Pb2BO3I: A Borate Iodide with the Largest Second‐Harmonic Generation (SHG) Response in the KBe2BO3F2 (KBBF) Family of Nonlinear Optical (NLO) Materials
Borate halides are an ideal materials class from which to design high‐performance nonlinear optical (NLO) materials. Currently, borate fluorides, chlorides, and bromides are extensively investigated while borate iodide materials discovery remains rare because of the perceived synthetic challenges. W...
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| Veröffentlicht in: | Angewandte Chemie International Edition 2018-05, Vol.57 (21), p.6100-6103 |
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| creator | Yu, Hongwei Koocher, Nathan Z. Rondinelli, James M. Halasyamani, P. Shiv |
| description | Borate halides are an ideal materials class from which to design high‐performance nonlinear optical (NLO) materials. Currently, borate fluorides, chlorides, and bromides are extensively investigated while borate iodide materials discovery remains rare because of the perceived synthetic challenges. We report a new borate iodide, Pb2BO3I, synthesized by a straightforward hydrothermal method. The Pb2BO3I chemical formula conceals that the compound exhibits a structure similar to the well‐established KBe2BO3F2 (KBBF), which we show supports the highest second‐harmonic generation (SHG) at 1064 nm in the KBBF family, 10 × KH2PO4 (KDP), arising from the inclusion of Pb2+ and I− and the crystal chemistry. Our work shows that KBBF‐related compounds can be synthesized incorporating iodide and exhibit superior NLO responses.
I've got my I on you: A new borate iodide, Pb2BO3I, is prepared for nonlinear optics applications by a straightforward hydrothermal method. It has a similar structure to KBe2BO3F2 (KBBF) and the highest second‐harmonic generation (SHG) in the KBBF family. Calculations show this SHG response arises from the inclusion of Pb2+ and I− ions. |
| doi_str_mv | 10.1002/anie.201802079 |
| format | Article |
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I've got my I on you: A new borate iodide, Pb2BO3I, is prepared for nonlinear optics applications by a straightforward hydrothermal method. It has a similar structure to KBe2BO3F2 (KBBF) and the highest second‐harmonic generation (SHG) in the KBBF family. Calculations show this SHG response arises from the inclusion of Pb2+ and I− ions.</description><edition>International ed. in English</edition><identifier>ISSN: 1433-7851</identifier><identifier>EISSN: 1521-3773</identifier><identifier>DOI: 10.1002/anie.201802079</identifier><language>eng</language><publisher>Weinheim: Wiley Subscription Services, Inc</publisher><subject>borates ; Bromides ; Chemical synthesis ; Fluorides ; Halides ; Harmonic generations ; Hydrothermal crystal growth ; Iodides ; Lead ; nonlinear optical materials ; Nonlinear optics ; Pb2BO3I ; Potassium phosphate ; Potassium phosphates ; second-harmonic generation</subject><ispartof>Angewandte Chemie International Edition, 2018-05, Vol.57 (21), p.6100-6103</ispartof><rights>2018 Wiley‐VCH Verlag GmbH & Co. KGaA, Weinheim</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><orcidid>0000-0003-1787-1040 ; 0000-0002-5607-0628 ; 0000-0003-0508-2175</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fanie.201802079$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fanie.201802079$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,780,784,1417,27924,27925,45574,45575</link.rule.ids></links><search><creatorcontrib>Yu, Hongwei</creatorcontrib><creatorcontrib>Koocher, Nathan Z.</creatorcontrib><creatorcontrib>Rondinelli, James M.</creatorcontrib><creatorcontrib>Halasyamani, P. Shiv</creatorcontrib><title>Pb2BO3I: A Borate Iodide with the Largest Second‐Harmonic Generation (SHG) Response in the KBe2BO3F2 (KBBF) Family of Nonlinear Optical (NLO) Materials</title><title>Angewandte Chemie International Edition</title><description>Borate halides are an ideal materials class from which to design high‐performance nonlinear optical (NLO) materials. Currently, borate fluorides, chlorides, and bromides are extensively investigated while borate iodide materials discovery remains rare because of the perceived synthetic challenges. We report a new borate iodide, Pb2BO3I, synthesized by a straightforward hydrothermal method. The Pb2BO3I chemical formula conceals that the compound exhibits a structure similar to the well‐established KBe2BO3F2 (KBBF), which we show supports the highest second‐harmonic generation (SHG) at 1064 nm in the KBBF family, 10 × KH2PO4 (KDP), arising from the inclusion of Pb2+ and I− and the crystal chemistry. Our work shows that KBBF‐related compounds can be synthesized incorporating iodide and exhibit superior NLO responses.
