Reactive co-sputter deposition of nanostructured cermet anodes for solid oxide fuel cells
The impact of a nanostructured NiO/yttria-stabilized zirconia (NiO/YSZ) and NiO/gadolinia-doped ceria (NiO/GDC) anode functional layers on low- and intermediate-temperature solid oxide fuel cell (SOFC) performance is investigated. NiO/YSZ and NiO/GDC thin films were reactively sputter-deposited by p...
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Veröffentlicht in: | Japanese Journal of Applied Physics 2018-01, Vol.57 (1S), p.1 |
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creator | Ionov, Igor V. Solovyev, Andrey A. Shipilova, Anna V. Lebedynskiy, Alexey M. Smolyanskiy, Egor A. Lauk, Alexander L. Semenov, Vyacheslav A. |
description | The impact of a nanostructured NiO/yttria-stabilized zirconia (NiO/YSZ) and NiO/gadolinia-doped ceria (NiO/GDC) anode functional layers on low- and intermediate-temperature solid oxide fuel cell (SOFC) performance is investigated. NiO/YSZ and NiO/GDC thin films were reactively sputter-deposited by pulsed direct current magnetron sputtering from the Ni, Zr-Y, and Ce-Gd targets onto commercial NiO/YSZ substrates. Anode-supported SOFCs based on magnetron sputtered YSZ and GDC electrolytes (∼4 µm) with and without the nanostructured anode layers are fabricated. A direct comparison of the YSZ- and GDC-based SOFCs in temperature range of 600-800 and 400-600 °C is made. The performance of cells with the nanostructured anode layers significantly increases as compared to that of the cell without it, especially at lower temperatures. Increase of cells performance was achieved by reduction of the total area-specific resistance by 26-30%. |
doi_str_mv | 10.7567/JJAP.57.01AF07 |
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NiO/YSZ and NiO/GDC thin films were reactively sputter-deposited by pulsed direct current magnetron sputtering from the Ni, Zr-Y, and Ce-Gd targets onto commercial NiO/YSZ substrates. Anode-supported SOFCs based on magnetron sputtered YSZ and GDC electrolytes (∼4 µm) with and without the nanostructured anode layers are fabricated. A direct comparison of the YSZ- and GDC-based SOFCs in temperature range of 600-800 and 400-600 °C is made. The performance of cells with the nanostructured anode layers significantly increases as compared to that of the cell without it, especially at lower temperatures. Increase of cells performance was achieved by reduction of the total area-specific resistance by 26-30%.</description><identifier>ISSN: 0021-4922</identifier><identifier>EISSN: 1347-4065</identifier><identifier>DOI: 10.7567/JJAP.57.01AF07</identifier><identifier>CODEN: JJAPB6</identifier><language>eng</language><publisher>Tokyo: The Japan Society of Applied Physics</publisher><subject>Anodes ; Cerium gadolinium oxides ; Cerium oxides ; Cermets ; Direct current ; Electrolytic cells ; Gadolinium ; Gadolinium oxides ; Magnetron sputtering ; Nanostructure ; Nickel oxides ; Solid oxide fuel cells ; Substrates ; Thin films ; Yttria-stabilized zirconia ; Yttrium oxide ; Zirconium dioxide</subject><ispartof>Japanese Journal of Applied Physics, 2018-01, Vol.57 (1S), p.1</ispartof><rights>2018 The Japan Society of Applied Physics</rights><rights>Copyright Japanese Journal of Applied Physics Jan 2018</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c442t-90ac9bfea8e98e273ef163eee59f830b0bd9303f446b526d4e6158b0c400daea3</citedby><cites>FETCH-LOGICAL-c442t-90ac9bfea8e98e273ef163eee59f830b0bd9303f446b526d4e6158b0c400daea3</cites><orcidid>0000-0001-6979-7191 ; 0000-0001-7775-9769</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://iopscience.iop.org/article/10.7567/JJAP.57.01AF07/pdf$$EPDF$$P50$$Giop$$H</linktopdf><link.rule.ids>314,780,784,27924,27925,53846,53893</link.rule.ids></links><search><creatorcontrib>Ionov, Igor V.