Rapid separation and large-scale synthesis of ß-FeOOH nanospindles for direct coal liquefaction

A rapid separation method for the large-scale synthesis (422 g) of β-FeOOH nanospindles has been achieved via a facile hydrolysis route, including a simple surface-modified process with sodium oleate to improve the dispersivity of β-FeOOH in the direct coal liquefaction (DCL) reaction. The as-prepar...

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Veröffentlicht in:Fuel processing technology 2017-10, Vol.165, p.80
Hauptverfasser: Sheng, Jianping, Baikenov, Murzabek Ispolovich, Liang, Xiaoyu, Rao, Xuehui, Ma, Fengyun, Su, Xintai, Zhang, Yi
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container_issue
container_start_page 80
container_title Fuel processing technology
container_volume 165
creator Sheng, Jianping
Baikenov, Murzabek Ispolovich
Liang, Xiaoyu
Rao, Xuehui
Ma, Fengyun
Su, Xintai
Zhang, Yi
description A rapid separation method for the large-scale synthesis (422 g) of β-FeOOH nanospindles has been achieved via a facile hydrolysis route, including a simple surface-modified process with sodium oleate to improve the dispersivity of β-FeOOH in the direct coal liquefaction (DCL) reaction. The as-prepared (also oleic acid-coated) β-FeOOH exhibited superior catalytic activity toward DCL reaction. The percent of conversion, oil yield, and liquefaction degree with the oleic acid-coated β-FeOOH are 92.6,73.8, and 80.8%, respectively. This facile separation approach allows large-scale production of nanocatalyst without any centrifugation or filtration process, which will be applicable for future industrial DCL processes.
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The as-prepared (also oleic acid-coated) β-FeOOH exhibited superior catalytic activity toward DCL reaction. The percent of conversion, oil yield, and liquefaction degree with the oleic acid-coated β-FeOOH are 92.6,73.8, and 80.8%, respectively. This facile separation approach allows large-scale production of nanocatalyst without any centrifugation or filtration process, which will be applicable for future industrial DCL processes.</description><identifier>ISSN: 0378-3820</identifier><identifier>EISSN: 1873-7188</identifier><language>eng</language><publisher>Amsterdam: Elsevier Science Ltd</publisher><subject>Catalytic activity ; Catalytic converters ; Centrifuges ; Coal ; Coal liquefaction ; Conversion coating ; Filters ; Liquefaction ; Morphology ; Oleic acid ; Particle size ; Separation ; Synthesis</subject><ispartof>Fuel processing technology, 2017-10, Vol.165, p.80</ispartof><rights>Copyright Elsevier Science Ltd. 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subjects Catalytic activity
Catalytic converters
Centrifuges
Coal
Coal liquefaction
Conversion coating
Filters
Liquefaction
Morphology
Oleic acid
Particle size
Separation
Synthesis
title Rapid separation and large-scale synthesis of ß-FeOOH nanospindles for direct coal liquefaction
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