Synthesis and reactivity of [M(η3-allyl)(η2-amidinato)(CO)2(phosphonium ylide)] (M = Mo, W): Investigation of the ligand properties of phosphonium ylides

Phosphonium ylide complexes of Mo and W were prepared. The electron donating ability of phosphonium ylide and the robustness of the M-C(phosphonium ylide) bond were investigated. [Display omitted] •Phosphonium ylide complexes of Mo and W were prepared and characterized spectroscopically, as well as...

Ausführliche Beschreibung

Bibliographische Detailangaben

Veröffentlicht in:	Inorganica Chimica Acta 2018-02, Vol.471, p.310-315
Hauptverfasser:	Takaki, Daichi, Ogata, Kenichi, Kurihara, Youji, Ueda, Kazuyoshi, Hashimoto, Toru, Yamaguchi, Yoshitaka
Format:	Artikel
Sprache:	eng
Schlagworte:	Bond strength Bonding strength Coordination compounds DFT calculations Diffraction Electron donating ability Electrons Ligands Molecules Phosphonium ylide Salt Spectrum analysis Substitution reactions X-ray diffraction
Online-Zugang:	Volltext
Tags:	Tag hinzufügen Keine Tags, Fügen Sie den ersten Tag hinzu!