A novel anode modified by 1,5‐dihydroxyanthraquinone/multiwalled carbon nanotubes composite in marine sediment microbial fuel cell and its electrochemical performance

Summary A novel anode modified by 1,5‐dihydroxyanthraquinone/multiwalled carbon nanotubes (DAQ/MWCNTs) composite was fabricated in order to improve its electrochemical performance in marine sediment microbial fuel cell (MSMFC). The number of microbes on the DAQ/MWCNTs modified anode is 18.02 times o...

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Veröffentlicht in:International journal of energy research 2018-06, Vol.42 (7), p.2574-2582
Hauptverfasser: Zhang, Haoshuang, Fu, Yubin, Zhou, Changyang, Liu, Shuang, Zhao, Minggang, Chen, Tonglai, Zai, Xuerong
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container_end_page 2582
container_issue 7
container_start_page 2574
container_title International journal of energy research
container_volume 42
creator Zhang, Haoshuang
Fu, Yubin
Zhou, Changyang
Liu, Shuang
Zhao, Minggang
Chen, Tonglai
Zai, Xuerong
description Summary A novel anode modified by 1,5‐dihydroxyanthraquinone/multiwalled carbon nanotubes (DAQ/MWCNTs) composite was fabricated in order to improve its electrochemical performance in marine sediment microbial fuel cell (MSMFC). The number of microbes on the DAQ/MWCNTs modified anode is 18.02 times of blank anode, and it has the best electrochemical performance compared with other anodes. Its exchange current density and biofilm capacitance are 1472.15 times and 18.66 times higher than that of blank anode, respectively. The maximum power density of composite modified MSMFC (890.12 mW·m−2) is 3.01‐fold of blank cell (296.11 mW·m−2). The mechanism analysis of DAQ/MWCNTs shows that DAQ, as an electron‐transfer mediator, can accelerate electron transfer to benefit the electrochemical performance of anode. This provides a new anode modification method for the development of high power MSMFC as long‐term power source to drive monitoring instruments.
doi_str_mv 10.1002/er.4034
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The number of microbes on the DAQ/MWCNTs modified anode is 18.02 times of blank anode, and it has the best electrochemical performance compared with other anodes. Its exchange current density and biofilm capacitance are 1472.15 times and 18.66 times higher than that of blank anode, respectively. The maximum power density of composite modified MSMFC (890.12 mW·m−2) is 3.01‐fold of blank cell (296.11 mW·m−2). The mechanism analysis of DAQ/MWCNTs shows that DAQ, as an electron‐transfer mediator, can accelerate electron transfer to benefit the electrochemical performance of anode. 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The number of microbes on the DAQ/MWCNTs modified anode is 18.02 times of blank anode, and it has the best electrochemical performance compared with other anodes. Its exchange current density and biofilm capacitance are 1472.15 times and 18.66 times higher than that of blank anode, respectively. The maximum power density of composite modified MSMFC (890.12 mW·m−2) is 3.01‐fold of blank cell (296.11 mW·m−2). The mechanism analysis of DAQ/MWCNTs shows that DAQ, as an electron‐transfer mediator, can accelerate electron transfer to benefit the electrochemical performance of anode. This provides a new anode modification method for the development of high power MSMFC as long‐term power source to drive monitoring instruments.</abstract><cop>Bognor Regis</cop><pub>Hindawi Limited</pub><doi>10.1002/er.4034</doi><tpages>9</tpages><orcidid>https://orcid.org/0000-0002-1523-3195</orcidid><orcidid>https://orcid.org/0000-0003-2899-7829</orcidid><oa>free_for_read</oa></addata></record>
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subjects 1,5‐Dihydroxyanthraquinone
Anodes
Biochemical fuel cells
Biofilms
Capacitance
composite modified anode
Current density
Electrochemical analysis
electrochemical performance
Electrochemistry
Electron transfer
Electrons
electron‐transfer mediator
Fuel cells
Fuel technology
Instruments
marine sediment microbial fuel cells
Marine sediments
Maximum power density
Microorganisms
Monitoring instruments
Multi wall carbon nanotubes
multiwalled carbon nanotubes
Nanotechnology
Nanotubes
Oxidoreductions
Sediment
title A novel anode modified by 1,5‐dihydroxyanthraquinone/multiwalled carbon nanotubes composite in marine sediment microbial fuel cell and its electrochemical performance
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