Liu, Weimin |
description | Lotus leaf-inspired superhydrophobic, fish scale-inspired underwater superoleophobic, and the switchable superwetting surfaces have been broadly developed by entire modification with water-repellent, water-loving, and smart components, respectively. Inspired by beetles, here a strategy of fractional modification is proposed to construct dual superlyophobic surfaces that have both superhydrophobic and underwater superoleophobic properties. Specifically, copper-based coatings on various substrates are fractionally modified by adjusting the concentration of perfluorinated mercaptan. The obtained dual superlyophobic surfaces display mutual advantages like using either superhydrophobic or underwater superoleophobic materials without any continuous external stimulus, for example on-demand oil–water separation. In theory, the distinctive dual superlyophobic state exists in a narrow range of surface chemistry, and thus needs elaborate surface modification. This discovery will facilitate the extension of the surfaces with completely opposite superwettability to enjoy the superiority in interfacial issues and applications. |
doi_str_mv | 10.1039/C8TA02933D |
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Inspired by beetles, here a strategy of fractional modification is proposed to construct dual superlyophobic surfaces that have both superhydrophobic and underwater superoleophobic properties. Specifically, copper-based coatings on various substrates are fractionally modified by adjusting the concentration of perfluorinated mercaptan. The obtained dual superlyophobic surfaces display mutual advantages like using either superhydrophobic or underwater superoleophobic materials without any continuous external stimulus, for example on-demand oil–water separation. In theory, the distinctive dual superlyophobic state exists in a narrow range of surface chemistry, and thus needs elaborate surface modification. This discovery will facilitate the extension of the surfaces with completely opposite superwettability to enjoy the superiority in interfacial issues and applications.</description><identifier>ISSN: 2050-7488</identifier><identifier>EISSN: 2050-7496</identifier><identifier>DOI: 10.1039/C8TA02933D</identifier><language>eng</language><publisher>Cambridge: Royal Society of Chemistry</publisher><subject>Beetles ; Hydrophobic surfaces ; Hydrophobicity ; Organic chemistry ; Substrates ; Surface chemistry ; Underwater ; Underwater construction</subject><ispartof>Journal of materials chemistry. 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This discovery will facilitate the extension of the surfaces with completely opposite superwettability to enjoy the superiority in interfacial issues and applications.</description><subject>Beetles</subject><subject>Hydrophobic surfaces</subject><subject>Hydrophobicity</subject><subject>Organic chemistry</subject><subject>Substrates</subject><subject>Surface chemistry</subject><subject>Underwater</subject><subject>Underwater construction</subject><issn>2050-7488</issn><issn>2050-7496</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2018</creationdate><recordtype>article</recordtype><recordid>eNpFkN9LwzAQx4MoOOZe_AsKvgnV_GqTPI5NpzDwZeJjSJqEdtSmJi2j_72RDnf3cHd8P9xxXwDuEXxCkIjnDT-sIRaEbK_AAsMC5oyK8vq_5_wWrGI8whQcwlKIBfjajqrN4tjb0E6-r71uqjQGpyobs1Mz1LNYTyac5WaYMtWZbOyMDSc12DAjvrUX4g7cONVGuzrXJfh8fTls3vL9x-59s97nFRblkFPBEOUlIYQpa7iylWJME00tEyVzEFGDFeYYakqwo1Ab7jgpEC80IzzlEjzMe_vgf0YbB3n0Y-jSSZm-FqhAjJJEPc5UFXyMwTrZh-ZbhUkiKP-8kxfvyC9CwWIH</recordid><startdate>2018</startdate><enddate>2018</enddate><creator>Tie, Lu</creator><creator>Li, Jing</creator><creator>Liu, Mingming</creator><creator>Guo, Zhiguang</creator><creator>Liang, Yongmin</creator><creator>Liu, Weimin</creator><general>Royal Society of Chemistry</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SP</scope><scope>7SR</scope><scope>7ST</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>C1K</scope><scope>JG9</scope><scope>L7M</scope><scope>SOI</scope><orcidid>https://orcid.org/0000-0001-5478-5622</orcidid><orcidid>https://orcid.org/0000-0002-4438-3344</orcidid><orcidid>https://orcid.org/0000-0001-8280-8211</orcidid><orcidid>https://orcid.org/0000-0002-4183-6440</orcidid></search><sort><creationdate>2018</creationdate><title>Dual