Effective IR Laser Conversion of Carbon-13 Enriched Chlorodifluoromethane to Dibromodifluoromethane
Infrared laser conversion of chlorodifluoromethane (CF 2 HCl) enriched in 13 C to 31%, to dibromodifluoromethane (CF 2 Br 2 ) with the same enrichment has been studied. Optimum conditions have been found, and effective laser synthesis of macroscopic amounts (1 g) of CF 2 Br 2 has been carried out. I...
Gespeichert in:
| Veröffentlicht in: | High energy chemistry 2018-05, Vol.52 (3), p.236-239 |
|---|---|
| Hauptverfasser: | , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 239 |
|---|---|
| container_issue | 3 |
| container_start_page | 236 |
| container_title | High energy chemistry |
| container_volume | 52 |
| creator | Laptev, V. B. Pigul’skii, S. V. |
| description | Infrared laser conversion of chlorodifluoromethane (CF
2
HCl) enriched in
13
C to 31%, to dibromodifluoromethane (CF
2
Br
2
) with the same enrichment has been studied. Optimum conditions have been found, and effective laser synthesis of macroscopic amounts (1 g) of CF
2
Br
2
has been carried out. IR absorption spectra of synthesized CF
2
Br
2
with a
13
C concentration of 31% have been recorded. The
13
C isotope shifts of the ν
1
, ν
6
, and ν
8
modes have been measured. |
| doi_str_mv | 10.1134/S0018143918030086 |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_journals_2048689911</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>2048689911</sourcerecordid><originalsourceid>FETCH-LOGICAL-c316t-ac654183b01d981cd3ea98a16975887039706cf053113244f2f733163879df133</originalsourceid><addsrcrecordid>eNp1kE9LAzEQxYMoWKsfwFvA8-rMJptNjrJWLRQE_5yXNJvYLW1Sk23Bb29KBUHxNAzv_d4wj5BLhGtExm9eAFAiZwolMAApjsgIBciCIZfHZLSXi71-Ss5SWgJAlX0jYibOWTP0O0unz3Smk420CX5nY-qDp8HRRsd58AUyOvGxNwvb0WaxCjF0vVtt81zbYaG9pUOgd_0877-Vc3Li9CrZi-85Jm_3k9fmsZg9PUyb21lhGIqh0EZUHCWbA3ZKoumY1UpqFKqupKyBqRqEcVCx_HHJuStdzTLJZK06h4yNydUhdxPDx9amoV2GbfT5ZFsCl0IqlckxwYPLxJBStK7dxH6t42eL0O67bP90mZnywKTs9e82_iT_D30BWxZ0TA</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2048689911</pqid></control><display><type>article</type><title>Effective IR Laser Conversion of Carbon-13 Enriched Chlorodifluoromethane to Dibromodifluoromethane</title><source>Springer Nature - Complete Springer Journals</source><creator>Laptev, V. B. ; Pigul’skii, S. V.</creator><creatorcontrib>Laptev, V. B. ; Pigul’skii, S. V.</creatorcontrib><description>Infrared laser conversion of chlorodifluoromethane (CF
2
HCl) enriched in
13
C to 31%, to dibromodifluoromethane (CF
2
Br
2
) with the same enrichment has been studied. Optimum conditions have been found, and effective laser synthesis of macroscopic amounts (1 g) of CF
2
Br
2
has been carried out. IR absorption spectra of synthesized CF
2
Br
2
with a
13
C concentration of 31% have been recorded. The
13
C isotope shifts of the ν
1
, ν
6
, and ν
8
modes have been measured.</description><identifier>ISSN: 0018-1439</identifier><identifier>EISSN: 1608-3148</identifier><identifier>DOI: 10.1134/S0018143918030086</identifier><language>eng</language><publisher>Moscow: Pleiades Publishing</publisher><subject>Absorption spectra ; Carbon 13 ; Chemistry ; Chemistry and Materials Science ; Chlorodifluoromethane ; Conversion ; Enrichment ; Infrared lasers ; Lasers ; Photonics ; Physical Chemistry</subject><ispartof>High energy chemistry, 2018-05, Vol.52 (3), p.236-239</ispartof><rights>Pleiades Publishing, Ltd. 2018</rights><rights>Copyright Springer Science & Business Media 2018</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c316t-ac654183b01d981cd3ea98a16975887039706cf053113244f2f733163879df133</citedby><cites>FETCH-LOGICAL-c316t-ac654183b01d981cd3ea98a16975887039706cf053113244f2f733163879df133</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1134/S0018143918030086$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1134/S0018143918030086$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,777,781,27905,27906,41469,42538,51300</link.rule.ids></links><search><creatorcontrib>Laptev, V. B.</creatorcontrib><creatorcontrib>Pigul’skii, S. V.</creatorcontrib><title>Effective IR Laser Conversion of Carbon-13 Enriched Chlorodifluoromethane to Dibromodifluoromethane</title><title>High energy chemistry</title><addtitle>High Energy Chem</addtitle><description>Infrared laser conversion of chlorodifluoromethane (CF
2
HCl) enriched in
13
C to 31%, to dibromodifluoromethane (CF
2
Br
2
) with the same enrichment has been studied. Optimum conditions have been found, and effective laser synthesis of macroscopic amounts (1 g) of CF
