Smart modification of inorganic fibers and flammability mechanical and radiation shielding properties of their rubber composites
Facile and smart method for the modification of inorganic fibers has been developed. The polyaniline was synthesized on basalt fiber surface presenting an organic polymer shell to the inorganic fibers. The modified basalt fibers were dispersed in rubber-producing well-dispersed rubber composites. Va...
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| Veröffentlicht in: | Journal of thermal analysis and calorimetry 2018-06, Vol.132 (3), p.1567-1578 |
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| container_issue | 3 |
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| container_title | Journal of thermal analysis and calorimetry |
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| creator | Attia, Nour F. Hegazi, Elham M. Abdelmageed, A. A. |
| description | Facile and smart method for the modification of inorganic fibers has been developed. The polyaniline was synthesized on basalt fiber surface presenting an organic polymer shell to the inorganic fibers. The modified basalt fibers were dispersed in rubber-producing well-dispersed rubber composites. Various mass loadings of modified basalt fibers were dispersed and optimized. The effect of radiation on the properties of developed rubber composites was investigated by exposure to different gamma radiation doses. The flammability, thermal and mechanical properties were studied. The flammability of developed composites was improved achieving 62 and 16% reduction in the peak heat release rate compared to blank rubber and unmodified basalt fiber-based rubber composite, respectively. This is in addition to significant reduction in emission of CO and CO
2
gases by 65 and 58%, respectively. Also, the tensile strength property was enhanced by 38 and 53% compared to blank and unmodified basalt composite, respectively. The role of polyaniline layer on inorganic fiber surface and their effect on the properties of the produced composites was studied. The organic polymer shell achieved good compatibility and interfacial adhesion of basalt fibers with rubber matrix and radiation protection effect for the developed composites. |
| doi_str_mv | 10.1007/s10973-018-7141-y |
| format | Article |
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2
gases by 65 and 58%, respectively. Also, the tensile strength property was enhanced by 38 and 53% compared to blank and unmodified basalt composite, respectively. The role of polyaniline layer on inorganic fiber surface and their effect on the properties of the produced composites was studied. The organic polymer shell achieved good compatibility and interfacial adhesion of basalt fibers with rubber matrix and radiation protection effect for the developed composites.</description><identifier>ISSN: 1388-6150</identifier><identifier>EISSN: 1588-2926</identifier><identifier>DOI: 10.1007/s10973-018-7141-y</identifier><language>eng</language><publisher>Dordrecht: Springer Netherlands</publisher><subject>Analytical Chemistry ; Basalt ; Carbon dioxide ; Chemical synthesis ; Chemistry ; Chemistry and Materials Science ; Dispersion ; Emissions control ; Fibers ; Flammability ; Gamma rays ; Heat release rate ; Inorganic Chemistry ; Measurement Science and Instrumentation ; Mechanical properties ; Nuclear energy ; Physical Chemistry ; Polyanilines ; Polymer matrix composites ; Polymer Sciences ; Polymers ; Radiation (Physics) ; Radiation protection ; Radiation shielding ; Rubber ; Thermodynamic properties</subject><ispartof>Journal of thermal analysis and calorimetry, 2018-06, Vol.132 (3), p.1567-1578</ispartof><rights>Akadémiai Kiadó, Budapest, Hungary 2018</rights><rights>COPYRIGHT 2018 Springer</rights><rights>Copyright Springer Science & Business Media 2018</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c389t-c633ff0b6c965bc8b2a9675c3feeeccbf3e2aa307e83e42a5bf33883111f25803</citedby><cites>FETCH-LOGICAL-c389t-c633ff0b6c965bc8b2a9675c3feeeccbf3e2aa307e83e42a5bf33883111f25803</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s10973-018-7141-y$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s10973-018-7141-y$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,780,784,27924,27925,41488,42557,51319</link.rule.ids></links><search><creatorcontrib>Attia, Nour F.