Acetic Acid Assistant Hydrogenation of Graphene Sheets with Ferromagnetism

Ferromagnetism of pure carbon-based materials has been widely researched for several years. In therocially and experimentally, semi-hydrogenation graphene sheets exhibit ferromagnitism, which is related to the degree of hydrogenation. Here we reported the controllable hydrogenation of graphene using...

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Veröffentlicht in:Chemical research in Chinese universities 2018-06, Vol.34 (3), p.344-349
Hauptverfasser: Sun, Qiushi, Wang, Xiaofeng, Li, Benxian, Wu, Yunpeng, Zhang, Ziqing, Zhang, Xinyang, Zhao, Xudong, Liu, Xiaoyang
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container_end_page 349
container_issue 3
container_start_page 344
container_title Chemical research in Chinese universities
container_volume 34
creator Sun, Qiushi
Wang, Xiaofeng
Li, Benxian
Wu, Yunpeng
Zhang, Ziqing
Zhang, Xinyang
Zhao, Xudong
Liu, Xiaoyang
description Ferromagnetism of pure carbon-based materials has been widely researched for several years. In therocially and experimentally, semi-hydrogenation graphene sheets exhibit ferromagnitism, which is related to the degree of hydrogenation. Here we reported the controllable hydrogenation of graphene using ball-milling method with acetic acid as hydrogenating agent. The hydrogenation graphene sheets were characterized by means of transmission electron microscopy(TEM), Raman spectroscopy and X-ray photoelectron spectroscopy, and magnetic measurement. The relusts of Raman spectroscopy demonstrate that the relative intensity of D band increases with the hydrogenation degree. The resluts of magnetic meansurement indicate the maximal magnetic moment of 0.274 A·m 2 /kg at 2 K for semi-hydrogenation graphene.
doi_str_mv 10.1007/s40242-018-8001-9
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subjects Acetic acid
Analytical Chemistry
Ball milling
Chemistry
Chemistry and Materials Science
Chemistry/Food Science
Ferromagnetism
Graphene
Hydrogenation
Inorganic Chemistry
Magnetic measurement
Magnetic moments
Magnetism
Organic Chemistry
Physical Chemistry
Raman spectroscopy
Sheets
Spectrum analysis
Transmission electron microscopy
title Acetic Acid Assistant Hydrogenation of Graphene Sheets with Ferromagnetism
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