2
Br
2
has been carried out. IR absorption spectra of synthesized CF
2
Br
2
with a
13
C concentration of 31% have been recorded. The
13
C isotope shifts of the ν
1
, ν
6
, and ν
8
modes have been measured.</description><subject>Absorption spectra</subject><subject>Carbon 13</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Chlorodifluoromethane</subject><subject>Conversion</subject><subject>Enrichment</subject><subject>Infrared lasers</subject><subject>Lasers</subject><subject>Photonics</subject><subject>Physical Chemistry</subject><issn>0018-1439</issn><issn>1608-3148</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2018</creationdate><recordtype>article</recordtype><recordid>eNp1kE9LAzEQxYMoWKsfwFvA8-rMJptNjrJWLRQE_5yXNJvYLW1Sk23Bb29KBUHxNAzv_d4wj5BLhGtExm9eAFAiZwolMAApjsgIBciCIZfHZLSXi71-Ss5SWgJAlX0jYibOWTP0O0unz3Smk420CX5nY-qDp8HRRsd58AUyOvGxNwvb0WaxCjF0vVtt81zbYaG9pUOgd_0877-Vc3Li9CrZi-85Jm_3k9fmsZg9PUyb21lhGIqh0EZUHCWbA3ZKoumY1UpqFKqupKyBqRqEcVCx_HHJuStdzTLJZK06h4yNydUhdxPDx9amoV2GbfT5ZFsCl0IqlckxwYPLxJBStK7dxH6t42eL0O67bP90mZnywKTs9e82_iT_D30BWxZ0TA</recordid><startdate>20180501</startdate><enddate>20180501</enddate><creator>Laptev, V. B.</creator><creator>Pigul’skii, S. V.</creator><general>Pleiades Publishing</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20180501</creationdate><title>Effective IR Laser Conversion of Carbon-13 Enriched Chlorodifluoromethane to Dibromodifluoromethane</title><author>Laptev, V. B. ; Pigul’skii, S. V.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c316t-ac654183b01d981cd3ea98a16975887039706cf053113244f2f733163879df133</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2018</creationdate><topic>Absorption spectra</topic><topic>Carbon 13</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Chlorodifluoromethane</topic><topic>Conversion</topic><topic>Enrichment</topic><topic>Infrared lasers</topic><topic>Lasers</topic><topic>Photonics</topic><topic>Physical Chemistry</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Laptev, V. B.</creatorcontrib><creatorcontrib>Pigul’skii, S. V.</creatorcontrib><collection>CrossRef</collection><jtitle>High energy chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Laptev, V. B.</au><au>Pigul’skii, S. V.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Effective IR Laser Conversion of Carbon-13 Enriched Chlorodifluoromethane to Dibromodifluoromethane</atitle><jtitle>High energy chemistry</jtitle><stitle>High Energy Chem</stitle><date>2018-05-01</date><risdate>2018</risdate><volume>52</volume><issue>3</issue><spage>236</spage><epage>239</epage><pages>236-239</pages><issn>0018-1439</issn><eissn>1608-3148</eissn><abstract>Infrared laser conversion of chlorodifluoromethane (CF
2
HCl) enriched in
13
C to 31%, to dibromodifluoromethane (CF
2
Br
2
) with the same enrichment has been studied. Optimum conditions have been found, and effective laser synthesis of macroscopic amounts (1 g) of CF
2
Br
2
has been carried out. IR absorption spectra of synthesized CF
2
Br
2
with a
13
C concentration of 31% have been recorded. The
13
C isotope shifts of the ν
1
, ν
6
, and ν
8
modes have been measured.</abstract><cop>Moscow</cop><pub>Pleiades Publishing</pub><doi>10.1134/S0018143918030086</doi><tpages>4</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0018-1439 |
| ispartof | High energy chemistry, 2018-05, Vol.52 (3), p.236-239 |
| issn | 0018-1439 1608-3148 |
| language | eng |
| recordid | cdi_proquest_journals_2048689911 |
| source | Springer Nature - Complete Springer Journals |
| subjects | Absorption spectra Carbon 13 Chemistry Chemistry and Materials Science Chlorodifluoromethane Conversion Enrichment Infrared lasers Lasers Photonics Physical Chemistry |
| title | Effective IR Laser Conversion of Carbon-13 Enriched Chlorodifluoromethane to Dibromodifluoromethane |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-20T20%3A17%3A17IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Effective%20IR%20Laser%20Conversion%20of%20Carbon-13%20Enriched%20Chlorodifluoromethane%20to%20Dibromodifluoromethane&rft.jtitle=High%20energy%20chemistry&rft.au=Laptev,%20V.%20B.&rft.date=2018-05-01&rft.volume=52&rft.issue=3&rft.spage=236&rft.epage=239&rft.pages=236-239&rft.issn=0018-1439&rft.eissn=1608-3148&rft_id=info:doi/10.1134/S0018143918030086&rft_dat=%3Cproquest_cross%3E2048689911%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=2048689911&rft_id=info:pmid/&rfr_iscdi=true |