</creatorcontrib><creatorcontrib>Hegazi, Elham M.</creatorcontrib><creatorcontrib>Abdelmageed, A. A.</creatorcontrib><title>Smart modification of inorganic fibers and flammability mechanical and radiation shielding properties of their rubber composites</title><title>Journal of thermal analysis and calorimetry</title><addtitle>J Therm Anal Calorim</addtitle><description>Facile and smart method for the modification of inorganic fibers has been developed. The polyaniline was synthesized on basalt fiber surface presenting an organic polymer shell to the inorganic fibers. The modified basalt fibers were dispersed in rubber-producing well-dispersed rubber composites. Various mass loadings of modified basalt fibers were dispersed and optimized. The effect of radiation on the properties of developed rubber composites was investigated by exposure to different gamma radiation doses. The flammability, thermal and mechanical properties were studied. The flammability of developed composites was improved achieving 62 and 16% reduction in the peak heat release rate compared to blank rubber and unmodified basalt fiber-based rubber composite, respectively. This is in addition to significant reduction in emission of CO and CO
2
gases by 65 and 58%, respectively. Also, the tensile strength property was enhanced by 38 and 53% compared to blank and unmodified basalt composite, respectively. The role of polyaniline layer on inorganic fiber surface and their effect on the properties of the produced composites was studied. The organic polymer shell achieved good compatibility and interfacial adhesion of basalt fibers with rubber matrix and radiation protection effect for the developed composites.</description><subject>Analytical Chemistry</subject><subject>Basalt</subject><subject>Carbon dioxide</subject><subject>Chemical synthesis</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Dispersion</subject><subject>Emissions control</subject><subject>Fibers</subject><subject>Flammability</subject><subject>Gamma rays</subject><subject>Heat release rate</subject><subject>Inorganic Chemistry</subject><subject>Measurement Science and Instrumentation</subject><subject>Mechanical properties</subject><subject>Nuclear energy</subject><subject>Physical Chemistry</subject><subject>Polyanilines</subject><subject>Polymer matrix composites</subject><subject>Polymer Sciences</subject><subject>Polymers</subject><subject>Radiation (Physics)</subject><subject>Radiation protection</subject><subject>Radiation shielding</subject><subject>Rubber</subject><subject>Thermodynamic properties</subject><issn>1388-6150</issn><issn>1588-2926</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2018</creationdate><recordtype>article</recordtype><recordid>eNp1kU9rFTEUxQdRsFY_gLuAKxfT5k8nM1mWorVQKFhdh0zmZt4tM8kzyQPfzo_ufY4gXUgWudz8zslNTtO8F_xCcN5fFsFNr1ouhrYXV6I9vmjORDcMrTRSv6RaUa1Fx183b0p54pwbw8VZ8-txdbmyNU0Y0LuKKbIUGMaUZxfRs4Aj5MJcnFhY3Lq6EResR7aC350At_w5y27CTV12CMuEcWb7nPaQK0I5WdYdYGb5MJIf82ndp4IVytvmVXBLgXd_9_Pm--dP326-tPcPt3c31_etV4OprddKhcBH7Y3uRj-M0hndd14FAPB-DAqkc4r3MCi4kq6jDj1ZCSGC7AauzpsPmy9N9eMApdqndMiRrrSSq6HXvRaGqIuNmt0CFmNINTtPa4IVfYoQkPrXHc3Ee20kCT4-ExBT4Wed3aEUe_f49TkrNtbnVEqGYPcZ6fuPVnB7StFuKVpK0Z5StEfSyE1TiI0z5H9j_1_0G45domQ</recordid><startdate>20180601</startdate><enddate>20180601</enddate><creator>Attia, Nour F.</creator><creator>Hegazi, Elham M.</creator><creator>Abdelmageed, A. A.</creator><general>Springer Netherlands</general><general>Springer</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>ISR</scope></search><sort><creationdate>20180601</creationdate><title>Smart modification of inorganic fibers and flammability mechanical and radiation shielding properties of their rubber composites</title><author>Attia, Nour F. ; Hegazi, Elham M. ; Abdelmageed, A. A.