</creatorcontrib><creatorcontrib>Solovyev, Andrey A.</creatorcontrib><creatorcontrib>Shipilova, Anna V.</creatorcontrib><creatorcontrib>Lebedynskiy, Alexey M.</creatorcontrib><creatorcontrib>Smolyanskiy, Egor A.</creatorcontrib><creatorcontrib>Lauk, Alexander L.</creatorcontrib><creatorcontrib>Semenov, Vyacheslav A.</creatorcontrib><title>Reactive co-sputter deposition of nanostructured cermet anodes for solid oxide fuel cells</title><title>Japanese Journal of Applied Physics</title><addtitle>Jpn. J. Appl. Phys</addtitle><description>The impact of a nanostructured NiO/yttria-stabilized zirconia (NiO/YSZ) and NiO/gadolinia-doped ceria (NiO/GDC) anode functional layers on low- and intermediate-temperature solid oxide fuel cell (SOFC) performance is investigated. NiO/YSZ and NiO/GDC thin films were reactively sputter-deposited by pulsed direct current magnetron sputtering from the Ni, Zr-Y, and Ce-Gd targets onto commercial NiO/YSZ substrates. Anode-supported SOFCs based on magnetron sputtered YSZ and GDC electrolytes (∼4 µm) with and without the nanostructured anode layers are fabricated. A direct comparison of the YSZ- and GDC-based SOFCs in temperature range of 600-800 and 400-600 °C is made. The performance of cells with the nanostructured anode layers significantly increases as compared to that of the cell without it, especially at lower temperatures. Increase of cells performance was achieved by reduction of the total area-specific resistance by 26-30%.</description><subject>Anodes</subject><subject>Cerium gadolinium oxides</subject><subject>Cerium oxides</subject><subject>Cermets</subject><subject>Direct current</subject><subject>Electrolytic cells</subject><subject>Gadolinium</subject><subject>Gadolinium oxides</subject><subject>Magnetron sputtering</subject><subject>Nanostructure</subject><subject>Nickel oxides</subject><subject>Solid oxide fuel cells</subject><subject>Substrates</subject><subject>Thin films</subject><subject>Yttria-stabilized zirconia</subject><subject>Yttrium oxide</subject><subject>Zirconium dioxide</subject><issn>0021-4922</issn><issn>1347-4065</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2018</creationdate><recordtype>article</recordtype><recordid>eNp1kE1LxDAQhoMouK5ePQc8KXRNmqQfx2Vx1UVQ_Dh4CmkygZZuU5NU9N_bpQte9DTM8LzvwIPQOSWLXGT59WazfFqIfEHock3yAzSjjOcJJ5k4RDNCUprwMk2P0UkIzbhmgtMZen8GpWP9CVi7JPRDjOCxgd6FOtauw87iTnUuRD_oOHgwWIPfQsTj0UDA1nkcXFsb7L5qA9gO0I5I24ZTdGRVG-BsP-fobX3zurpLHh5v71fLh0RznsakJEqXlQVVQFlAmjOwNGMAIEpbMFKRypSMMMt5Vok0MxwyKoqKaE6IUaDYHF1Mvb13HwOEKBs3-G58KVPCBROsKNhILSZKexeCByt7X2-V_5aUyJ0-udMnRS4nfWPgcgrUrv9tbBrV7yD6sudkb-zIXv3B_lP8A0xlf2o</recordid><startdate>20180101</startdate><enddate>20180101</enddate><creator>Ionov, Igor V.</creator><creator>Solovyev, Andrey A.</creator><creator>Shipilova, Anna V.</creator><creator>Lebedynskiy, Alexey M.</creator><creator>Smolyanskiy, Egor A.</creator><creator>Lauk, Alexander L.</creator><creator>Semenov, Vyacheslav A.</creator><general>The Japan Society of Applied Physics</general><general>Japanese Journal of Applied Physics</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7U5</scope><scope>8FD</scope><scope>H8D</scope><scope>L7M</scope><orcidid>https://orcid.org/0000-0001-6979-7191</orcidid><orcidid>https://orcid.org/0000-0001-7775-9769</orcidid></search><sort><creationdate>20180101</creationdate><title>Reactive co-sputter deposition of nanostructured cermet anodes for solid oxide fuel cells</title><author>Ionov, Igor V. ; Solovyev, Andrey A. ; Shipilova, Anna V. ; Lebedynskiy, Alexey M. ; Smolyanskiy, Egor A. ; Lauk, Alexander L. ; Semenov, Vyacheslav A.