Primary dendrite growth of Co3Sn2 intermetallic compound in rapidly solidified ternary Co35Cu35Sn30 alloy

The rapid solidification of ternary Co 35 Cu 35 Sn 30 alloy droplets with 20–785 µm diameter was realized by drop tube technique, aiming to investigate the dendrite growth mechanism of primary Co 3 Sn 2 intermetallic compound at high cooling rate. As alloy droplet diameter decreases, the surface seg...

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Veröffentlicht in:Applied physics. A, Materials science & processing Materials science & processing, 2018-07, Vol.124 (7), p.1-8, Article 472
Hauptverfasser: Liu, J. M., Zhai, W., Dai, F. P., Yan, P. X., Wei, B.
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container_issue 7
container_start_page 1
container_title Applied physics. A, Materials science & processing
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creator Liu, J. M.
Zhai, W.
Dai, F. P.
Yan, P. X.
Wei, B.
description The rapid solidification of ternary Co 35 Cu 35 Sn 30 alloy droplets with 20–785 µm diameter was realized by drop tube technique, aiming to investigate the dendrite growth mechanism of primary Co 3 Sn 2 intermetallic compound at high cooling rate. As alloy droplet diameter decreases, the surface segregation occurs prior to the solidification process with an increased probability, and the segregation shell becomes more apparent. The dendrite growth of primary Co 3 Sn 2 compound dominates the droplet solidification process, which evolves from equiaxed dendrite to spherical grain and is accompanied by remarkable grain refinement with the decrease of droplet diameter. Meanwhile, a peculiar zone near the droplet surface in which the primary Co 3 Sn 2 compound grows directionally is observed. This directional structure becomes more evident as droplet diameter decreases, which is attributed to the temperature gradient along the radial direction inside droplet. In each alloy droplet, owing to the increased cooling rate from the center to the surface, the grain size decreases accordingly.
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subjects Applied physics
Characterization and Evaluation of Materials
Condensed Matter Physics
Cooling rate
Dendritic structure
Grain refinement
Intermetallic compounds
Machines
Manufacturing
Materials science
Nanotechnology
Optical and Electronic Materials
Physics
Physics and Astronomy
Processes
Rapid solidification
Surfaces and Interfaces
Temperature gradients
Thin Films
title Primary dendrite growth of Co3Sn2 intermetallic compound in rapidly solidified ternary Co35Cu35Sn30 alloy
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