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c389t-c633ff0b6c965bc8b2a9675c3feeeccbf3e2aa307e83e42a5bf33883111f25803</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2018</creationdate><topic>Analytical Chemistry</topic><topic>Basalt</topic><topic>Carbon dioxide</topic><topic>Chemical synthesis</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Dispersion</topic><topic>Emissions control</topic><topic>Fibers</topic><topic>Flammability</topic><topic>Gamma rays</topic><topic>Heat release rate</topic><topic>Inorganic Chemistry</topic><topic>Measurement Science and Instrumentation</topic><topic>Mechanical properties</topic><topic>Nuclear energy</topic><topic>Physical Chemistry</topic><topic>Polyanilines</topic><topic>Polymer matrix composites</topic><topic>Polymer Sciences</topic><topic>Polymers</topic><topic>Radiation (Physics)</topic><topic>Radiation protection</topic><topic>Radiation shielding</topic><topic>Rubber</topic><topic>Thermodynamic properties</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Attia, Nour F.</creatorcontrib><creatorcontrib>Hegazi, Elham M.</creatorcontrib><creatorcontrib>Abdelmageed, A. A.</creatorcontrib><collection>CrossRef</collection><collection>Gale In Context: Science</collection><jtitle>Journal of thermal analysis and calorimetry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Attia, Nour F.</au><au>Hegazi, Elham M.</au><au>Abdelmageed, A. A.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Smart modification of inorganic fibers and flammability mechanical and radiation shielding properties of their rubber composites</atitle><jtitle>Journal of thermal analysis and calorimetry</jtitle><stitle>J Therm Anal Calorim</stitle><date>2018-06-01</date><risdate>2018</risdate><volume>132</volume><issue>3</issue><spage>1567</spage><epage>1578</epage><pages>1567-1578</pages><issn>1388-6150</issn><eissn>1588-2926</eissn><abstract>Facile and smart method for the modification of inorganic fibers has been developed. The polyaniline was synthesized on basalt fiber surface presenting an organic polymer shell to the inorganic fibers. The modified basalt fibers were dispersed in rubber-producing well-dispersed rubber composites. Various mass loadings of modified basalt fibers were dispersed and optimized. The effect of radiation on the properties of developed rubber composites was investigated by exposure to different gamma radiation doses. The flammability, thermal and mechanical properties were studied. The flammability of developed composites was improved achieving 62 and 16% reduction in the peak heat release rate compared to blank rubber and unmodified basalt fiber-based rubber composite, respectively. This is in addition to significant reduction in emission of CO and CO
2
gases by 65 and 58%, respectively. Also, the tensile strength property was enhanced by 38 and 53% compared to blank and unmodified basalt composite, respectively. The role of polyaniline layer on inorganic fiber surface and their effect on the properties of the produced composites was studied. The organic polymer shell achieved good compatibility and interfacial adhesion of basalt fibers with rubber matrix and radiation protection effect for the developed composites.</abstract><cop>Dordrecht</cop><pub>Springer Netherlands</pub><doi>10.1007/s10973-018-7141-y</doi><tpages>12</tpages></addata></record> |
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| subjects | Analytical Chemistry Basalt Carbon dioxide Chemical synthesis Chemistry Chemistry and Materials Science Dispersion Emissions control Fibers Flammability Gamma rays Heat release rate Inorganic Chemistry Measurement Science and Instrumentation Mechanical properties Nuclear energy Physical Chemistry Polyanilines Polymer matrix composites Polymer Sciences Polymers Radiation (Physics) Radiation protection Radiation shielding Rubber Thermodynamic properties |
| title | Smart modification of inorganic fibers and flammability mechanical and radiation shielding properties of their rubber composites |
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