superlyophobic surfaces with superhydrophobicity and underwater superoleophobicity</title><author>Tie, Lu ; Li, Jing ; Liu, Mingming ; Guo, Zhiguang ; Liang, Yongmin ; Liu, Weimin</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c296t-49714863337aed8aeca77b3b4e7967f014d2a2820b432f40bd8f835185b738383</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2018</creationdate><topic>Beetles</topic><topic>Hydrophobic surfaces</topic><topic>Hydrophobicity</topic><topic>Organic chemistry</topic><topic>Substrates</topic><topic>Surface chemistry</topic><topic>Underwater</topic><topic>Underwater construction</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Tie, Lu</creatorcontrib><creatorcontrib>Li, Jing</creatorcontrib><creatorcontrib>Liu, Mingming</creatorcontrib><creatorcontrib>Guo, Zhiguang</creatorcontrib><creatorcontrib>Liang, Yongmin</creatorcontrib><creatorcontrib>Liu, Weimin</creatorcontrib><collection>CrossRef</collection><collection>Electronics & Communications Abstracts</collection><collection>Engineered Materials Abstracts</collection><collection>Environment Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Environmental Sciences and Pollution Management</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>Environment Abstracts</collection><jtitle>Journal of materials chemistry. A, Materials for energy and sustainability</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Tie, Lu</au><au>Li, Jing</au><au>Liu, Mingming</au><au>Guo, Zhiguang</au><au>Liang, Yongmin</au><au>Liu, Weimin</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Dual superlyophobic surfaces with superhydrophobicity and underwater superoleophobicity</atitle><jtitle>Journal of materials chemistry. A, Materials for energy and sustainability</jtitle><date>2018</date><risdate>2018</risdate><volume>6</volume><issue>25</issue><spage>11682</spage><epage>11687</epage><pages>11682-11687</pages><issn>2050-7488</issn><eissn>2050-7496</eissn><abstract>Lotus leaf-inspired superhydrophobic, fish scale-inspired underwater superoleophobic, and the switchable superwetting surfaces have been broadly developed by entire modification with water-repellent, water-loving, and smart components, respectively. Inspired by beetles, here a strategy of fractional modification is proposed to construct dual superlyophobic surfaces that have both superhydrophobic and underwater superoleophobic properties. Specifically, copper-based coatings on various substrates are fractionally modified by adjusting the concentration of perfluorinated mercaptan. The obtained dual superlyophobic surfaces display mutual advantages like using either superhydrophobic or underwater superoleophobic materials without any continuous external stimulus, for example on-demand oil–water separation. In theory, the distinctive dual superlyophobic state exists in a narrow range of surface chemistry, and thus needs elaborate surface modification. This discovery will facilitate the extension of the surfaces with completely opposite superwettability to enjoy the superiority in interfacial issues and applications.</abstract><cop>Cambridge</cop><pub>Royal Society of Chemistry</pub><doi>10.1039/C8TA02933D</doi><tpages>6</tpages><orcidid>https://orcid.org/0000-0001-5478-5622</orcidid><orcidid>https://orcid.org/0000-0002-4438-3344</orcidid><orcidid>https://orcid.org/0000-0001-8280-8211</orcidid><orcidid>https://orcid.org/0000-0002-4183-6440</orcidid></addata></record> |
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source | Royal Society Of Chemistry Journals 2008- |
subjects | Beetles Hydrophobic surfaces Hydrophobicity Organic chemistry Substrates Surface chemistry Underwater Underwater construction |
title | Dual superlyophobic surfaces with superhydrophobicity and underwater superoleophobicity |
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