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c442t-90ac9bfea8e98e273ef163eee59f830b0bd9303f446b526d4e6158b0c400daea3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2018</creationdate><topic>Anodes</topic><topic>Cerium gadolinium oxides</topic><topic>Cerium oxides</topic><topic>Cermets</topic><topic>Direct current</topic><topic>Electrolytic cells</topic><topic>Gadolinium</topic><topic>Gadolinium oxides</topic><topic>Magnetron sputtering</topic><topic>Nanostructure</topic><topic>Nickel oxides</topic><topic>Solid oxide fuel cells</topic><topic>Substrates</topic><topic>Thin films</topic><topic>Yttria-stabilized zirconia</topic><topic>Yttrium oxide</topic><topic>Zirconium dioxide</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Ionov, Igor V.</creatorcontrib><creatorcontrib>Solovyev, Andrey A.</creatorcontrib><creatorcontrib>Shipilova, Anna V.</creatorcontrib><creatorcontrib>Lebedynskiy, Alexey M.</creatorcontrib><creatorcontrib>Smolyanskiy, Egor A.</creatorcontrib><creatorcontrib>Lauk, Alexander L.</creatorcontrib><creatorcontrib>Semenov, Vyacheslav A.</creatorcontrib><collection>CrossRef</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>Technology Research Database</collection><collection>Aerospace Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Japanese Journal of Applied Physics</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Ionov, Igor V.</au><au>Solovyev, Andrey A.</au><au>Shipilova, Anna V.</au><au>Lebedynskiy, Alexey M.</au><au>Smolyanskiy, Egor A.</au><au>Lauk, Alexander L.</au><au>Semenov, Vyacheslav A.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Reactive co-sputter deposition of nanostructured cermet anodes for solid oxide fuel cells</atitle><jtitle>Japanese Journal of Applied Physics</jtitle><addtitle>Jpn. J. Appl. Phys</addtitle><date>2018-01-01</date><risdate>2018</risdate><volume>57</volume><issue>1S</issue><spage>1</spage><pages>1-</pages><issn>0021-4922</issn><eissn>1347-4065</eissn><coden>JJAPB6</coden><abstract>The impact of a nanostructured NiO/yttria-stabilized zirconia (NiO/YSZ) and NiO/gadolinia-doped ceria (NiO/GDC) anode functional layers on low- and intermediate-temperature solid oxide fuel cell (SOFC) performance is investigated. NiO/YSZ and NiO/GDC thin films were reactively sputter-deposited by pulsed direct current magnetron sputtering from the Ni, Zr-Y, and Ce-Gd targets onto commercial NiO/YSZ substrates. Anode-supported SOFCs based on magnetron sputtered YSZ and GDC electrolytes (∼4 µm) with and without the nanostructured anode layers are fabricated. A direct comparison of the YSZ- and GDC-based SOFCs in temperature range of 600-800 and 400-600 °C is made. The performance of cells with the nanostructured anode layers significantly increases as compared to that of the cell without it, especially at lower temperatures. Increase of cells performance was achieved by reduction of the total area-specific resistance by 26-30%.</abstract><cop>Tokyo</cop><pub>The Japan Society of Applied Physics</pub><doi>10.7567/JJAP.57.01AF07</doi><tpages>5</tpages><orcidid>https://orcid.org/0000-0001-6979-7191</orcidid><orcidid>https://orcid.org/0000-0001-7775-9769</orcidid><oa>free_for_read</oa></addata></record> |
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subjects | Anodes Cerium gadolinium oxides Cerium oxides Cermets Direct current Electrolytic cells Gadolinium Gadolinium oxides Magnetron sputtering Nanostructure Nickel oxides Solid oxide fuel cells Substrates Thin films Yttria-stabilized zirconia Yttrium oxide Zirconium dioxide |
title | Reactive co-sputter deposition of nanostructured cermet anodes for solid oxide fuel cells |
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