Dichloro(propane-1,3-diamine-[kappa]2N,N')platinum(II), dichloro(propane-1,3-diamine-[kappa]2N,N')palladium(II) and [mu]-4,9-diazadodecane-1,12-diamine-[kappa]2N1,N4:[kappa]2N9,N12-bis[dichloroplatinum(II)]
In the title compounds, [PtCl2(C3H10N2)], (I), [PdCl2(C3H10N2)], (II), and [Pt2Cl4(C10H26N4)], (III), each metal atom lies in a distorted cis -square coordination geometry. Compounds (I) and (II) are isostructural, and each complex has a mirror plane through the metal atom and the middle C atom of t...
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| Veröffentlicht in: | Acta crystallographica. Section C, Crystal structure communications Crystal structure communications, 2006-04, Vol.62 (4), p.m136 |
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| container_title | Acta crystallographica. Section C, Crystal structure communications |
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| creator | Odoko, Mamiko Okabe, Nobuo |
| description | In the title compounds, [PtCl2(C3H10N2)], (I), [PdCl2(C3H10N2)], (II), and [Pt2Cl4(C10H26N4)], (III), each metal atom lies in a distorted cis -square coordination geometry. Compounds (I) and (II) are isostructural, and each complex has a mirror plane through the metal atom and the middle C atom of the propane-1,3-diamine ligand. In (III), the binuclear complex [Pt2Cl4(spn)] has an inversion center at the middle of the 4,9-diazadodecane-1,12-diamine (spermine, spn) ligand. The six-membered chelate rings in (III) adopt a chair form, which is unsymmetrical and less flattened than those in (I) and (II). In all three crystal structures, there are intermolecular N--H[ctdot]Cl hydrogen bonds. [PUBLICATION ABSTRACT] |
| doi_str_mv | 10.1107/S010827010600610X |
| format | Article |
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Compounds (I) and (II) are isostructural, and each complex has a mirror plane through the metal atom and the middle C atom of the propane-1,3-diamine ligand. In (III), the binuclear complex [Pt2Cl4(spn)] has an inversion center at the middle of the 4,9-diazadodecane-1,12-diamine (spermine, spn) ligand. The six-membered chelate rings in (III) adopt a chair form, which is unsymmetrical and less flattened than those in (I) and (II). In all three crystal structures, there are intermolecular N--H[ctdot]Cl hydrogen bonds. [PUBLICATION ABSTRACT]</description><identifier>ISSN: 0108-2701</identifier><identifier>EISSN: 1600-5759</identifier><identifier>DOI: 10.1107/S010827010600610X</identifier><language>eng</language><publisher>Chester: Wiley Subscription Services, Inc</publisher><subject>Atoms & subatomic particles ; Crystal structure ; Crystallography ; Geometry ; Hydrogen bonds</subject><ispartof>Acta crystallographica. 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Section C, Crystal structure communications</title><description>In the title compounds, [PtCl2(C3H10N2)], (I), [PdCl2(C3H10N2)], (II), and [Pt2Cl4(C10H26N4)], (III), each metal atom lies in a distorted cis -square coordination geometry. Compounds (I) and (II) are isostructural, and each complex has a mirror plane through the metal atom and the middle C atom of the propane-1,3-diamine ligand. In (III), the binuclear complex [Pt2Cl4(spn)] has an inversion center at the middle of the 4,9-diazadodecane-1,12-diamine (spermine, spn) ligand. The six-membered chelate rings in (III) adopt a chair form, which is unsymmetrical and less flattened than those in (I) and (II). In all three crystal structures, there are intermolecular N--H[ctdot]Cl hydrogen bonds. 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Compounds (I) and (II) are isostructural, and each complex has a mirror plane through the metal atom and the middle C atom of the propane-1,3-diamine ligand. In (III), the binuclear complex [Pt2Cl4(spn)] has an inversion center at the middle of the 4,9-diazadodecane-1,12-diamine (spermine, spn) ligand. The six-membered chelate rings in (III) adopt a chair form, which is unsymmetrical and less flattened than those in (I) and (II). In all three crystal structures, there are intermolecular N--H[ctdot]Cl hydrogen bonds. [PUBLICATION ABSTRACT]</abstract><cop>Chester</cop><pub>Wiley Subscription Services, Inc</pub><doi>10.1107/S010827010600610X</doi></addata></record> |
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| identifier | ISSN: 0108-2701 |
| ispartof | Acta crystallographica. Section C, Crystal structure communications, 2006-04, Vol.62 (4), p.m136 |
| issn | 0108-2701 1600-5759 |
| language | eng |
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| source | Wiley Online Library Journals Frontfile Complete; Alma/SFX Local Collection |
| subjects | Atoms & subatomic particles Crystal structure Crystallography Geometry Hydrogen bonds |
| title | Dichloro(propane-1,3-diamine-[kappa]2N,N')platinum(II), dichloro(propane-1,3-diamine-[kappa]2N,N')palladium(II) and [mu]-4,9-diazadodecane-1,12-diamine-[kappa]2N1,N4:[kappa]2N9,N12-bis[dichloroplatinum(II)] |
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