I've got my I on you: A new borate iodide, Pb2BO3I, is prepared for nonlinear optics applications by a straightforward hydrothermal method. It has a similar structure to KBe2BO3F2 (KBBF) and the highest second‐harmonic generation (SHG) in the KBBF family. Calculations show this SHG response arises from the inclusion of Pb2+ and I− ions.</description><subject>borates</subject><subject>Bromides</subject><subject>Chemical synthesis</subject><subject>Fluorides</subject><subject>Halides</subject><subject>Harmonic generations</subject><subject>Hydrothermal crystal growth</subject><subject>Iodides</subject><subject>Lead</subject><subject>nonlinear optical materials</subject><subject>Nonlinear optics</subject><subject>Pb2BO3I</subject><subject>Potassium phosphate</subject><subject>Potassium phosphates</subject><subject>second-harmonic generation</subject><issn>1433-7851</issn><issn>1521-3773</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2018</creationdate><recordtype>article</recordtype><recordid>eNo9UMtO40AQtNCuBMty5dwSl-Rg6Jmx4zG3GJGHCAnicbbGnjYMcmayYyOU234CV35vv2QngDhVtVRV3V1RdMzwlCHyM2UNnXJkEjlm-V50wFLOYpFl4kfgiRBxJlO2H_3quueglxJHB9H7TcWLlZifwxgK51VPMHfaaIJX0z9B_0SwUP6Ruh7uqHZW__v7NlN-7aypYUqWgsU4C4O72XQIt9RtnO0IjP2wXhW0S59wGFwVxWQIE7U27RZcA0tnW2NJeVhtelOrFgbLxWoI1-EEb1Tb_Y5-NgHo6AsPo4fJ5f3FLF6spvOL8SJ-FAzzOOUN1jJNE50E0kgSOkklVSNBqLRCUXFUqFVasworluVqJNMaGy1yzSpO4jA6-czdePfnJTxaPrsXb8PKkmPCMReZTIIq_1S9mpa25cabtfLbkmG5677cdV9-d1-Ol_PL70n8B0bueMw</recordid><startdate>20180522</startdate><enddate>20180522</enddate><creator>Yu, Hongwei</creator><creator>Koocher, Nathan Z.</creator><creator>Rondinelli, James M.</creator><creator>Halasyamani, P. Shiv</creator><general>Wiley Subscription Services, Inc</general><scope>7TM</scope><scope>K9.</scope><orcidid>https://orcid.org/0000-0003-1787-1040</orcidid><orcidid>https://orcid.org/0000-0002-5607-0628</orcidid><orcidid>https://orcid.org/0000-0003-0508-2175</orcidid></search><sort><creationdate>20180522</creationdate><title>Pb2BO3I: A Borate Iodide with the Largest Second‐Harmonic Generation (SHG) Response in the KBe2BO3F2 (KBBF) Family of Nonlinear Optical (NLO) Materials</title><author>Yu, Hongwei ; Koocher, Nathan Z. ; Rondinelli, James M. ; Halasyamani, P. Shiv</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-g3109-52f0c8554d4f0cf8e3d458eb63e0ada03b20a0da5c1b0b179a685c0fd39d1b2e3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2018</creationdate><topic>borates</topic><topic>Bromides</topic><topic>Chemical synthesis</topic><topic>Fluorides</topic><topic>Halides</topic><topic>Harmonic generations</topic><topic>Hydrothermal crystal growth</topic><topic>Iodides</topic><topic>Lead</topic><topic>nonlinear optical materials</topic><topic>Nonlinear optics</topic><topic>Pb2BO3I</topic><topic>Potassium phosphate</topic><topic>Potassium phosphates</topic><topic>second-harmonic generation</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Yu, Hongwei</creatorcontrib><creatorcontrib>Koocher, Nathan Z.</creatorcontrib><creatorcontrib>Rondinelli, James M.</creatorcontrib><creatorcontrib>Halasyamani, P. Shiv</creatorcontrib><collection>Nucleic Acids Abstracts</collection><collection>ProQuest Health & Medical Complete (Alumni)</collection><jtitle>Angewandte Chemie International Edition</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Yu, Hongwei</au><au>Koocher, Nathan Z.</au><au>Rondinelli, James M.</au><au>Halasyamani, P. Shiv</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Pb2BO3I: A Borate Iodide with the Largest Second‐Harmonic Generation (SHG) Response in the KBe2BO3F2 (KBBF) Family of Nonlinear Optical (NLO) Materials</atitle><jtitle>Angewandte Chemie International Edition</jtitle><date>2018-05-22</date><risdate>2018</risdate><volume>57</volume><issue>21</issue><spage>6100</spage><epage>6103</epage><pages>6100-6103</pages><issn>1433-7851</issn><eissn>1521-3773</eissn><abstract>Borate halides are an ideal materials class from which to design high‐performance nonlinear optical (NLO) materials. Currently, borate fluorides, chlorides, and bromides are extensively investigated while borate iodide materials discovery remains rare because of the perceived synthetic challenges. We report a new borate iodide, Pb2BO3I, synthesized by a straightforward hydrothermal method. The Pb2BO3I chemical formula conceals that the compound exhibits a structure similar to the well‐established KBe2BO3F2 (KBBF), which we show supports the highest second‐harmonic generation (SHG) at 1064 nm in the KBBF family, 10 × KH2PO4 (KDP), arising from the inclusion of Pb2+ and I− and the crystal chemistry. Our work shows that KBBF‐related compounds can be synthesized incorporating iodide and exhibit superior NLO responses.
I've got my I on you: A new borate iodide, Pb2BO3I, is prepared for nonlinear optics applications by a straightforward hydrothermal method. It has a similar structure to KBe2BO3F2 (KBBF) and the highest second‐harmonic generation (SHG) in the KBBF family. Calculations show this SHG response arises from the inclusion of Pb2+ and I− ions.</abstract><cop>Weinheim</cop><pub>Wiley Subscription Services, Inc</pub><doi>10.1002/anie.201802079</doi><tpages>4</tpages><edition>International ed. in English</edition><orcidid>https://orcid.org/0000-0003-1787-1040</orcidid><orcidid>https://orcid.org/0000-0002-5607-0628</orcidid><orcidid>https://orcid.org/0000-0003-0508-2175</orcidid><oa>free_for_read</oa></addata></record> |
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| subjects | borates Bromides Chemical synthesis Fluorides Halides Harmonic generations Hydrothermal crystal growth Iodides Lead nonlinear optical materials Nonlinear optics Pb2BO3I Potassium phosphate Potassium phosphates second-harmonic generation |
| title | Pb2BO3I: A Borate Iodide with the Largest Second‐Harmonic Generation (SHG) Response in the KBe2BO3F2 (KBBF) Family of Nonlinear Optical (NLO) Materials |
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