加熱した錫めっき銅板および黄銅板における錫めっき層の状態分析

Voltammetric technique using an ammonia buffer solution(0.5 mol/dm3 NH4OH+0.5 mol/dm3 NH4Cl)was applied to ascertain the corrosion products formed on tin plating on pure copper or brass and to clarify the products' formation processes. The main corrosion products formed on tin plating in air we...

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Veröffentlicht in:Hyōmen gijutsu 2017/06/01, Vol.68(6), pp.349-354
Hauptverfasser: 中山, 茂吉, 林, 美樹, 藤岡, 寛之, 関谷, 貴志, 能登谷, 武紀, 大堺, 利行
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container_end_page 354
container_issue 6
container_start_page 349
container_title Hyōmen gijutsu
container_volume 68
creator 中山, 茂吉
林, 美樹
藤岡, 寛之
関谷, 貴志
能登谷, 武紀
大堺, 利行
description Voltammetric technique using an ammonia buffer solution(0.5 mol/dm3 NH4OH+0.5 mol/dm3 NH4Cl)was applied to ascertain the corrosion products formed on tin plating on pure copper or brass and to clarify the products' formation processes. The main corrosion products formed on tin plating in air were found to be SnO and SnO2・nH2O. Results further showed that SnO was formed in air at 180 ℃, although SnO2・nH2O was formed at 80 ℃ with high relative humidity of 90%. Copper/tin alloy layers in tin plating on copper grew with increased heating time. Analytical results show that the SnO film thickness on tin plating was lower than that on tin sheets. Moreover, characteristic behavior was shown for tin plating on brass in which Zn diffused rapidly to the surface under high-humidity conditions. The diffused Zn was oxidized to ZnO. However, the SnO amounts on tin plating on brass were lower than on pure copper.
doi_str_mv 10.4139/sfj.68.349
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identifier ISSN: 0915-1869
ispartof 表面技術, 2017/06/01, Vol.68(6), pp.349-354
issn 0915-1869
1884-3409
language jpn
recordid cdi_proquest_journals_2050313389
source J-STAGE
subjects Ammonia
Ammonia Buffer Solution
Ammonium chloride
Boats
Brass
Brass plating
Buffer solutions
Copper
Copper plating
Corrosion products
Film thickness
Heat treatment
Humidity
Organic chemistry
Relative humidity
Tin base alloys
Tin dioxide
Tin Oxides
Tin Plating
Voltammetry
Zinc oxide
title 加熱した錫めっき銅板および黄銅板における錫めっき層の状態分析
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